Issue 100, 2021

Nickel-catalyzed synthesis of Zn(i)–Zn(i) bonded compounds

Abstract

This work reports the first catalyzed synthesis of d-block metal–metal bonded complexes. The treatment of terminal zinc hydrides [LZnH] [L = CH3C(2,6-iPr2C6H3N)CHC(CH3)(N(CH2)nCH2PR2); n = 1, 2; R = Ph, iPr] in the presence of 5 mol% Ni(CO)2(PPh3)2 afforded Zn(I)–Zn(I) bonded compounds [L2Zn2] in high isolated yields with concomitant elimination of dihydrogen. Stoichiometric reactions, kinetic studies and DFT calculations were conducted to elucidate the reaction mechanism.

Graphical abstract: Nickel-catalyzed synthesis of Zn(i)–Zn(i) bonded compounds

Supplementary files

Article information

Article type
Communication
Submitted
10 Urr. 2021
Accepted
15 Aza. 2021
First published
16 Aza. 2021

Chem. Commun., 2021,57, 13696-13699

Nickel-catalyzed synthesis of Zn(I)–Zn(I) bonded compounds

S. Jiang, Y. Cai, A. Carpentier, I. del Rosal, L. Maron and X. Xu, Chem. Commun., 2021, 57, 13696 DOI: 10.1039/D1CC05719G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements