Carbocyclic pincer carbene complexes of ruthenium: syntheses and reversible hydrogenation

Nicholas R. Wiedmaier, Hartmut Schubert, Hermann A. Mayer and Lars Wesemann

Dalton Trans., 2021, 50, 11814
DOI: 10.1039/D1DT02266K

Beyond simple hetero Diels–Alder cycloadditions. A new type of element–ligand cooperativity at N,C,N-coordinated arsinidene and stibinidene centres in the reaction with an electron-deficient alkyne

Jan Zechovský, Vít Kremláček, Milan Erben, Martin Hejda, Elena Rychagova, Roman Jambor, Aleš Růžička, Sergey Ketkov and Libor Dostál

Dalton Trans., 2022, 51, 15933
DOI: 10.1039/D2DT02499C

Cooperative borane activation by tuning hemilability of different Os-κ2-N,Se-chelated complexes

Faneesha Assanar, Sourav Gayen, Deepak Kumar Patel, Thalappil Pradeep and Sundargopal Ghosh

Chem. Sci., 2026, 17, 3129
DOI: 10.1039/D5SC06346A

Synthesis and reactivity of a PCcarbeneP cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)

Simon Sung, Qingyang Wang, Tobias Krämer and Rowan D. Young

Chem. Sci., 2018, 9, 8234
DOI: 10.1039/C8SC02782J

Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis

Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre and Paul Fleurat-Lessard

Chem. Sci., 2021, 12, 253
DOI: 10.1039/D0SC04736H

Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PCylideN pincer ligand

Sébastien Lapointe, Prakash Duari and Viktoria H. Gessner

Chem. Sci., 2023, 14, 3816
DOI: 10.1039/D2SC06759E

Stable nickel complexes of a siliconoid/silylene hybrid ligand: competent hydrosilylation catalysts for terminal olefins

Luisa Giarrana, Dennis Welterlich, Michael Zimmer, Bernd Morgenstern and David Scheschkewitz

Inorg. Chem. Front., 2026, 13, 3462
DOI: 10.1039/D6QI00025H

Cooperative B–H bond activation: dual site borane activation by redox active κ2-N,S-chelated complexes

Mohammad Zafar, Asif Ahmad, Suvam Saha, Rongala Ramalakshmi, Thierry Roisnel and Sundargopal Ghosh

Chem. Sci., 2022, 13, 8567
DOI: 10.1039/D2SC00907B

Metal–ligand cooperative C–O bond cleavage of propargylic alcohol with protic pyrazole complexes of ruthenium

Naoto Tashima, Satomi Ohta and Shigeki Kuwata

Faraday Discuss., 2019, 220, 364
DOI: 10.1039/C9FD00040B

Cooperation towards nobility: equipping first-row transition metals with an aluminium sword

Sergio Fernández, Selwin Fernando and Oriol Planas

Dalton Trans., 2023, 52, 14259
DOI: 10.1039/D3DT02722H

Cycloaddition of isoselenocyanates to sodium and magnesium metallacycles

Vladimir A. Dodonov, Olga A. Kushnerova, Roman V. Rumyantsev, Alexander S. Novikov, Vladimir K. Osmanov and Igor L. Fedushkin

Dalton Trans., 2022, 51, 4113
DOI: 10.1039/D1DT04366H

Directed C–H activation with iron carbene complexes

Zachary S. Lincoln, Melissa R. Hoffbauer and Vlad M. Iluc

Inorg. Chem. Front., 2024, 11, 5579
DOI: 10.1039/D4QI01088D

N-Heterocyclic silylenes as ambiphilic activators and ligands

Mirjam J. Krahfuss and Udo Radius

Dalton Trans., 2021, 50, 6752
DOI: 10.1039/D1DT00617G

Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation

Matthew R. Elsby, Changjin Oh, Mina Son, Scott Y. H. Kim, Mu-Hyun Baik and R. Tom Baker

Chem. Sci., 2022, 13, 12550
DOI: 10.1039/D2SC04339D

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

Matthew R. Elsby and R. Tom Baker

Chem. Soc. Rev., 2020, 49, 8933
DOI: 10.1039/D0CS00509F

Cooperative E–H bond insertions and activations by transition metal complexes (E = B, C, Si, and Al): hemilability at play

Suvam Saha, Stutee Mohapatra and Sundargopal Ghosh

Dalton Trans., 2026, 55, 4387
DOI: 10.1039/D5DT03092G

Quantifying variation in cooperative B–H bond activations using Os(ii) and Os(iii) κ2-N,S-chelated complexes: same, but different

Sourav Gayen, Faneesha Assanar, Sampad Shyamal, Dorothy Priyanka Dorairaj and Sundargopal Ghosh

Chem. Sci., 2024, 15, 15913
DOI: 10.1039/D4SC05092D

Silylene induced cooperative B–H bond activation and unprecedented aldehyde C–H bond splitting with amidinate ring expansion

V. S. V. S. N. Swamy, K. Vipin Raj, Kumar Vanka, Sakya S. Sen and Herbert W. Roesky

Chem. Commun., 2019, 55, 3536
DOI: 10.1039/C9CC00296K

Facile synthesis of Pd(ii) and Ni(ii) pincer carbene complexes by the double C–H bond activation of a new hexahydropyrimidine-based bis(phosphine): catalysis of C–N couplings

Vasudevan Subramaniyan, Bidisa Dutta, Anbarasu Govindaraj and Ganesan Mani

Dalton Trans., 2019, 48, 7203
DOI: 10.1039/C8DT03413C

Cooperative approaches in catalytic hydrogenation and dehydrogenation

Michael A. Stevens and Annie L. Colebatch

Chem. Soc. Rev., 2022, 51, 1881
DOI: 10.1039/D1CS01171E

Direct oxide transfer from an η2-keto ligand to generate a cobalt PCcarbeneP(O) pincer complex

Simon Sung, Hendrik Tinnermann, Tobias Krämer and Rowan D. Young

Dalton Trans., 2019, 48, 9920
DOI: 10.1039/C9DT02313E

Redox-state dependent activation of silanes and ammonia with reverse polarity (PCcarbeneP)Ni complexes: electrophilic vs. nucleophilic carbenes

Etienne A. LaPierre, Warren E. Piers and Chris Gendy

Dalton Trans., 2018, 47, 16789
DOI: 10.1039/C8DT04409K

Formation and Reactivity with tBuCN of a Thorium Phosphinidiide through a Combined Experimental and Computational Analysis

Michael L. Tarlton, Yan Yang, Steven P. Kelley, Laurent Maron and Justin R. Walensky

Organometallics, 2021, 40, 2701
DOI: 10.1021/acs.organomet.1c00330

Rhodium Complexes in P−H Bond Activation Reactions

Víctor Varela‐Izquierdo, Ana M. Geer, Bas de Bruin, José A. López, Miguel A. Ciriano and Cristina Tejel

Chemistry A European J, 2019, 25, 15915
DOI: 10.1002/chem.201903981

Polymer‐Anchored Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

Shrouq Mujahed, Federica Valentini, Shirel Cohen, Luigi Vaccaro and Dmitri Gelman

ChemSusChem, 2019, 12, 4693
DOI: 10.1002/cssc.201901728

Square Planar Nucleophilic and Radical Pt(II) Carbenes

Anthony P. Deziel, Melissa R. Hoffbauer and Vlad M. Iluc

Organometallics, 2019, 38, 879
DOI: 10.1021/acs.organomet.8b00864

Reactivity of Transition Metal Gallylene Complexes Toward Substrates with Multiple Carbon–Element Bonds

Vladimir A. Dodonov, Vladimir G. Sokolov, Evgeny V. Baranov, Alexandra A. Skatova, Wenhua Xu, Yanxia Zhao, Xiao-Juan Yang and Igor L. Fedushkin

Inorg. Chem., 2022, 61, 14962
DOI: 10.1021/acs.inorgchem.2c01296

The chemistry of Group 8 metal complexes with phosphinous acids and related P OH ligands

Javier Francos, David Elorriaga, Pascale Crochet and Victorio Cadierno

Coordination Chemistry Reviews, 2019, 387, 199
DOI: 10.1016/j.ccr.2019.02.014

Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid

María L. Buil, Javier A. Cabeza, Miguel A. Esteruelas, Susana Izquierdo, Carlos J. Laglera-Gándara, Antonio I. Nicasio and Enrique Oñate

Inorg. Chem., 2021, 60, 16860
DOI: 10.1021/acs.inorgchem.1c02893

Rh Complexes with Pincer Carbene CNC Lutidine-Based Ligands: Reactivity Studies toward H2Addition

Pablo Hermosilla, Pilar García-Orduña, Fernando J. Lahoz, Víctor Polo and Miguel A. Casado

Organometallics, 2021, 40, 3720
DOI: 10.1021/acs.organomet.1c00453

A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment

María Frutos, Nasrina Parvin, Antoine Baceiredo, David Madec, Nathalie Saffon‐Merceron, Vicenç Branchadell and Tsuyoshi Kato

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202201932

Tuning Ruthenium Carbene Complexes for Selective P−H Activation through Metal‐Ligand Cooperation

Kai‐Stephan Feichtner, Lennart T. Scharf, Thorsten Scherpf, Bert Mallick, Nils Boysen and Viktoria H. Gessner

Chemistry A European J, 2021, 27, 17351
DOI: 10.1002/chem.202103151

Access to and Reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP Pincer Complexes

Qingyang Wang, Richard A. Manzano, Hendrik Tinnermann, Simon Sung, Baptiste Leforestier, Tobias Krämer and Rowan D. Young

Angew Chem Int Ed, 2021, 60, 18168
DOI: 10.1002/anie.202104130

Experimental and Theoretical Study of NiII‐ and PdII‐Promoted Double Geminal C(sp3)−H Bond Activation Providing Facile Access to NHC Pincer Complexes: Isolated Intermediates and Mechanism

Fengkai He, Christophe Gourlaouen, Huan Pang and Pierre Braunstein

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202200507

From Carbene-Dithiolene Zwitterion Mediated B–H Bond Activation to BH3·SMe2-Assisted Boron–Boron Bond Formation

Yuzhong Wang, Phuong M. Tran, Mitchell E. Lahm, Pingrong Wei, Earle R. Adams, Henry F. Schaefer and Gregory H. Robinson

Organometallics, 2023, 42, 3328
DOI: 10.1021/acs.organomet.3c00361

Cationic Tetrylene‐Iron(0) Complexes: Access Points for Cooperative, Reversible Bond Activation and Open‐Shell Iron(−I) Ferrato‐Tetrylenes**

Philip M. Keil, Ademola Soyemi, Kilian Weisser, Tibor Szilvási, Christian Limberg and Terrance J. Hadlington

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202218141

Influence of Multisite Metal–Ligand Cooperativity on the Redox Activity of Noninnocent N2S2 Ligands

Kyle D. Spielvogel, Javier A. Luna, Sydney M. Loria, Leah P. Weisburn, Nathan C. Stumme, Mark R. Ringenberg, Gummadi Durgaprasad, Jason M. Keith, Scott K. Shaw and Scott R. Daly

Inorg. Chem., 2020, 59, 10845
DOI: 10.1021/acs.inorgchem.0c01353

Catalytic Deoxygenation of Amine and Pyridine N-Oxides Using Rhodium PCcarbeneP Pincer Complexes

Hendrik Tinnermann, Simon Sung, Ben A. Cala, Hashir J. Gill and Rowan D. Young

Organometallics, 2020, 39, 797
DOI: 10.1021/acs.organomet.9b00778

Facile Chan‐Lam coupling using ferrocene tethered N‐heterocyclic carbene‐copper complex anchored on graphene

Shivanand Gajare, Megha Jagadale, Altafhusen Naikwade, Prakash Bansode and Gajanan Rashinkar

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.4915

Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations

Xiaotian Qi and Yu Lan

Acc. Chem. Res., 2021, 54, 2905
DOI: 10.1021/acs.accounts.1c00075

Influence of the Leaving Group on C–H Activation Pathways in Palladium Pincer Complexes

Melissa R. Hoffbauer, Cezar C. Comanescu, Brittany J. Dymm and Vlad M. Iluc

Organometallics, 2018, 37, 2086
DOI: 10.1021/acs.organomet.8b00237

Thermodynamic Modulation of Dihydrogen Activation Through Rational Ligand Design in GeII–Ni0 Complexes

Philip M. Keil, Sophia Ezendu, Annika Schulz, Malte Kubisz, Tibor Szilvási and Terrance J. Hadlington

J. Am. Chem. Soc., 2024, 146, 23606
DOI: 10.1021/jacs.4c08297

Control over the Redox Cooperative Mechanism of Radical Carbene Transfer Reactions for the Efficient Active‐Metal‐Template Synthesis of [2]Rotaxanes

Arthur F. P. Alcântara, Liniquer A. Fontana, Marlon P. Almeida, Vitor H. Rigolin, Marcos A. Ribeiro, Wdeson P. Barros and Jackson D. Megiatto

Chemistry A European J, 2020, 26, 7808
DOI: 10.1002/chem.201905602

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Lennart Hensle and Viktoria H. Gessner

Chemistry A European J, 2025
DOI: 10.1002/chem.202502814

DFT Struggles to Predict the Energy Landscape for Iron Pyridine Diimine-Catalyzed [2 + 2] Cycloaddition of Alkenes: Insights into the Problem and Alternative Solutions

Nikunj Kumar and Puneet Gupta

J. Phys. Chem. A, 2024, 128, 4114
DOI: 10.1021/acs.jpca.3c08325

A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment

María Frutos, Nasrina Parvin, Antoine Baceiredo, David Madec, Nathalie Saffon‐Merceron, Vicenç Branchadell and Tsuyoshi Kato

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202201932

Charge frustration in ligand design and functional group transfer

Dominik Munz and Karsten Meyer

Nat Rev Chem, 2021, 5, 422
DOI: 10.1038/s41570-021-00276-3

Intramolecular O‐arylation using nano‐magnetite supportedN‐heterocyclic carbene‐copper complex with wingtip ferrocene

Altafhusen Naikwade, Megha Jagadale, Dolly Kale, Shivanand Gajare, Prakash Bansode and Gajanan Rashinkar

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.5066

Access to and Reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP Pincer Complexes

Qingyang Wang, Richard A. Manzano, Hendrik Tinnermann, Simon Sung, Baptiste Leforestier, Tobias Krämer and Rowan D. Young

Angewandte Chemie, 2021, 133, 18316
DOI: 10.1002/ange.202104130

Nucleophilic Reactivity at a ═CH Arm of a Lutidine-Based CNC/Rh System: Unusual Alkyne and CO2 Activation

Pablo Hermosilla, Pilar García-Orduña, Pablo J. Sanz Miguel, Víctor Polo and Miguel A. Casado

Inorg. Chem., 2022, 61, 7120
DOI: 10.1021/acs.inorgchem.2c00617

Reversible Dihydrogen Activation and Catalytic Transfer Hydrogenation with Iminophosphinoyl‐Tethered Ruthenium Carbene Complexes

Lennart Hensle, Kai‐Stephan Feichtner, Michelle Kleinhaus, Tobias Heinen, Nils Boysen, Florian Papp and Viktoria H. Gessner

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301600

Mechanistic Study on Catalytic Disproportionation of Hydrazine by a Protic Pincer‐Type Iron Complex through Proton‐Coupled Electron Transfer

Hiromasa Tanaka, Seiji Hitaoka, Kazuki Umehara, Kazunari Yoshizawa and Shigeki Kuwata

Eur J Inorg Chem, 2020, 2020, 1472
DOI: 10.1002/ejic.201901135

Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

Akinobu Nakada, Takeshi Matsumoto and Ho-Chol Chang

Coordination Chemistry Reviews, 2022, 473, 214804
DOI: 10.1016/j.ccr.2022.214804

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2018

James W. Herndon

Coordination Chemistry Reviews, 2019, 401, 213051
DOI: 10.1016/j.ccr.2019.213051

Nonpalindromic Rhodium PCcarbeneP Pincer Complexes Featuring Electron-Deficient Phosphino Substituents

Clarence Tan, Hendrik Tinnermann, Simon Sung, Li Heng Kat and Rowan D. Young

Organometallics, 2021, 40, 4098
DOI: 10.1021/acs.organomet.1c00538

Synthesis and Characterisation of Transition Metal Complexes of a Novel 1,5‐benzodiazepine‐Functionalised Tertiary Phosphine

Sean E. Durran, Mark R. J. Elsegood, Thomas A. Noble, Martin B. Smith, Thomas Gelbrich, Michael B. Hursthouse and Mark E. Light

Eur J Inorg Chem, 2021, 2021, 2274
DOI: 10.1002/ejic.202100236

Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study

Ranjeesh Thenarukandiyil, Eno Paenurk, Anthony Wong, Natalia Fridman, Amir Karton, Raanan Carmieli, Gabriel Ménard, Renana Gershoni-Poranne and Graham de Ruiter

Inorg. Chem., 2021, 60, 18296
DOI: 10.1021/acs.inorgchem.1c02925

LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts

George Kleinhans, Aino J. Karhu, Hugo Boddaert, Sadia Tanweer, David Wunderlin and Daniela I. Bezuidenhout

Chem. Rev., 2023, 123, 8781
DOI: 10.1021/acs.chemrev.3c00202

Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes

Richard A. Manzano and Rowan D. Young

Coordination Chemistry Reviews, 2021, 449, 214215
DOI: 10.1016/j.ccr.2021.214215

Ruthenium(II) Porphyrin Quinoid Carbene Complexes: Synthesis, Crystal Structure, and Reactivity toward Carbene Transfer and Hydrogen Atom Transfer Reactions

Hai-Xu Wang, Qingyun Wan, Kai Wu, Kam-Hung Low, Chen Yang, Cong-Ying Zhou, Jie-Sheng Huang and Chi-Ming Che

J. Am. Chem. Soc., 2019, 141, 9027
DOI: 10.1021/jacs.9b03357

Cooperative B–H and Si–H Bond Activations by κ2-N,S-Chelated Ruthenium Borate Complexes

Mohammad Zafar, Rongala Ramalakshmi, Asif Ahmad, P. K. Sudhadevi Antharjanam, Sébastien Bontemps, Sylviane Sabo-Etienne and Sundargopal Ghosh

Inorg. Chem., 2021, 60, 1183
DOI: 10.1021/acs.inorgchem.0c03306

Carbene complex formation versus cyclometallation from a phosphoryl-tethered methanide ruthenium complex

Kai-Stephan Feichtner, Florian Papp, Michelle Schmidt, Maurice Paaßen and Viktoria H. Gessner

Journal of Organometallic Chemistry, 2020, 915, 121235
DOI: 10.1016/j.jorganchem.2020.121235

C−N, C−S and S−S Bond Cleavage by Rhodium PCcarbeneP Pincer Complexes

Hendrik Tinnermann and Rowan D. Young

Chemistry An Asian Journal, 2020, 15, 2873
DOI: 10.1002/asia.202000515

Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PCcarbeneS Pincer Ligand

Lennart T. Scharf, Alexander Kowsari, Thorsten Scherpf, Kai-Stephan Feichtner and Viktoria H. Gessner

Organometallics, 2019, 38, 4093
DOI: 10.1021/acs.organomet.9b00386

Carbonylative Formal Cycloaddition between Alkylarenes and Aldimines Enabled by Palladium-Catalyzed Double C–H Bond Activation

Yongzheng Ding, Jianing Wu and Hanmin Huang

J. Am. Chem. Soc., 2023, 145, 4982
DOI: 10.1021/jacs.3c00004

Reversible C–C Double Bond Cleavage to Form a Metal Carbene and an Alkene Enabled on an Iridium Complex Bearing a Pincer-type Alkoxycarbene Ligand

Kohei Takahashi and Nobuharu Iwasawa

Organometallics, 2021, 40, 3926
DOI: 10.1021/acs.organomet.1c00498

Chelating and Pincer Oxime Complexes of Palladium: Rearrangement of a 1,3-Diacylbenzene Dioxime upon Palladium Coordination

Jordan K. Pierce, Emily A. McEachern, Fengrui Qu, Logan M. Whitt, Ken Belmore and Kevin H. Shaughnessy

Organometallics, 2024, 43, 737
DOI: 10.1021/acs.organomet.3c00526

Cationic Tetrylene‐Iron(0) Complexes: Access Points for Cooperative, Reversible Bond Activation and Open‐Shell Iron(−I) Ferrato‐Tetrylenes**

Philip M. Keil, Ademola Soyemi, Kilian Weisser, Tibor Szilvási, Christian Limberg and Terrance J. Hadlington

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202218141

Selective Carbanion–Pyridine Coordination of a Reactive P,N Ligand to RhI

Marc Devillard, Andreas Ehlers, Maxime A. Siegler and Jarl Ivar van der Vlugt

Chemistry A European J, 2019, 25, 3875
DOI: 10.1002/chem.201805504

Recent Advances in Rare Earth Complexes Containing N-Heterocyclic Carbenes: Synthesis, Reactivity, and Applications in Polymerization

Yu Pan, Xinxin Jiang, Yat-Ming So, Ching Tat To and Gaohong He

Catalysts, 2020, 10, 71
DOI: 10.3390/catal10010071

Carbon Dioxide Catalyzed Cyclometallation of a Carbene Complex: Synthesis and Mechanism

Lennart T. Scharf, Kai‐Stephan Feichtner and Viktoria H. Gessner

Eur J Inorg Chem, 2019, 2019, 2990
DOI: 10.1002/ejic.201900299

Stability and Solution Behavior of [(dpp-Bian)Ln] and [(dpp-Bian)LnX] (Ln = Yb, Tm, or Dy; X = I, F, or N3)

Vladimir A. Dodonov, Valentin M. Makarov, Marina N. Zemnyukova, Danila A. Razborov, Evgeny V. Baranov, Artem S. Bogomyakov, Victor I. Ovcharenko and Igor L. Fedushkin

Organometallics, 2023, 42, 2558
DOI: 10.1021/acs.organomet.2c00640

N‐Heterocyclic Carbene Complexes RuII(Arene) and their Application as ROMP Catalysts, Antioxidant and Anticancer Agents

Rubina Troiano, Domenico Iacopetta, Assunta D'Amato, Annaluisa Mariconda, Jessica Ceramella, Alessia Catalano, Maria Stefania Sinicropi and Pasquale Longo

Eur J Inorg Chem, 2024, 27
DOI: 10.1002/ejic.202400402

Porous [Ru(bpy)3]2+-Cored Metallosupramolecular Polymers: Preparation and Recyclable Photocatalysis for the Formation of Amides and 2-Diazo-2-phenylacetates

Zhong-Zheng Gao, Yan-Yan Xu, Ze-Kun Wang, Hui Wang, Dan-Wei Zhang and Zhan-Ting Li

ACS Appl. Polym. Mater., 2020, 2, 4885
DOI: 10.1021/acsapm.0c00800

Enthalpy-Controlled Insertion of a “Nonspectator” Tricoordinate Phosphorus Ligand into Group 10 Transition Metal–Carbon Bonds

Seung Jun Hwang, Akira Tanushi and Alexander T. Radosevich

J. Am. Chem. Soc., 2020, 142, 21285
DOI: 10.1021/jacs.0c11161

Cooperative B─H Bond Activation: A Direct Route to Monometallic Diborane(5) and Dihydroborate Complexes

Suvam Saha, Pekham Chakrabortty and Sundargopal Ghosh

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202502125