Issue 77, 2022

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Abstract

Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

Graphical abstract: An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Supplementary files

Article information

Article type
Communication
Submitted
22 Uzt. 2022
Accepted
24 Abu. 2022
First published
24 Abu. 2022

Chem. Commun., 2022,58, 10793-10796

Author version available

An aryl diimine cobalt(I) catalyst for carbonyl hydrosilylation

A. Sharma, S. So, J. Kim, S. N. MacMillan, M. Baik and R. J. Trovitch, Chem. Commun., 2022, 58, 10793 DOI: 10.1039/D2CC04089A

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