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Organocatalytic (5+1) benzannulation of Morita–Baylis–Hillman carbonates: synthesis of multisubstituted 4-benzylidene pyrazolones

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Catalytic asymmetric synthesis of 3,4′-indole–pyrazole derivatives featuring axially chiral bis-pentatomic heteroaryls

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Org. Chem. Front., 2022, 9, 1808
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Enantioselective cross-dehydrogenative coupling enabled by organocatalysis

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Green Chem., 2024, 26, 1846
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Organocatalytic enantioselective construction of axially chiral (1H)-isochromen-1-imines

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Recent advancements in the Ullmann homocoupling reaction for the synthesis of biaryl compounds

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Org. Biomol. Chem., 2025
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Catalytic atroposelective electrophilic amination of diaryl anilines and diaryl phenols for the synthesis of axially chiral diaryl compounds

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Synthesis of axially chiral N-aryl benzimidazoles via chiral phosphoric acid catalyzed enantioselective oxidative aromatization

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Catalytically atroposelective ring-opening of configurationally labile compounds to access axially chiral biaryls

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Org. Chem. Front., 2022, 9, 4507
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Catalytic Atroposelective Synthesis of Axially Chiral Azomethine Imines and Neuroprotective Activity Evaluation

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Angew Chem Int Ed, 2024, 63
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Modular Construction of Heterobiaryl Atropisomers and Axially Chiral Styrenes via All‐Carbon Tetrasubstituted VQMs

Bo‐Bo Gou, Yue Tang, Yan‐Hong Lin, Le Yu, Qing‐Song Jian, Huai‐Ri Sun, Jie Chen and Ling Zhou

Angewandte Chemie, 2022, 134
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Construction of CF3-Functionalized Fully Substituted Benzonitriles through Rauhut–Currier Reaction Initiated [3 + 3] Benzannulation

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J. Org. Chem., 2021, 86, 14844
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Synthetic Strategies to Control C–N Atropisomerism in Acyclic Amines and Amides

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Synthesis, 2023, 55, 2427
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Catalytic Atroposelective Synthesis of Axially Chiral Azomethine Imines and Neuroprotective Activity Evaluation

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Angewandte Chemie, 2024, 136
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Atroposelective Synthesis of C–C Axially Chiral Compounds via Mono- and Dinuclear Vanadium Catalysis

Ankit Kumar, Hiroaki Sasai and Shinobu Takizawa

Acc. Chem. Res., 2022, 55, 2949
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The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers

Shao-Hua Xiang, Jun Kee Cheng and Bin Tan

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Atroposelective Synthesis of Heterobiaryls through Ring Formation

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Chemistry A European J, 2023, 29
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N‐Heterocyclic carbene‐catalyzed Atroposelective Annulation for Access to Pyrrolo[3,4‐b]pyridines Derivatives with C−N Axial Chirality

Yanting Li, Xiao‐Yong Duan, Yamei Wei, Jiahan Li, Xiaojie Ren and Jing Qi

Asian J Org Chem, 2022, 11
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Dynamic Kinetic Resolution of 2‐(Quinolin‐8‐yl)Benzaldehydes: Atroposelective Iridium‐Catalyzed Transfer Hydrogenative Allylation

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Angewandte Chemie, 2023, 135
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Synthesis and Characterizations of 5,5′‐Bibenzo[rst]pentaphene with Axial Chirality and Symmetry‐Breaking Charge Transfer

Xiushang Xu, Suman Gunasekaran, Scott Renken, Lorenzo Ripani, Dieter Schollmeyer, Woojae Kim, Massimo Marcaccio, Andrew Musser and Akimitsu Narita

Advanced Science, 2022, 9
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Asymmetric Cycloaddition Reactions of Aryne Intermediates with a Chiral Carbon–Carbon Axis: Syntheses of Axially Chiral Biaryl Compounds

Tomoyuki Yoshimura, Ken-ichi Onda and Jun-ichi Matsuo

Org. Lett., 2023, 25, 8952
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Organocatalytic dynamic kinetic resolution of N-arylindole lactams: atroposelective construction of axially chiral amino acids bearing a C-N chiral axis

Xianfang Hong, Jingcheng Guo, Jinhua Liu, Wei Cao, Chenlong Wei, Ye Zhang, Xiaoxiang Zhang and Zhenqian Fu

Sci. China Chem., 2022, 65, 905
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Copper-Catalyzed Asymmetric Ring-Opening Reaction of Cyclic Diaryliodonium Salts with Imides

Fu Cheng, Dong-Sen Duan, Li-Ming Jiang, Bao-Sheng Li, Jia-Xuan Wang, Yu-Jia Zhou, He-Yu Jiao, Tao Wu, Dao-Yong Zhu and Shao-Hua Wang

Org. Lett., 2022, 24, 1394
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Catalytic Enantioselectivede novoConstruction of Chiral Arenes through Desymmetrizing Oxidative [4+2]‐Cycloaddition

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Angew Chem Int Ed, 2022, 61
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Catalytic Atroposelective Electrophilic Amination to Access Axially Chiral Diaryl Phenols

Ying Shao, Han Wang, Qiang Chen, Shengbiao Tang and Jiangtao Sun

Chemistry An Asian Journal, 2025
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Dynamic Kinetic Resolution of 2‐(Quinolin‐8‐yl)Benzaldehydes: Atroposelective Iridium‐Catalyzed Transfer Hydrogenative Allylation

José A. Carmona, Patricia Rodríguez‐Salamanca, Rosario Fernández, José M. Lassaletta and Valentín Hornillos

Angew Chem Int Ed, 2023, 62
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Lewis Acid‐Base Interactions as a Racemization Strategy for the Atroposelective Synthesis of (Hetero)biaryls via Dynamic Kinetic Resolution

José A. Carmona, Carlos Rodríguez‐Franco, Rosario Fernández, José M. Lassaletta and Valentín Hornillos

ChemCatChem, 2024, 16
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Biocatalytic Atroposelective Synthesis of Axially Chiral N-Arylindoles via Dynamic Kinetic Resolution

Patricia Rodríguez-Salamanca, Gonzalo de Gonzalo, José A. Carmona, Joaquín López-Serrano, Javier Iglesias-Sigüenza, Rosario Fernández, José M. Lassaletta and Valentín Hornillos

ACS Catal., 2023, 13, 659
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[RhCp*Cl2]2-Catalyzed Indole Functionalization: Synthesis of Bioinspired Indole-Fused Polycycles

Amar Nath Singh Chauhan, Ghanshyam Mali, Garima Dua, Priya Samant, Akhilesh Kumar and Rohan D. Erande

ACS Omega, 2023, 8, 27894
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Organocatalytic Atroposelective Cross-Coupling of 2-Naphthols with Diaryliodonium Salts

Sushree Ranjan Sahoo and Vinod K. Singh

Org. Lett., 2025, 27, 4085
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Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid

Dmitry A. Gruzdev, Angelina A. Telegina, Marina A. Ezhikova, Mikhail I. Kodess, Galina L. Levit and Victor P. Krasnov

Molecules, 2024, 29, 4487
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Catalytic Enantioselectivede novoConstruction of Chiral Arenes through Desymmetrizing Oxidative [4+2]‐Cycloaddition

Biki Ghosh, Mahesh Singh Harariya and Santanu Mukherjee

Angewandte Chemie, 2022, 134
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Organocatalytic Enantioselective Construction of Spiroketal Lactones Bearing Axial and Central Chirality via an Asymmetric Domino Reaction

Shiyu Xu, Aima Huang, Yang Yang, Ying Wang, Ming Zhang, Zhihui Sun, Man Zhao, Yuanlin Wei, Guofeng Li and Liang Hong

Org. Lett., 2022, 24, 2978
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Synthesis and biological evaluation of atropisomeric tetrahydroisoquinolines overcoming docetaxel resistance in triple-negative human breast cancer cells

Jayoung Song, Ahreum Kim, Intaek Hong, Sangji Kim, Woong Sub Byun, Hyun Soo Lee, Hyung Sik Kim, Sang Kook Lee and Yongseok Kwon

Bioorganic Chemistry, 2023, 137, 106573
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Asymmetric Synthesis of Axially Chiral C−N Atropisomers

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Chemistry A European J, 2022, 28
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Asymmetric reactions involving aryne intermediates

Ken Kamikawa

Nat Rev Chem, 2023, 7, 496
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Atherton–Todd Reaction-Guided Enantioselective Synthesis of Axially Chiral Olefins via Bifunctional Phosphonium Salt-Regulating Ketone-Enol Tautomerism

Siqiang Fang, Jiajia He, Zanjiao Liu, Zhishan Su, Fengyuan Guo and Tianli Wang

ACS Catal., 2023, 13, 13077
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Palladium‐Catalyzed Directed Atroposelective C−H Iodination to Synthesize Axial Chiral Biaryl N‐Oxides via Enantioselective Desymmetrization Strategy

Linxi Yao, Alemayehu Gashaw Woldegiorgis, Shaoying Huang, Yongtao Wang and Xufeng Lin

Chemistry A European J, 2023, 29
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Asymmetric synthesis of binaphthyls through photocatalytic cross-coupling and organocatalytic kinetic resolution

Heng-Hui Li, Jia-Yan Zhang, Shaoyu Li, Yong-Bin Wang, Jun Kee Cheng, Shao-Hua Xiang and Bin Tan

Sci. China Chem., 2022, 65, 1142
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Modular Construction of Heterobiaryl Atropisomers and Axially Chiral Styrenes via All‐Carbon Tetrasubstituted VQMs

Bo‐Bo Gou, Yue Tang, Yan‐Hong Lin, Le Yu, Qing‐Song Jian, Huai‐Ri Sun, Jie Chen and Ling Zhou

Angew Chem Int Ed, 2022, 61
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Ru(II)-Catalyzed Deoxygenative Formal [3 + 1 + 2] Benzannulation of Allyl Alcohols and Acetylenediesters via C–H Activation and Selective Carbon–Carbon Triple Bond Cleavage

Dattatraya H. Dethe, Amar Uike and Nagabhushana C. Beeralingappa

Org. Lett., 2024, 26, 2013
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