Gianluigi Albano
Org. Chem. Front., 2024,11, 1495-1622
From themed collection:
2024 Organic Chemistry Frontiers Review-type Articles
Abstract
A general and authoritative literature overview on Pd-catalyzed cross-dehydrogenative coupling reactions of (hetero)arenes from the origins to 2023, where not only the synthetic aspects were described but also the most relevant mechanistic features.
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li and Dong Xue
Org. Chem. Front., 2024,11, 2313-2318
Abstract
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
Wei Chen, Kai Chen, Xuejie Wang, Linjie Yang and Wanzhi Chen
RSC Adv., 2024,14, 16624-16628
Abstract
Pd/NHC catalyzes the one-pot synthesis of diarylamine compounds from nitroarenes, by introducing triethylsilane as a reducing agent.
Anna Lenarda, Itisha Jain, Aleksi Kaleva, Valtteri Oksanen, Sami Heikkinen, Risto Koivula, Tom Wirtanen, Michele Melchionna, Tao Hu and Juho Helaja
Green Chem., 2026,28, 199-212
Abstract
Porous activated carbon bearing OH and C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O groups, in the presence of a molecular oxidant, catalyzes metal-free cascade synthesis of diarylamines via enamine formation and oxidative aromatization.
Junming Wang, Weiguo Xue, Zhuozheng Wang, Hao Li, Huiying Lv, Chaoliang Wei, Qingwei Kong, Xiaowei Xu, Kebin Chi, Dejun Shi, Yufeng Liu, Tuanle Li and Yi Luo
New J. Chem., 2025,49, 14851-14865
Abstract
A new catalytic antioxidation mechanism of diarylamines is proposed, highlighting a β-H transfer pathway via ROO˙ radicals, which shows that Fe(III) coordination significantly enhances radical-scavenging efficiency.