Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, Kira I. Pashanova, Olesya Yu. Trofimova, Maxim G. Chegerev, Alyona A. Starikova, Anton V. Cherkasov, Georgy K. Fukin, Ilya A. Yakushev and Alexandr V. Piskunov

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6593

Aluminum-Catalyzed Hydroboration of Alkenes

Alessandro Bismuto, Michael J. Cowley and Stephen P. Thomas

ACS Catal., 2018, 8, 2001
DOI: 10.1021/acscatal.7b04279

Tetranuclear Strontium and Barium Siloxide/Amide Clusters in Metal‐Ligand Cooperative Catalysis

Benjamin Freitag, Phillip Stegner, Katharina Thum, Christian A. Fischer and Sjoerd Harder

Eur J Inorg Chem, 2018, 2018, 1938
DOI: 10.1002/ejic.201800231

Ring‐Shaped Phosphinoamido‐Magnesium‐Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis

Lea Fohlmeister and Andreas Stasch

Chemistry A European J, 2016, 22, 10235
DOI: 10.1002/chem.201601623

Molecular Main Group Metal Hydrides

Matthew M. D. Roy, Alvaro A. Omaña, Andrew S. S. Wilson, Michael S. Hill, Simon Aldridge and Eric Rivard

Chem. Rev., 2021, 121, 12784
DOI: 10.1021/acs.chemrev.1c00278

Bis(o-Aminophenolato)germanium(II) and Tin(II) Complexes in Hydroboration Reactions of Aromatic Aldehydes

K. V. Arsen’eva, A. V. Klimashevskaya, A. V. Cherkasov and A. V. Piskunov

Russ J Coord Chem, 2025, 51, 246
DOI: 10.1134/S1070328425600238

Heavy Alkaline–Earth Metal Formazanate Complexes and Their Catalytic Applications

Da Jin, Xiaofei Sun and Peter W. Roesky

Organometallics, 2023, 42, 1725
DOI: 10.1021/acs.organomet.2c00591

Diverse Functionality of Molecular Germanium: Emerging Opportunities as Catalysts

Nilanjana Mukherjee and Moumita Majumdar

J. Am. Chem. Soc., 2024, 146, 24209
DOI: 10.1021/jacs.4c05498

Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds

Yuanyuan Li, Haohua Chen, Lingbo Qu, Ruopeng Bai and Yu Lan

Chinese Chemical Letters, 2019, 30, 2249
DOI: 10.1016/j.cclet.2019.06.001

Osmium-Acyl Decarbonylation Promoted by Tp-Mediated Allenylidene Abstraction: A New Role of the Tp Ligand

Sonia Bajo, Miguel A. Esteruelas, Ana M. López and Enrique Oñate

Organometallics, 2014, 33, 4057
DOI: 10.1021/om500569m

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes

Marc Magre, Marcin Szewczyk and Magnus Rueping

Org. Lett., 2020, 22, 1594
DOI: 10.1021/acs.orglett.0c00184

Reduction of Cyclic and Linear Organic Carbonates Using a Readily Available Magnesium Catalyst

Marcin Szewczyk, Marc Magre, Viktoriia Zubar and Magnus Rueping

ACS Catal., 2019, 9, 11634
DOI: 10.1021/acscatal.9b04086

Cobalt(II) Coordination Polymer as a Precatalyst for Selective Hydroboration of Aldehydes, Ketones, and Imines

Jing Wu, Haisu Zeng, Jessica Cheng, Shengping Zheng, James A. Golen, David R. Manke and Guoqi Zhang

J. Org. Chem., 2018, 83, 9442
DOI: 10.1021/acs.joc.8b01094

Organomagnesium‐Catalyzed Isomerization of Terminal Alkynes to Allenes and Internal Alkynes

Raphaël Rochat, Koji Yamamoto, Michael J. Lopez, Haruki Nagae, Hayato Tsurugi and Kazushi Mashima

Chemistry A European J, 2015, 21, 8112
DOI: 10.1002/chem.201500179

Synthesis and Structure of a Dimeric Yttrium Complex [LSi(BH3)(C5Me4)Y(CH2SiMe3)2]2 (L = PhC(NtBu)2) and Its Catalytic Application for Hydroboration of Ketones and Aldehydes

Ke Lou, Fenghua Zu, Jianjun Yi and Chunming Cui

Organometallics, 2021, 40, 4092
DOI: 10.1021/acs.organomet.1c00501

Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide

Che Chang Chong and Rei Kinjo

ACS Catal., 2015, 5, 3238
DOI: 10.1021/acscatal.5b00428

Highly Selective Hydroboration of Carbonyls by a Manganese Catalyst: Insight into the Reaction Mechanism

Srikanth Vijjamarri, Timothy M. O’Denius, Bin Yao, Alena Kubátová and Guodong Du

Organometallics, 2020, 39, 3375
DOI: 10.1021/acs.organomet.0c00448

Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin

Andrew D. Bage, Thomas A. Hunt and Stephen P. Thomas

Org. Lett., 2020, 22, 4107
DOI: 10.1021/acs.orglett.0c01168

Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles

Courtney Boone, Ilia Korobkov and Georgii I. Nikonov

ACS Catal., 2013, 3, 2336
DOI: 10.1021/cs400581w

Organocatalytic, Enantioselective, Intramolecular Oxa-Michael Reaction of Alkoxyboronate: A New Strategy for Enantioenriched 1-Substituted 1,3-Dihydroisobenzofurans

Barnala Raveendra, Braja Gopal Das and Prasanta Ghorai

Org. Lett., 2014, 16, 5580
DOI: 10.1021/ol502614n

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage

Smita Patnaik and Aaron D. Sadow

Angew Chem Int Ed, 2019, 58, 2505
DOI: 10.1002/anie.201813305

Investigation of N‐Heterocyclic Carbene‐Supported Group 12 Triflates as Pre‐catalysts for Hydrosilylation/Borylation

Matthew M. D. Roy, Michael J. Ferguson, Robert McDonald and Eric Rivard

Chemistry A European J, 2016, 22, 18236
DOI: 10.1002/chem.201603704

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

Ross McLellan, Alan R. Kennedy, Samantha A. Orr, Stuart D. Robertson and Robert E. Mulvey

Angew Chem Int Ed, 2017, 56, 1036
DOI: 10.1002/anie.201610905

Synthesis and Catalytic Activity of Iron Hydride Ligated with Bidentate N-Heterocyclic Silylenes for Hydroboration of Carbonyl Compounds

Xinghao Qi, Tingting Zheng, Junhao Zhou, Yanhong Dong, Xia Zuo, Xiaoyan Li, Hongjian Sun, Olaf Fuhr and Dieter Fenske

Organometallics, 2019, 38, 268
DOI: 10.1021/acs.organomet.8b00700

On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides

Alexa Caise, Barnabé Berger, Aidan Murray, Eugene Kolychev, Jamie Hicks, M. Ángeles Fuentes, Job J. C. Struijs, Jose M. Goicoechea and Simon Aldridge

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202517007

Catalytic Hydroboration of Ketones Using Mn(CO)5Br and Mn2(CO)10

Aleksandra Szymańska, Mateusz Nowicki, Subhabrata De, Barbara Krupa, Jakub Szyling, Katarina Ležaić, Marc‐Etienne Moret and Jędrzej Walkowiak

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.70092

Hydrido‐Komplexe des Calciums: eine neue Familie molekularer Erdalkalimetall‐Verbindungen

Debabrata Mukherjee, Danny Schuhknecht and Jun Okuda

Angewandte Chemie, 2018, 130, 9736
DOI: 10.1002/ange.201801869

Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions

Kuntal Manna, Pengfei Ji, Francis X. Greene and Wenbin Lin

J. Am. Chem. Soc., 2016, 138, 7488
DOI: 10.1021/jacs.6b03689

n-Butyllithium Catalyzed Selective Hydroboration of Aldehydes and Ketones

Zhangye Zhu, Xueli Wu, Xiaojuan Xu, Zhenjie Wu, Mingqiang Xue, Yingming Yao, Qi Shen and Xiaoguang Bao

J. Org. Chem., 2018, 83, 10677
DOI: 10.1021/acs.joc.8b01495

Hydroboration, Cyanosilylation, and Sequential Cyanosilylation and Hydroboration of Carbonyl Compounds in the Presence of a TiIV Amido Complex as an Efficient Catalyst

Adimulam Harinath, Jayeeta Bhattcharjee, Koteswar Rao Gorantla, Bhabani S. Mallik and Tarun K. Panda

Eur J Org Chem, 2018, 2018, 3180
DOI: 10.1002/ejoc.201800547

Lanthanide Mimicking by Magnesium for Oxazolidinone Synthesis

Rohit Kumar, Biplab Mahata, S. Gayathridevi, K. Vipin Raj, Kumar Vanka and Sakya S. Sen

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303478

Rapid, Mild, and Selective Ketone and Aldehyde Hydroboration/Reduction Mediated by a Simple Lanthanide Catalyst

Victoria L. Weidner, Christopher J. Barger, Massimiliano Delferro, Tracy L. Lohr and Tobin J. Marks

ACS Catal., 2017, 7, 1244
DOI: 10.1021/acscatal.6b03332

Accessing the Single‐Electron Manifold: Magnesium‐mediated Hydrogen Release from Silanes

David J. Liptrot, Professor Michael S. Hill and Mary F. Mahon

Angew Chem Int Ed, 2014, 53, 6224
DOI: 10.1002/anie.201403208

Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis

Yoon Kyung Jang, Marc Magre and Magnus Rueping

Org. Lett., 2019, 21, 8349
DOI: 10.1021/acs.orglett.9b03131

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

Ross McLellan, Alan R. Kennedy, Robert E. Mulvey, Samantha A. Orr and Stuart D. Robertson

Chemistry A European J, 2017, 23, 16853
DOI: 10.1002/chem.201703609

Homoleptic Lanthanide Amide Catalysts for Organic Synthesis: Experiment and Theory

Rachel D. Dicken, Alessandro Motta and Tobin J. Marks

ACS Catal., 2021, 11, 2715
DOI: 10.1021/acscatal.0c04882

Recent Developments in Homogeneous Organomagnesium Catalysis

Raphaël Rochat, Michael J. Lopez, Hayato Tsurugi and Kazushi Mashima

ChemCatChem, 2016, 8, 10
DOI: 10.1002/cctc.201500853

Conclusive Evidence on the Mechanism of the Rhodium-Mediated Decyanative Borylation

Miguel A. Esteruelas, Montserrat Oliván and Andrea Vélez

J. Am. Chem. Soc., 2015, 137, 12321
DOI: 10.1021/jacs.5b07357

Magnesium-Catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines

Nicole L. Lampland, Megan Hovey, Debabrata Mukherjee and Aaron D. Sadow

ACS Catal., 2015, 5, 4219
DOI: 10.1021/acscatal.5b01038

Mg(OTf)2 as an Excellent Catalyst for the Reductive Depolymerization and Methanolysis of Polyesters and Polycarbonates

Carlota M. Alfaia and Ana C. Fernandes

Advanced Sustainable Systems, 2024, 8
DOI: 10.1002/adsu.202400042

Neutral, Cationic and Hydride‐substituted Siloxygermylenes

Matthew M. D. Roy, Shiori Fujimori, Michael J. Ferguson, Robert McDonald, Norihiro Tokitoh and Eric Rivard

Chemistry A European J, 2018, 24, 14392
DOI: 10.1002/chem.201802958

Selective Hydroboration of Carboxylic Acids with a Homogeneous Manganese Catalyst

Milan K. Barman, Kuhali Das and Biplab Maji

J. Org. Chem., 2019, 84, 1570
DOI: 10.1021/acs.joc.8b03108

Metal-Free Catalytic Reduction of α,β-Unsaturated Esters by 1,3,2-Diazaphospholene and Subsequent C–C Coupling with Nitriles

Che Chang Chong, Bin Rao and Rei Kinjo

ACS Catal., 2017, 7, 5814
DOI: 10.1021/acscatal.7b01338

Magnesium-Catalyzed Primary, Secondary, and Tertiary Amide Hydroboration

Biplab Mahata, V. Devaraj, Soumya Ranjan Dash, Rajesh G. Gonnade, Kumar Vanka and Sakya S. Sen

Inorg. Chem., 2025, 64, 13405
DOI: 10.1021/acs.inorgchem.5c01787

An Unsymmetric Imino–Phosphanamidinate Ligand and its Y(III) Complex: Synthesis, Characterization, and Catalytic Hydroboration of Carbonyl Compounds

Srinivas Anga, Joydev Acharya and Vadapalli Chandrasekhar

J. Org. Chem., 2021, 86, 2224
DOI: 10.1021/acs.joc.0c02383

Magnesium-Catalyzed Regioselective Hydrophosphinylation of Alkenes with Diarylphosphine Oxides

Lei Zhang, Shaokun Bai and Lijiao Zheng

Organometallics, 2023, 42
DOI: 10.1021/acs.organomet.3c00247

Rapid Synthesis of 3,3′ Bis-Arylated BINOL Derivatives Using a C–H Borylation in Situ Suzuki–Miyaura Coupling Sequence

Ijaz Ahmed and Daniel A. Clark

Org. Lett., 2014, 16, 4332
DOI: 10.1021/ol502126r

Cobalt-Catalyzed Hydroboration of Alkenes, Aldehydes, and Ketones

Sem Raj Tamang, Deepika Bedi, Sara Shafiei-Haghighi, Cecilia R. Smith, Christian Crawford and Michael Findlater

Org. Lett., 2018, 20, 6695
DOI: 10.1021/acs.orglett.8b02775

Donor‐influenced Structure–Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido‐Monohydrido‐Dialkylaluminates

Lara E. Lemmerz, Ross McLellan, Neil R. Judge, Alan R. Kennedy, Samantha A. Orr, Marina Uzelac, Eva Hevia, Stuart D. Robertson, Jun Okuda and Robert E. Mulvey

Chemistry A European J, 2018, 24, 9940
DOI: 10.1002/chem.201801541

Novel aluminium compounds derived from Schiff bases: Synthesis, characterization and catalytic performance in hydroboration

Da Jin, Xiaoli Ma, Yashuai Liu, Jiong Peng and Zhi Yang

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.4637

N-Methylation and Trideuteromethylation of Amines via Magnesium-Catalyzed Reduction of Cyclic and Linear Carbamates

Marc Magre, Marcin Szewczyk and Magnus Rueping

Org. Lett., 2020, 22, 3209
DOI: 10.1021/acs.orglett.0c00988

Titanocene(II)-Catalyzed Hydroboration of Carbonyl Compounds

Abdulafeez A. Oluyadi, Shuhua Ma and Clare N. Muhoro

Organometallics, 2013, 32, 70
DOI: 10.1021/om300828m

Reactivity of [TismPriBenz]MgH and [TismPriBenz]MgMe towards Carbonyl Compounds: Access to Terminal Alkoxide and Enolate Complexes

David A. Vaccaro, Ran Yan and Gerard Parkin

Organometallics, 2024, 43, 746
DOI: 10.1021/acs.organomet.3c00541

Synthesis, characterization, and catalytic performance of aluminum and Tin(II) compounds supported by β-diketiminato ligands

Ying Liu, Xin Liu, Yashuai Liu, Wenling Li, Yi Ding, Mingdong Zhong, Xiaoli Ma and Zhi Yang

Inorganica Chimica Acta, 2018, 471, 244
DOI: 10.1016/j.ica.2017.11.012

On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides

Alexa Caise, Barnabé Berger, Aidan Murray, Eugene Kolychev, Jamie Hicks, M. Ángeles Fuentes, Job J. C. Struijs, Jose M. Goicoechea and Simon Aldridge

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202517007

An unusual chiral-at-metal mechanism for BINOL-metal asymmetric catalysis

Zhenxing Li, Pengfei Chen, Zhigang Ni, Liuzhou Gao, Yue Zhao, Ranran Wang, Congqing Zhu, Guoqiang Wang and Shuhua Li

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-56000-y

Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation

Yaoyu Liang, Uttam Kumar Das, Jie Luo, Yael Diskin-Posner, Liat Avram and David Milstein

J. Am. Chem. Soc., 2022, 144, 19115
DOI: 10.1021/jacs.2c08491

Ligand Effects in Calcium Catalyzed Ketone Hydroboration

Steffen Brand, Andrea Causero, Holger Elsen, Jürgen Pahl, Jens Langer and Sjoerd Harder

Eur J Inorg Chem, 2020, 2020, 1728
DOI: 10.1002/ejic.202000264

Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds

Che Chang Chong, Hajime Hirao and Rei Kinjo

Angew Chem Int Ed, 2015, 54, 190
DOI: 10.1002/anie.201408760

Computational insights into hydroboration with acyclic α-Borylamido-germylene and stannylene catalysts: Cooperative dual catalysis the key to system efficiency

Subhrashis Banerjee and Kumar Vanka

Polyhedron, 2022, 222, 115907
DOI: 10.1016/j.poly.2022.115907

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

Terrance J. Hadlington, Markus Hermann, Gernot Frenking and Cameron Jones

J. Am. Chem. Soc., 2014, 136, 3028
DOI: 10.1021/ja5006477

Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration

Naresh Eedugurala, Zhuoran Wang, Umesh Chaudhary, Nicholas Nelson, Kapil Kandel, Takeshi Kobayashi, Igor I. Slowing, Marek Pruski and Aaron D. Sadow

ACS Catal., 2015, 5, 7399
DOI: 10.1021/acscatal.5b01671

Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation

Marc Magre, Eva Paffenholz, Bholanath Maity, Luigi Cavallo and Magnus Rueping

J. Am. Chem. Soc., 2020, 142, 14286
DOI: 10.1021/jacs.0c05917

Electrostatic Catalyst Generated from Diazadiborinine for Carbonyl Reduction

Di Wu, Ruixing Wang, Yongxin Li, Rakesh Ganguly, Hajime Hirao and Rei Kinjo

Chem, 2017, 3, 134
DOI: 10.1016/j.chempr.2017.06.001

Reductive Elimination and Oxidative Addition of Hydrogen at Organostannylium and Organogermylium Cations

Fatima Diab, Frederik S. W. Aicher, Christian P. Sindlinger, Klaus Eichele, Hartmut Schubert and Lars Wesemann

Chemistry A European J, 2019, 25, 4426
DOI: 10.1002/chem.201805770

Hydroboration of Aldehydes, Ketones, and Carbodiimides Promoted by Mono(imidazolin‐2‐iminato) Hafnium Complexes

Maxim Khononov, Natalia Fridman, Matthias Tamm and Moris S. Eisen

Eur J Org Chem, 2020, 2020, 3153
DOI: 10.1002/ejoc.201901750

Organoactinide‐Catalyzed Monohydroboration of Carbodiimides

Heng Liu, Kseniya Kulbitski, Matthias Tamm and Moris S. Eisen

Chemistry A European J, 2018, 24, 5738
DOI: 10.1002/chem.201705987

Formation of [NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]− via CS2 Insertion into Nickel(III) Hydride Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]−

Kuan-Ting Lai, Wei-Chieh Ho, Tzung-Wen Chiou and Wen-Feng Liaw

Inorg. Chem., 2013, 52, 4151
DOI: 10.1021/ic400293k

Beyond Hydrofunctionalisation: A Well‐Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation

Sandeep Yadav, Ruchi Dixit, Kumar Vanka and Sakya S. Sen

Chemistry A European J, 2018, 24, 1269
DOI: 10.1002/chem.201705795

Accessing the Single‐Electron Manifold: Magnesium‐mediated Hydrogen Release from Silanes

David J. Liptrot, Professor Michael S. Hill and Mary F. Mahon

Angewandte Chemie, 2014, 126, 6338
DOI: 10.1002/ange.201403208

Hydrophosphanylation of Alkynes via Magnesium Complexes: Evidence for Ligand Dependency in Structure–Activity Relationships

Darakshan Parveen, Sneha Mittal, Radhika Shrivas, Biswarup Pathak and Dipak Kumar Roy

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500002

Progressing the Frustrated Lewis Pair Abilities of N-Heterocyclic Carbene/GaR3 Combinations for Catalytic Hydroboration of Aldehydes and Ketones

Leonie J. Bole, Marina Uzelac, Alberto Hernán-Gómez, Alan R. Kennedy, Charles T. O’Hara and Eva Hevia

Inorg. Chem., 2021, 60, 13784
DOI: 10.1021/acs.inorgchem.1c01276

Tris(cyclopentadienyl)lanthanide Complexes as Catalysts for Hydroboration Reaction toward Aldehydes and Ketones

Sufang Chen, Dandan Yan, Mingqiang Xue, Yubiao Hong, Yingming Yao and Qi Shen

Org. Lett., 2017, 19, 3382
DOI: 10.1021/acs.orglett.7b01335

Bulky guanidinate stabilized homoleptic magnesium, calcium and zinc complexes and their catalytic activity in the Tishchenko reaction

Milan Kr Barman, Ashim Baishya and Sharanappa Nembenna

Journal of Organometallic Chemistry, 2015, 785, 52
DOI: 10.1016/j.jorganchem.2015.02.044

Base‐Free Palladium‐Catalyzed Hydrodechlorination of Aryl Chlorides with Pinacol Borane

Yutaro Yamamoto, Keisuke Nogi, Hideki Yorimitsu and Atsuhiro Osuka

ChemistrySelect, 2017, 2, 1723
DOI: 10.1002/slct.201700189

Catalytic Hydroboration of Aldehydes, Ketones, and Alkenes Using Potassium Carbonate: A Small Key to Big Transformation

Da Hun Ma, Ashok Kumar Jaladi, Ji Hye Lee, Tae Sung Kim, Won Kyu Shin, Hyonseok Hwang and Duk Keun An

ACS Omega, 2019, 4, 15893
DOI: 10.1021/acsomega.9b01877

Aluminum-Catalyzed Selective Hydroboration of Alkenes and Alkynylsilanes

Feng Li, Xu Bai, Yuan Cai, Han Li, Shuo-Qing Zhang, Feng-Hua Liu, Xin Hong, Youjun Xu and Shi-Liang Shi

Org. Process Res. Dev., 2019, 23, 1703
DOI: 10.1021/acs.oprd.9b00205

Hydrido Complexes of Calcium: A New Family of Molecular Alkaline‐Earth‐Metal Compounds

Debabrata Mukherjee, Danny Schuhknecht and Jun Okuda

Angew Chem Int Ed, 2018, 57, 9590
DOI: 10.1002/anie.201801869

Nucleophilic Addition and α-C–H Substitution Reactions of an Imine Mediated by Dibutylmagnesium and Organolithium Reagents

Yan Dang, Yalan Wang, Yafei Li, Man Xu, Chaohong Jia, Yanhua Lu, Liang Zhang, Yahong Li and Yuanzhi Xia

Organometallics, 2021, 40, 1830
DOI: 10.1021/acs.organomet.0c00815

Hydrosilylation of Olefins Catalyzed by Well-Defined Cationic Aluminum Complexes: Lewis Acid versus Insertion Mechanisms

Kayla Jakobsson, Terry Chu and Georgii I. Nikonov

ACS Catal., 2016, 6, 7350
DOI: 10.1021/acscatal.6b01694

1,2-Hydroboration of Pyridines by Organomagnesium

Xinli Liu, Bingwen Li, Xiufang Hua and Dongmei Cui

Org. Lett., 2020, 22, 4960
DOI: 10.1021/acs.orglett.0c01388

Silyl Anion Initiated Hydroboration of Aldehydes and Ketones

Martin W. Stanford, Alessandro Bismuto and Michael J. Cowley

Chemistry A European J, 2020, 26, 9855
DOI: 10.1002/chem.202000897

Ligand Influence on Carbonyl Hydroboration Catalysis by Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M=Li, Na, K)

Hassan Osseili, Debabrata Mukherjee, Thomas P. Spaniol and Jun Okuda

Chemistry A European J, 2017, 23, 14292
DOI: 10.1002/chem.201702818

Catalytic Hydroboration of Organic Nitriles Promoted by Aluminum Complex

Adimulam Harinath, Jayeeta Bhattacharjee and Tarun K. Panda

Adv Synth Catal, 2019, 361, 850
DOI: 10.1002/adsc.201801252

s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds

Marc Magre, Marcin Szewczyk and Magnus Rueping

Chem. Rev., 2022, 122, 8261
DOI: 10.1021/acs.chemrev.1c00641

ChemInform Abstract: Magnesium‐Catalyzed Hydroboration of Aldehydes and Ketones.

Merle Arrowsmith, Terrance J. Hadlington, Michael S. Hill and Gabriele Kociok‐Koehn

ChemInform, 2012, 43
DOI: 10.1002/chin.201235035

Expanding the Scope of BICAAC Organocatalyst: Hydroboration of Carbonyl and Alkyne Substrates

Alisha Sharma, Surbhi Bansal, Archana Velloth, Sugumar Venkataramani and Sanjay Singh

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501880

Nucleophilic Magnesium Silanide and Silaamidinate Derivatives

Bibian Okokhere-Edeghoghon, Maximilian Dehmel, Michael S. Hill, Robert Kretschmer, Mary F. Mahon, Claire L. McMullin, Louis J. Morris and Nasir A. Rajabi

Inorg. Chem., 2020, 59, 13679
DOI: 10.1021/acs.inorgchem.0c02034

Mononuclear Three-Coordinate Magnesium Complexes of a Highly Sterically Encumbered β-Diketiminate Ligand

Merle Arrowsmith, Brant Maitland, Gabriele Kociok-Köhn, Andreas Stasch, Cameron Jones and Michael S. Hill

Inorg. Chem., 2014, 53, 10543
DOI: 10.1021/ic501638v

Magnesium-Promoted Selectively Reduction of Unprotected Indoles and Quinoxalines

Nana Wei, Wanzhen Guo, Xing Lu, Zhiqiang Ren, Haojie Ma, Yuqi Zhang, Jijiang Wang and Bo Han

Chinese Journal of Organic Chemistry, 2026, 46, 1027
DOI: 10.6023/cjoc202508021

Alkaline Earth Metal Compounds of Methylpyridinato β-Diketiminate Ligands and Their Catalytic Application in Hydroboration of Aldehydes and Ketones

Sandeep Yadav, Ruchi Dixit, Milan Kumar Bisai, Kumar Vanka and Sakya S. Sen

Organometallics, 2018, 37, 4576
DOI: 10.1021/acs.organomet.8b00568

Heterobimetallic s‐Block Hydrides by σ‐Bond Metathesis

David J. Liptrot, Michael S. Hill and Mary F. Mahon

Chemistry A European J, 2014, 20, 9871
DOI: 10.1002/chem.201403215

Aluminum Hydrides Stabilized by N‐Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane

Daniel Franz, Lorenz Sirtl, Alexander Pöthig and Shigeyoshi Inoue

Zeitschrift anorg allge chemie, 2016, 642, 1245
DOI: 10.1002/zaac.201600313

Aluminum Hydride Catalyzed Hydroboration of Alkynes

Alessandro Bismuto, Stephen P. Thomas and Michael J. Cowley

Angewandte Chemie, 2016, 128, 15582
DOI: 10.1002/ange.201609690

Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis

Bhupendra Goswami, Thomas J. Feuerstein, Ravi Yadav, Ralf Köppe, Sergei Lebedkin, Manfred M. Kappes and Peter W. Roesky

Chemistry A European J, 2021, 27, 4401
DOI: 10.1002/chem.202004833

Heterocyclic Carbene‐Catalyzed Hydride Transfer in the Hydroboration of Carbonyl Compounds

Tianhao Li, Jianying Zhang and Chunming Cui

Chin. J. Chem., 2019, 37, 679
DOI: 10.1002/cjoc.201900139

Grignard reagents-catalyzed hydroboration of aldehydes and ketones

Weifan Wang, Kai Lu, Yi Qin, Weiwei Yao, Dandan Yuan, Sumod A. Pullarkat, Li Xu and Mengtao Ma

Tetrahedron, 2020, 76, 131145
DOI: 10.1016/j.tet.2020.131145

Crystallographic Characterisation of Organolithium and Organomagnesium Intermediates in Reactions of Aldehydes and Ketones

Jennifer R. Lynch, Alan R. Kennedy, Jim Barker, Jacqueline Reid and Robert E. Mulvey

Helvetica Chimica Acta, 2022, 105
DOI: 10.1002/hlca.202200082

Determination of the Mechanism and True Catalyst in CO2 Hydroboration Catalyzed by the Low-Valent Magnesium(I) Dimer: A Computational Study

Lin Yang, Zhendong Li and Xiaoyan Li

J. Phys. Chem. A, 2026, 130, 2061
DOI: 10.1021/acs.jpca.5c07854

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes

Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping

Angew Chem Int Ed, 2019, 58, 7025
DOI: 10.1002/anie.201902188

Molecular Magnesium Hydrides

Debabrata Mukherjee and Jun Okuda

Angew Chem Int Ed, 2018, 57, 1458
DOI: 10.1002/anie.201708592

Synthesis, characterization and reactivity of a neutral antimony(III) complex

Xiong Sun and Congqing Zhu

Chinese Chemical Letters, 2021, 32, 717
DOI: 10.1016/j.cclet.2020.07.006

Lanthanide aryloxides catalyzed hydroboration of aldehydes and ketones

Zhangye Zhu, Ping Dai, Zhenjie Wu, Mingqiang Xue, Yingming Yao, Qi Shen and Xiaoguang Bao

Catalysis Communications, 2018, 112, 26
DOI: 10.1016/j.catcom.2018.04.014

Regioselective Ring Opening Reactions of Pyridine N-Oxide Analogues by Magnesium Hydride Complexes

Hongyan Xie, Xinli Liu and Dongmei Cui

Organometallics, 2017, 36, 3597
DOI: 10.1021/acs.organomet.7b00517

Role of Alkaline-Earth Metal-Catalyst: A Theoretical Study of Pyridines Hydroboration

Yuanyuan Li, Meijun Wu, Haohua Chen, Dongdong Xu, Lingbo Qu, Jing Zhang, Ruopeng Bai and Yu Lan

Front. Chem., 2019, 7
DOI: 10.3389/fchem.2019.00149

Efficient and selective carbonyl hydroboration catalyzed by a lithium NCN-Pincer magnesiate complex [Li(THF)4][NCN-MgBr2]

Man Luo, Jia Li, Qian Xiao, Shilong Yang, Fan Su and Mengtao Ma

Journal of Organometallic Chemistry, 2018, 868, 31
DOI: 10.1016/j.jorganchem.2018.04.040

Monomeric Magnesium Catalyzed Alkene and Alkyne Hydroboration

Rohit Kumar, Sayan Dutta, Vishal Sharma, Praval P. Singh, Rajesh G. Gonnade, Debasis Koley and Sakya S. Sen

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201896

Nickel(II) Catalyzed Hydroboration: A Route to Selective Reduction of Aldehydes and N‐Allylimines

Istiak Hossain and Joseph A. R. Schmidt

Eur J Inorg Chem, 2020, 2020, 1877
DOI: 10.1002/ejic.202000092

Heteroleptic Magnesium n-Butyl on a Chemically Non-innocent 2-Anilidomethylpyridine Ligand Leading to Diverse Magnesium Hydrides

Chhotan Mandal, Shalini Joshi, Sabyashachi Mishra and Debabrata Mukherjee

Inorg. Chem., 2024, 63, 15692
DOI: 10.1021/acs.inorgchem.4c01612

Catalyst-Free Approach for Hydroboration of Carboxylic Acids under Mild Conditions

Xiaojuan Xu, Dandan Yan, Zhangye Zhu, Zihan Kang, Yingming Yao, Qi Shen and Mingqiang Xue

ACS Omega, 2019, 4, 6775
DOI: 10.1021/acsomega.9b00406

Supported Single-Site Ti(IV) on a Metal–Organic Framework for the Hydroboration of Carbonyl Compounds

Zhiyuan Huang, Dong Liu, Jeffrey Camacho-Bunquin, Guanghui Zhang, Dali Yang, Juan M. López-Encarnación, Yunjie Xu, Magali S. Ferrandon, Jens Niklas, Oleg G. Poluektov, Julius Jellinek, Aiwen Lei, Emilio E. Bunel and Massimiliano Delferro

Organometallics, 2017, 36, 3921
DOI: 10.1021/acs.organomet.7b00544

Pincer‐Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide

Lingyu Liu, Siu‐Kwan Lo, Cory Smith and Jose M. Goicoechea

Chemistry A European J, 2021, 27, 17379
DOI: 10.1002/chem.202103009

Magnesium‐Mediated Cyanosilylation and Hydroboration of Arene and N‐Heteroarene Aldehydes: An Experimental and Theoretical Study

Darakshan Parveen, Sougata Saha, Rahul Kumar Yadav, Swapan K. Pati and Dipak Kumar Roy

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401853

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

Ross McLellan, Alan R. Kennedy, Samantha A. Orr, Stuart D. Robertson and Robert E. Mulvey

Angewandte Chemie, 2017, 129, 1056
DOI: 10.1002/ange.201610905

N-Heterocyclic Germylene and Stannylene Catalyzed Cyanosilylation and Hydroboration of Aldehydes

Rajarshi Dasgupta, Shubhajit Das, Shweta Hiwase, Swapan K. Pati and Shabana Khan

Organometallics, 2019, 38, 1429
DOI: 10.1021/acs.organomet.8b00673

Iron-borane catalyzed carbonyl hydroboration and isolation of an iron(I)-ketyl radical

Laura A. Grose, Ryan J. Schwamm, Adam Brookfield, David Robinson and Darren Willcox

Nat Commun, 2026, 17
DOI: 10.1038/s41467-026-69500-2

Magnesium‐Catalyzed Tandem Dehydrogenation‐Dehydrocoupling: An Atom Economical Access to Alkynylboranes

Mélodie Birepinte, Virginie Liautard, Laurent Chabaud and Mathieu Pucheault

Chemistry A European J, 2020, 26, 3236
DOI: 10.1002/chem.201905772

Lithium tert‐Butoxide‐catalyzed Hydroboration of Carbonyl Compounds

Jea Ho Kim, Ashok Kumar Jaladi, Hyun Tae Kim and Duk Keun An

Bulletin Korean Chem Soc, 2019, 40, 971
DOI: 10.1002/bkcs.11855

N-Heterocyclic Carbene-Supported Aryl- and Alk- oxides of Beryllium and Magnesium

Jacob E. Walley, Yuen-Onn Wong, Lucas A. Freeman, Diane A. Dickie and Robert J. Gilliard

Catalysts, 2019, 9, 934
DOI: 10.3390/catal9110934

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage

Smita Patnaik and Aaron D. Sadow

Angewandte Chemie, 2019, 131, 2527
DOI: 10.1002/ange.201813305

N-Heterocyclic Carbene–Carbodiimide (“NHC–CDI”) Adduct or Zwitterionic-Type Neutral Amidinate-Supported Magnesium(II) and Zinc(II) Complexes

Ashim Baishya, Lokesh Kumar, Milan Kr. Barman, Himansu S. Biswal and Sharanappa Nembenna

Inorg. Chem., 2017, 56, 9535
DOI: 10.1021/acs.inorgchem.7b00879

A Uranium(IV) Alkyl Complex: Synthesis and Catalytic Property in Carbonyl Hydroboration

Xiong Sun, Xingxing Gong, Zhuoyi Xie and Congqing Zhu

Chin. J. Chem., 2022, 40, 2047
DOI: 10.1002/cjoc.202200176

Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs

Julia Schneider, Christian P. Sindlinger, Sarah M. Freitag, Hartmut Schubert and Lars Wesemann

Angew Chem Int Ed, 2017, 56, 333
DOI: 10.1002/anie.201609155

Efficient and Selective Iron-Complex-Catalyzed Hydroboration of Aldehydes

Uttam K. Das, Carolyn S. Higman, Bulat Gabidullin, Jason E. Hein and R. Tom Baker

ACS Catal., 2018, 8, 1076
DOI: 10.1021/acscatal.7b03785

Multimetallic Alkaline-Earth Hydride Cations

Lucia Garcia, Mary F. Mahon and Michael S. Hill

Organometallics, 2019, 38, 3778
DOI: 10.1021/acs.organomet.9b00493

Bimetallic Bis-anion Cascade Complexes of Magnesium in Nonaqueous Solution

David Van Craen, Ian G. Flynn, Veronica Carta and Amar H. Flood

Inorg. Chem., 2020, 59, 5939
DOI: 10.1021/acs.inorgchem.9b03710

Solubility of mono-alkyl magnesium complex in pure and binary solvents: Measurement, correlation, thermodynamics from 268.15 K to 318.15 K

Jin Li, Xiaoli Ma, Yangfan Peng, Xing He, Zonggang Du and Zhi Yang

Journal of Molecular Liquids, 2021, 337, 116423
DOI: 10.1016/j.molliq.2021.116423

Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration

Debabrata Mukherjee, Hassan Osseili, Thomas P. Spaniol and Jun Okuda

J. Am. Chem. Soc., 2016, 138, 10790
DOI: 10.1021/jacs.6b06319

Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs

Julia Schneider, Christian P. Sindlinger, Sarah M. Freitag, Hartmut Schubert and Lars Wesemann

Angewandte Chemie, 2017, 129, 339
DOI: 10.1002/ange.201609155

Recent Advances in Aluminum Compounds for Catalysis

Congjian Ni, Xiaoli Ma, Zhi Yang and Herbert W. Roesky

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100929

Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium–Hydrogen Bond

Silvia Schnitzler, Thomas P. Spaniol and Jun Okuda

Inorg. Chem., 2016, 55, 12997
DOI: 10.1021/acs.inorgchem.6b02509

Transforming Hydroxide-Containing Metal–Organic Framework Nodes for Transition Metal Catalysis

Xuanyu Feng, Yang Song and Wenbin Lin

Trends in Chemistry, 2020, 2, 965
DOI: 10.1016/j.trechm.2020.08.009

Iron Catalyzed Hydroboration of Aldehydes and Ketones

Sem Raj Tamang and Michael Findlater

J. Org. Chem., 2017, 82, 12857
DOI: 10.1021/acs.joc.7b02020

Copper(II)-Catalyzed Selective Hydroboration of Ketones and Aldehydes

Haisu Zeng, Jing Wu, Sihan Li, Christina Hui, Anita Ta, Shu-Yuan Cheng, Shengping Zheng and Guoqi Zhang

Org. Lett., 2019, 21, 401
DOI: 10.1021/acs.orglett.8b03583

Catalytic hydrogenation of acetone to isopropyl alcohol with CAl3MgH2¯ containing planar tetracoordinate carbon

Abdul Hamid Malhan and Krishnan Thirumoorthy

Front. Chem., 2026, 13
DOI: 10.3389/fchem.2025.1750798

Magnesium Catalysis for the Hydroboration of Carbodiimides

Catherine Weetman, Michael S. Hill and Mary F. Mahon

Chemistry A European J, 2016, 22, 7158
DOI: 10.1002/chem.201600681

Methanediide Formation via Hydrogen Elimination in Magnesium versus Aluminium Hydride Complexes of a Sterically Demanding Bis(iminophosphoranyl)methanediide

Christian Sindlinger, Samuel Lawrence, David Cordes, Alexandra Slawin and Andreas Stasch

Inorganics, 2017, 5, 29
DOI: 10.3390/inorganics5020029

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes

Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping

Angewandte Chemie, 2019, 131, 7099
DOI: 10.1002/ange.201902188

Aluminum Hydride Catalyzed Hydroboration of Alkynes

Alessandro Bismuto, Stephen P. Thomas and Michael J. Cowley

Angew Chem Int Ed, 2016, 55, 15356
DOI: 10.1002/anie.201609690

[(Me6TREN)MgOCHPh2][B(C6F5)4]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

Ankur, Ramkumar Kannan, Raju Chambenahalli, Sumanta Banerjee, Yan Yang, Laurent Maron and Ajay Venugopal

Eur J Inorg Chem, 2021, 2021, 4632
DOI: 10.1002/ejic.202100651

Catalytic hydrogenation of alkyne with planar tetracoordinate carbon in CAl3MgH2¯ system

Abdul Hamid Malhan and Krishnan Thirumoorthy

Front. Chem., 2025, 13
DOI: 10.3389/fchem.2025.1672968

Two Carbenes versus One in Magnesium Chemistry: Synthesis of Terminal Dihalide, Dialkyl, and Grignard Reagents

Yuen Onn Wong, Lucas A. Freeman, A. Danai Agakidou, Diane A. Dickie, Charles Edwin Webster and Robert J. Gilliard

Organometallics, 2019, 38, 688
DOI: 10.1021/acs.organomet.8b00866

Magnesium Catalysis of Imine Hydroboration

Merle Arrowsmith, Michael S. Hill and Gabriele Kociok‐Köhn

Chemistry A European J, 2013, 19, 2776
DOI: 10.1002/chem.201203190

P–N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform

Yi-Chun Lin, Emmanuel Hatzakis, Sean M. McCarthy, Kyle D. Reichl, Ting-Yi Lai, Hemant P. Yennawar and Alexander T. Radosevich

J. Am. Chem. Soc., 2017, 139, 6008
DOI: 10.1021/jacs.7b02512

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis

Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping

Angew Chem Int Ed, 2019, 58, 17567
DOI: 10.1002/anie.201908012

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis

Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping

Angewandte Chemie, 2019, 131, 17731
DOI: 10.1002/ange.201908012

Aluminum Monohydride Catalyzed Selective Hydroboration of Carbonyl Compounds

Vineet Kumar Jakhar, Milan Kr. Barman and Sharanappa Nembenna

Org. Lett., 2016, 18, 4710
DOI: 10.1021/acs.orglett.6b02310

Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds

Che Chang Chong, Hajime Hirao and Rei Kinjo

Angewandte Chemie, 2015, 127, 192
DOI: 10.1002/ange.201408760

n‐Butyllithium (1 mol %)‐catalyzed Hydroboration of Aldehydes and Ketones with Pinacolborane

Su Jin Yang, Ashok Kumar Jaladi, Jea Ho Kim, Shankaraiah Gundeti and Duk Keun An

Bulletin Korean Chem Soc, 2019, 40, 34
DOI: 10.1002/bkcs.11635

A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration

Jacob B. Geri and Nathaniel K. Szymczak

J. Am. Chem. Soc., 2015, 137, 12808
DOI: 10.1021/jacs.5b08406

Molekulare Magnesiumhydride

Debabrata Mukherjee and Jun Okuda

Angewandte Chemie, 2018, 130, 1472
DOI: 10.1002/ange.201708592

Recent developments in the reduction of unsaturated bonds by magnesium precursors

Indrani Banerjee and Tarun K. Panda

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6333