Issue 77, 2022
From the journal:

Chemical Communications

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation†

Anuja Sharma, ORCID logo a   Sangho So, ORCID logo bc   Jun-Hyeong Kim, ORCID logo bc   Samantha N. MacMillan, ORCID logo d   Mu-Hyun Baik ORCID logo *bc  and  Ryan J. Trovitch ORCID logo *a  

* Corresponding authors

a School of Molecular Sciences, Arizona State University, Tempe, Arizona 85287, USA
E-mail: ryan.trovitch@asu.edu

b Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

c Center for Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea

d Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA

Abstract

Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

Graphical abstract: An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

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Article information

DOI
https://doi.org/10.1039/D2CC04089A
Article type
Communication
Submitted
22 Uzt. 2022
Accepted
24 Abu. 2022
First published
24 Abu. 2022

Chem. Commun., 2022,58, 10793-10796

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An aryl diimine cobalt(I) catalyst for carbonyl hydrosilylation

A. Sharma, S. So, J. Kim, S. N. MacMillan, M. Baik and R. J. Trovitch, Chem. Commun., 2022, 58, 10793 DOI: 10.1039/D2CC04089A

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