Herein, we present a room-temperature, nickel-catalyzed borylation protocol for the efficient synthesis of benzoxaboroles and benzodiazaborines.
A novel adaptive latent Bayesian optimisation (ALaBO) algorithm accelerates the development of mixed variable catalytic reactions.
A catalytic system-controlled divergent reaction was reported to construct three distinct nitrogen-containing heterocycles from readily available starting materials via a precise chemical bond activation and annulation cascade.
A palladium-catalyzed three-component annulation reaction involving multiple C–H activation has been developed, which offers a new synthetic approach for succinimide-fused tricyclic scaffolds.
The alkenylation reaction of vinylene carbonate with vinyl triflates using a Pd catalyst provides an access to 1,2-dioxygenated dienes, which undergo a tandem DA cycloaddition/decarboxylative aromatization reaction to give 2-naphthols and phenols.