[RbSr3X][(BS3)2] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

Yihan Yun, Xueling Hou, Zhihua Yang, Guangmao Li and Shilie Pan

Chem. Commun., 2024, 60, 118
DOI: 10.1039/D3CC05205B

Na2B12Si6Se18: a novel B12-cluster-containing quaternary selenoborate framework material

Gopabandhu Panigrahi, Hunter B. Tisdale, Gregory Morrison and Hans-Conrad zur Loye

Dalton Trans., 2025, 54, 1956
DOI: 10.1039/D4DT03139C

MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra

Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li and Feng Yu

Dalton Trans., 2023, 52, 11401
DOI: 10.1039/D3DT01496G

LaBS3 revisited: a promising mid-infrared nonlinear optical material

Ya-Xiang Han, Chun-Li Hu, Zhi Fang, Qian-Qian Chen, Bing-Xuan Li, Yuan Lin and Jiang-Gao Mao

J. Mater. Chem. C, 2022, 10, 12556
DOI: 10.1039/D2TC02699F

Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

Ping Feng, Jia-Xiang Zhang, Mao-Yin Ran, Xin-Tao Wu, Hua Lin and Qi-Long Zhu

Chem. Sci., 2024, 15, 5869
DOI: 10.1039/D4SC00697F

An overview of Mg-based IR nonlinear optical materials

Jia-Xiang Zhang, Mao-Yin Ran, Xin-Tao Wu, Hua Lin and Qi-Long Zhu

Inorg. Chem. Front., 2023, 10, 5244
DOI: 10.1039/D3QI01144E

Selenoborates: a latent structure resource for infrared functional crystal materials

Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li and Shilie Pan

Inorg. Chem. Front., 2025, 12, 2182
DOI: 10.1039/D4QI02770A

Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

Bo Zhang, Mao-Yin Ran, Xin-Tao Wu, Hua Lin and Qi-Long Zhu

Coordination Chemistry Reviews, 2024, 517, 216053
DOI: 10.1016/j.ccr.2024.216053

Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey and Chi Zhang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202318107

Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey and Chi Zhang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202318107

AIB3IIC2IIIQ6VIXVII: A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS3] and Polycations

Jiazheng Zhou, Ketian Hou, Yu Chu, Zhihua Yang, Junjie Li and Shilie Pan

Small, 2024, 20
DOI: 10.1002/smll.202308806

Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li and Shilie Pan

Advanced Optical Materials, 2023, 11
DOI: 10.1002/adom.202300256

Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties

Adam A. King, Logan S. Breton, Gregory Morrison, Mark D. Smith and Hans-Conrad zur Loye

Inorg. Chem., 2023, 62, 18172
DOI: 10.1021/acs.inorgchem.3c02639

NaREP2Se6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP2Se6]−}∞ Framework Built by RESe8 and P2Se6 Motifs and Multiple Properties

Chen-Yi Zhao, Zi-Xia Chen, Wen-Dong Yao, Wenfeng Zhou, Wenlong Liu and Sheng-Ping Guo

Inorg. Chem., 2023, 62, 19843
DOI: 10.1021/acs.inorgchem.3c03695

Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications

Anna A. Berseneva and Hans-Conrad zur Loye

Crystal Growth & Design, 2023, 23, 5368
DOI: 10.1021/acs.cgd.3c00573

Rare Bird: U+5 in Uranium Chalcogenides

Anna A. Berseneva, Vladislav V. Klepov, Habiba B. Kashem, Alevtina A. Maksimova, Gregory Morrison, Joshua Wright, Joseph Schaeperkoetter, Scott T. Misture and Hans-Conrad zur Loye

Chem. Mater., 2024
DOI: 10.1021/acs.chemmater.4c01440

Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

He-Di Yang, Mao-Yin Ran, Wen-Bo Wei, Xin-Tao Wu, Hua Lin and Qi-Long Zhu

Materials Today Physics, 2023, 35, 101127
DOI: 10.1016/j.mtphys.2023.101127

Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method

Adam A. King, Logan S. Breton, Greg Morrison, Mark D. Smith, Mingli Liang, P. Shiv Halasyamani and Hans-Conrad zur Loye

Inorg. Chem., 2023, 62, 7446
DOI: 10.1021/acs.inorgchem.3c00708

Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

Gopabandhu Panigrahi, Gregory Morrison, Mark D. Smith and Hans-Conrad zur Loye

Inorg. Chem., 2024, 63, 23802
DOI: 10.1021/acs.inorgchem.4c03987

Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides

Linfeng Dong, Shengzi Zhang, Pifu Gong, Lei Kang and Zheshuai Lin

Coordination Chemistry Reviews, 2024, 509, 215805
DOI: 10.1016/j.ccr.2024.215805

Synergistic Machine Learning Guided Discovery of ABa3(BSe3)2X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials

Yihan Yun, Mengfan Wu, Zhihua Yang, Guangmao Li and Shilie Pan

Advanced Science, 2025, 12
DOI: 10.1002/advs.202417851