Issue 45, 2017

N-Heterocyclic carbene-stabilised arsinidene (AsH)

Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)3 with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)3.31][AsCO] with imidazolium chlorides.

Graphical abstract: N-Heterocyclic carbene-stabilised arsinidene (AsH)

Supplementary files

Article information

Article type
Communication
Submitted
05 apr 2017
Accepted
24 apr 2017
First published
25 apr 2017

Chem. Commun., 2017,53, 6069-6072

N-Heterocyclic carbene-stabilised arsinidene (AsH)

A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer and M. Tamm, Chem. Commun., 2017, 53, 6069 DOI: 10.1039/C7CC02628E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements