During the ECO2RR, the dynamic reconstruction of the mixed-valence Cu complex [CuIICl(phen)2][CuICl2] leads to exposure of Cu(I) active sites and reduces Cu–Cu distances, thereby facilitating C–C coupling.
The racemic and meso forms of 2,2′′-dibromo-1,1′′-biferrocene were prepared via the coupling of 1-bromo-2-lithioferrocene, and they were structurally characterized.
A series of versatile phthalocyanine precursors, consisting of gem-dibromovinyl phthalonitrile derivatives, were synthesized and characterized by various spectroscopic and X-ray crystallographic techniques.
Synthesis of pseudotetrahedral bis[(S or R)-N-1-(phenyl)ethyl-(2,4-dihalogen-salicylaldiminato-κ2N,O)]-Δ/Λ-nickel(II), Δ/Λ-Ni(S or R)L1–3 with Δ- or Λ-chirality induction at-metal.
This comprehensive review divulges recent advancements in the synthesis, characterization, X-ray structure, supramolecular contacts, and applications of supramolecular spodium-bonded Zn/Cd complexes with N/O/S-donor ligands.