The interconversion equilibrium of coordinated NO to NO2− has been described for trinuclear ruthenium acetates for the first time. The compounds are capable to release NO in aqueous media by means of light stimulation and pH changes.
A homochiral 3D supramolecular structure was prepared through spontaneous asymmetrical crystallization using achiral precursors in the absence of any homochiral sources.
This work introduces a novel bimetallic MOF with superior endotoxin detection and enhanced catalytic activity for broader diagnostic applications.
After UV illumination at 254 nm for 10 min, the incorporated LiYGeO4:Bi3+ in the PCN-PLM can continuously provide light irradiation at 365 nm to regulate the CO2 adsorption capacity of PCN-250.
The concept of aliovalent substitution in metal–organic frameworks is critically analysed, emphasising literature examples that demonstrate the effective formation of a solid solution and clarify the nature of the charge compensation mechanism.