Biocatalytic reductive aminations with NAD(P)H-dependent enzymes: enzyme discovery, engineering and synthetic applications

Abstract

This review summarized NAD(P)H-dependent amine dehydrogenases and imine reductases which catalyzes asymmetric reductive amination to produce optically active amines.

Enhancing photocatalytic CO₂ reduction to formate through one-pot self-assembly of a semiartificial cell

Abstract

A semiartificial cell constructed by one-pot self-assembly is designed to enables the enzyme to adopt an activated conformation with high activity and promotes the electron transport efficiency from the photo-antennas to FDH.

Boosting the photocatalytic CO₂ conversion efficiency of MOFs using a solid electron conveyor

Abstract

A semiartificial photosynthesis system containing a solid electron hyperchannel to cavity-confined enzymes with an activated conformation is constructed for enhanced photocatalytic CO₂ reduction.

Crystallization-based downstream processing of ω-transaminase- and amine dehydrogenase-catalyzed reactions

Abstract

This study highlights the use of selective crystallization as a downstream-processing concept for amine products from biocatalytic reactions.

Engineered enzymatic cascade converts diols to amino alcohols

Abstract

Aliphatic amino alcohols such as 6-amino-1-hexanol are potential platform chemicals for a variety of advanced materials. Selective enzymatic synthesis from biomass-derived diols could simplify production while minimizing hazards.

Chapter 22
Valorisation of Carbon Dioxide via Enzymatic Transformation