Photochemical hydrogen production and cobaloximes: the influence of the cobalt axial N-ligand on the system stability

Athanassios Panagiotopoulos, Kalliopi Ladomenou, Dongyue Sun, Vincent Artero and Athanassios G. Coutsolelos

Dalton Trans., 2016, 45, 6732
DOI: 10.1039/C5DT04502A

Proton reduction to hydrogen in biological and chemical systems

Phong D. Tran and James Barber

Phys. Chem. Chem. Phys., 2012, 14, 13772
DOI: 10.1039/c2cp42413d

Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments

Marian Chatenet, Bruno G. Pollet, Dario R. Dekel, Fabio Dionigi, Jonathan Deseure, Pierre Millet, Richard D. Braatz, Martin Z. Bazant, Michael Eikerling, Iain Staffell, Paul Balcombe, Yang Shao-Horn and Helmut Schäfer

Chem. Soc. Rev., 2022, 51, 4583
DOI: 10.1039/D0CS01079K

Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes

Maria Drosou, Fotios Kamatsos and Christiana A. Mitsopoulou

Inorg. Chem. Front., 2020, 7, 37
DOI: 10.1039/C9QI01113G

Electrocatalytic proton reduction by dinuclear cobalt complexes in a nonaqueous electrolyte

Manaswini Raj and Sumanta Kumar Padhi

New J. Chem., 2022, 46, 6027
DOI: 10.1039/D1NJ06003A

Consecutive ligand-based PCET processes affording a doubly reduced nickel pyrazinedithiolate which transforms into a metal hydride required to evolve H2

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Dalton Trans., 2019, 48, 635
DOI: 10.1039/C8DT04497J

A polypyridyl Co(ii) complex-based water reduction catalyst with double H2 evolution sites

Junfei Wang, Chao Li, Qianxiong Zhou, Weibo Wang, Yuanjun Hou, Baowen Zhang and Xuesong Wang

Catal. Sci. Technol., 2016, 6, 8482
DOI: 10.1039/C6CY01897A

Cobalt, nickel, and iron complexes of 8-hydroxyquinoline-di(2-picolyl)amine for light-driven hydrogen evolution

Nadia Alessandra Carmo dos Santos, Mirco Natali, Elena Badetti, Klaus Wurst, Giulia Licini and Cristiano Zonta

Dalton Trans., 2017, 46, 16455
DOI: 10.1039/C7DT02666H

Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation

Debashis Basu, Shivnath Mazumder, Jens Niklas, Habib Baydoun, Dakshika Wanniarachchi, Xuetao Shi, Richard J. Staples, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Chem. Sci., 2016, 7, 3264
DOI: 10.1039/C5SC04214C

Successes, challenges, and opportunities for quantum chemistry in understanding metalloenzymes for solar fuels research

Maylis Orio and Dimitrios A. Pantazis

Chem. Commun., 2021, 57, 3952
DOI: 10.1039/D1CC00705J

A tricarboxylated PtCl(terpyridine) derivative exhibiting pH-dependent photocatalytic activity for H2 evolution from water

Kosei Yamauchi and Ken Sakai

Dalton Trans., 2015, 44, 8685
DOI: 10.1039/C5DT00425J

X-ray absorption spectroscopy with time-tagged photon counting: application to study the structure of a Co(i) intermediate of H2 evolving photo-catalyst

Grigory Smolentsev, Alexander A. Guda, Markus Janousch, Cristophe Frieh, Gaudenz Jud, Flavio Zamponi, Murielle Chavarot-Kerlidou, Vincent Artero, Jeroen A. van Bokhoven and Maarten Nachtegaal

Faraday Discuss., 2014, 171, 259
DOI: 10.1039/C4FD00035H

Metalloporphyrin-modified semiconductors for solar fuel production

D. Khusnutdinova, A. M. Beiler, B. L. Wadsworth, S. I. Jacob and G. F. Moore

Chem. Sci., 2017, 8, 253
DOI: 10.1039/C6SC02664H

Ru–protein–Co biohybrids designed for solar hydrogen production: understanding electron transfer pathways related to photocatalytic function

Sarah R. Soltau, Peter D. Dahlberg, Jens Niklas, Oleg G. Poluektov, Karen L. Mulfort and Lisa M. Utschig

Chem. Sci., 2016, 7, 7068
DOI: 10.1039/C6SC03121H

A diamine-grafted metal–organic framework with outstanding CO2 capture properties and a facile coating approach for imparting exceptional moisture stability

Minjung Kang, Jeong Eun Kim, Dong Won Kang, Hwa Young Lee, Dohyun Moon and Chang Seop Hong

J. Mater. Chem. A, 2019, 7, 8177
DOI: 10.1039/C8TA07965J

Enhancing H2evolution performance of an immobilised cobalt catalyst by rational ligand design

Janina Willkomm, Nicoleta M. Muresan and Erwin Reisner

Chem. Sci., 2015, 6, 2727
DOI: 10.1039/C4SC03946G

Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties

Vishakha Kaim and Sandeep Kaur-Ghumaan

New J. Chem., 2021, 45, 20272
DOI: 10.1039/D1NJ02104D

A molecular cobalt catalyst supported by an amine-bis(phenolate) ligand for both electrolytic and photolytic water reduction

Ling-Zhi Fu, Ling-Ling Zhou and Shu-Zhong Zhan

RSC Adv., 2015, 5, 84770
DOI: 10.1039/C5RA14753K

Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts

Mei Wang, Lin Chen and Licheng Sun

Energy Environ. Sci., 2012, 5, 6763
DOI: 10.1039/c2ee03309g

A mechanistic study of proton reduction catalyzed by a pentapyridine cobalt complex: evidence for involvement of an anation-based pathway

Amanda E. King, Yogesh Surendranath, Nicholas A. Piro, Julian P. Bigi, Jeffrey R. Long and Christopher J. Chang

Chem. Sci., 2013, 4, 1578
DOI: 10.1039/c3sc22239j

Stabilisation effects of phosphane ligands in the homogeneous approach of sunlight induced hydrogen production

C. M. Strabler, S. Sinn, R. Pehn, J. Pann, J. Dutzler, W. Viertl, J. Prock, K. Ehrmann, A. Weninger, H. Kopacka, L. De Cola and P. Brüggeller

Faraday Discuss., 2017, 198, 211
DOI: 10.1039/C6FD00210B

Influence of nitro substituents on the redox, electronic, and proton reduction catalytic behavior of phenolate-based [N2O3]-type cobalt(iii) complexes

Debashis Basu, Shivnath Mazumder, Kenneth K. Kpogo and Cláudio N. Verani

Dalton Trans., 2019, 48, 14669
DOI: 10.1039/C9DT03158H

Novel cobalt/nickel–tungsten-sulfide catalysts for electrocatalytic hydrogen generation from water

Phong D. Tran, Sing Yang Chiam, Pablo P. Boix, Yi Ren, Stevin S. Pramana, Jennifer Fize, Vincent Artero and James Barber

Energy Environ. Sci., 2013, 6, 2452
DOI: 10.1039/c3ee40600h

Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

Nathan Coutard, Nicolas Kaeffer and Vincent Artero

Chem. Commun., 2016, 52, 13728
DOI: 10.1039/C6CC06311J

Protein secondary-shell interactions enhance the photoinduced hydrogen production of cobalt protoporphyrin IX

Dayn Joseph Sommer, Michael David Vaughn and Giovanna Ghirlanda

Chem. Commun., 2014, 50, 15852
DOI: 10.1039/C4CC06700B

Improving the overall performance of photochemical H2 evolution catalyzed by the Co-NHC complex via the redox tuning of electron relays

Koichi Yatsuzuka, Kosei Yamauchi, Ken Kawano, Hironobu Ozawa and Ken Sakai

Sustainable Energy Fuels, 2021, 5, 740
DOI: 10.1039/D0SE01597K

Distinguishing deposition, corrosion, and stripping of transient heterogeneous materials during molecular electrocatalysis

David J. Sconyers and James D. Blakemore

Dalton Trans., 2019, 48, 6372
DOI: 10.1039/C9DT00584F

Toward the rational benchmarking of homogeneous H2-evolving catalysts

Vincent Artero and Jean-Michel Saveant

Energy Environ. Sci., 2014, 7, 3808
DOI: 10.1039/C4EE01709A

Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions

V. Sara Thoi, Yujie Sun, Jeffrey R. Long and Christopher J. Chang

Chem. Soc. Rev., 2013, 42, 2388
DOI: 10.1039/C2CS35272A

Earth-abundant hydrogen evolution electrocatalysts

James R. McKone, Smaranda C. Marinescu, Bruce S. Brunschwig, Jay R. Winkler and Harry B. Gray

Chem. Sci., 2014, 5, 865
DOI: 10.1039/C3SC51711J

Aqueous light driven hydrogen production by a Ru–ferredoxin–Co biohybrid

S. R. Soltau, J. Niklas, P. D. Dahlberg, O. G. Poluektov, D. M. Tiede, K. L. Mulfort and L. M. Utschig

Chem. Commun., 2015, 51, 10628
DOI: 10.1039/C5CC03006D

Efficient photocatalytic hydrogen production in water using a cobalt(iii) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(i) species and its reactivity toward proton reduction

Siddhartha Varma, Carmen E. Castillo, Thibaut Stoll, Jérôme Fortage, Allan G. Blackman, Florian Molton, Alain Deronzier and Marie-Noëlle Collomb

Phys. Chem. Chem. Phys., 2013, 15, 17544
DOI: 10.1039/c3cp52641k

Photoinduced hydrogen evolution with new tetradentate cobalt(ii) complexes based on the TPMA ligand

Mirco Natali, Elena Badetti, Elisa Deponti, Marta Gamberoni, Francesca A. Scaramuzzo, Andrea Sartorel and Cristiano Zonta

Dalton Trans., 2016, 45, 14764
DOI: 10.1039/C6DT01705C

A pentadentate nitrogen-rich copper electrocatalyst for water reduction with pH-dependent molecular mechanisms

Danushka M. Ekanayake, Krista M. Kulesa, Jaffarguriqbal Singh, Kenneth K. Kpogo, Shivnath Mazumder, H. Bernhard Schlegel and Cláudio N. Verani

Dalton Trans., 2017, 46, 16812
DOI: 10.1039/C7DT02711G

Efficient photocatalytic hydrogen generation from water by a cationic cobalt(ii) porphyrin

Mirco Natali, Alessandra Luisa, Elisabetta Iengo and Franco Scandola

Chem. Commun., 2014, 50, 1842
DOI: 10.1039/c3cc48882a

A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion

Christopher J. Wood, Gareth H. Summers, Charlotte A. Clark, Nicolas Kaeffer, Maximilian Braeutigam, Lea Roberta Carbone, Luca D'Amario, Ke Fan, Yoann Farré, Stéphanie Narbey, Frédéric Oswald, Lee A. Stevens, Christopher D. J. Parmenter, Michael W. Fay, Alessandro La Torre, Colin E. Snape, Benjamin Dietzek, Danilo Dini, Leif Hammarström, Yann Pellegrin, Fabrice Odobel, Licheng Sun, Vincent Artero and Elizabeth A. Gibson

Phys. Chem. Chem. Phys., 2016, 18, 10727
DOI: 10.1039/C5CP05326A

Qualitative extension of the EC′ Zone Diagram to a molecular catalyst for a multi-electron, multi-substrate electrochemical reaction

Daniel J. Martin, Brian D. McCarthy, Eric S. Rountree and Jillian L. Dempsey

Dalton Trans., 2016, 45, 9970
DOI: 10.1039/C6DT00302H

Electro- and photochemical H2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Fiorella Lucarini, Jennifer Fize, Adina Morozan, Federico Droghetti, Euro Solari, Rosario Scopelliti, Marco Marazzi, Mirco Natali, Mariachiara Pastore, Vincent Artero and Albert Ruggi

Sustainable Energy Fuels, 2023, 7, 3384
DOI: 10.1039/D3SE00295K

Structure–function analyses of solar fuelscatalysts using in situ X-ray scattering

Karen L. Mulfort, Anusree Mukherjee, Oleksandr Kokhan, Pingwu Du and David M. Tiede

Chem. Soc. Rev., 2013, 42, 2215
DOI: 10.1039/C2CS35247H

Conjugated nanoporous polycarbazole bearing a cobalt complex for efficient visible-light driven hydrogen evolution

Bin Guo, Hai-Yan Li, Jian-Ying Chen, David James Young, Jian-Ping Lang and Hong-Xi Li

New J. Chem., 2020, 44, 8736
DOI: 10.1039/D0NJ01534B

Molecular systems for light driven hydrogen production

William T. Eckenhoff and Richard Eisenberg

Dalton Trans., 2012, 41, 13004
DOI: 10.1039/c2dt30823a

Analysis of multi-electron, multi-step homogeneous catalysis by rotating disc electrode voltammetry: theory, application, and obstacles

Katherine J. Lee, Cole T. Gruninger, Kunal M. Lodaya, Saad Qadeer, Boyce E. Griffith and Jillian L. Dempsey

Analyst, 2020, 145, 1258
DOI: 10.1039/C9AN02192B

DFT analysis into the intermediates of nickel pyridinethiolate catalysed proton reduction

Carolyn N. Virca and Theresa M. McCormick

Dalton Trans., 2015, 44, 14333
DOI: 10.1039/C5DT02044A

Distinguishing between homogeneous and heterogeneous hydrogen-evolution catalysis with molecular cobalt complexes

David J. Sconyers and James D. Blakemore

Chem. Commun., 2017, 53, 7286
DOI: 10.1039/C7CC02188G

A noble metal-free photocatalytic system based on a novel cobalt tetrapyridyl catalyst for hydrogen production in fully aqueous medium

N. Queyriaux, E. Giannoudis, C. D. Windle, S. Roy, J. Pécaut, A. G. Coutsolelos, V. Artero and M. Chavarot-Kerlidou

Sustainable Energy Fuels, 2018, 2, 553
DOI: 10.1039/C7SE00428A

Modulation of electronic and redox properties in phenolate-rich cobalt(iii) complexes and their implications for catalytic proton reduction

Debashis Basu, Marco M. Allard, Fernando R. Xavier, Mary Jane Heeg, H. Bernhard Schlegel and Claudio N. Verani

Dalton Trans., 2015, 44, 3454
DOI: 10.1039/C4DT03337J

Importance of proton-coupled electron transfer in cathodic regeneration of organic hydrides

Stefan Ilic, Abdulaziz Alherz, Charles B. Musgrave and Ksenija D. Glusac

Chem. Commun., 2019, 55, 5583
DOI: 10.1039/C9CC00928K

Photoinduced hydrogen evolution by a pentapyridine cobalt complex: elucidating some mechanistic aspects

Elisa Deponti, Alessandra Luisa, Mirco Natali, Elisabetta Iengo and Franco Scandola

Dalton Trans., 2014, 43, 16345
DOI: 10.1039/C4DT02269F

A computational mechanistic investigation of hydrogen production in water using the [RhIII(dmbpy)2Cl2]+/[RuII(bpy)3]2+/ascorbic acid photocatalytic system

Megumi Kayanuma, Thibaut Stoll, Chantal Daniel, Fabrice Odobel, Jérôme Fortage, Alain Deronzier and Marie-Noëlle Collomb

Phys. Chem. Chem. Phys., 2015, 17, 10497
DOI: 10.1039/C4CP04949G

Photoinitiated multi-step charge separation and ultrafast charge transfer induced dissociation in a pyridyl-linked photosensitizer–cobaloxime assembly

Brad S. Veldkamp, Won-Sik Han, Scott M. Dyar, Samuel W. Eaton, Mark A. Ratner and Michael R. Wasielewski

Energy Environ. Sci., 2013, 6, 1917
DOI: 10.1039/c3ee40378e

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang and Licheng Sun

Chem. Soc. Rev., 2019, 48, 2216
DOI: 10.1039/C8CS00897C

Enhanced photocatalytic hydrogen production by introducing the carboxylic acid group into cobaloxime catalysts

Junfei Wang, Chao Li, Qianxiong Zhou, Weibo Wang, Yuanjun Hou, Baowen Zhang and Xuesong Wang

Dalton Trans., 2015, 44, 17704
DOI: 10.1039/C5DT02645H

The Hydrogen Evolution Reaction: Using Molecular Design in Transition Metal Complexes to Control Catalytic Microenvironments on Electrode Surfaces

Logan Trowbridge and Peter E. Sues

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400637

Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes

Kristian E. Dalle, Julien Warnan, Jane J. Leung, Bertrand Reuillard, Isabell S. Karmel and Erwin Reisner

Chem. Rev., 2019, 119, 2752
DOI: 10.1021/acs.chemrev.8b00392

Computational Study of Anomalous Reduction Potentials for Hydrogen Evolution Catalyzed by Cobalt Dithiolene Complexes

Brian H. Solis and Sharon Hammes-Schiffer

J. Am. Chem. Soc., 2012, 134, 15253
DOI: 10.1021/ja306857q

Proton-coupled electron transfer chemistry of hangman macrocycles: Hydrogen and oxygen evolution reactions

Dilek K. Dogutan, D. Kwabena Bediako, Daniel J. Graham, Christopher M. Lemon and Daniel G. Nocera

J. Porphyrins Phthalocyanines, 2015, 19, 1
DOI: 10.1142/S1088424614501016

Molecular Cobalt Catalysts for H2 Generation with Redox Activity and Proton Relays in the Second Coordination Sphere

Lars Kohler, Jens Niklas, Ryan C. Johnson, Matthias Zeller, Oleg G. Poluektov and Karen L. Mulfort

Inorg. Chem., 2019, 58, 1697
DOI: 10.1021/acs.inorgchem.8b03297

Density functional theory insights into decorated, doped, and defective graphene as a model system for understanding hydrogen storage in carbon materials

Bauyrzhan Myrzakhmetov, Toreniyaz Shomenov, Fail Sultanov, Almagul Mentbayeva, Wenli Zhang and Yanwei Wang

Carbon Lett., 2026
DOI: 10.1007/s42823-025-01021-2

Influence of the Electrostatic Interaction between a Molecular Catalyst and Semiconductor on Photocatalytic Hydrogen Evolution Activity in Cobaloxime/CdS Hybrid Systems

Yuxing Xu, Ruotian Chen, Zhen Li, Ailong Li, Hongxian Han and Can Li

ACS Appl. Mater. Interfaces, 2017, 9, 23230
DOI: 10.1021/acsami.7b06154

Recent Advances in Radical Hydrofunctionalization of Alkenes and Dienes via Reductive Metal‐Hydride Hydrogen Atom Transfer (MHAT)

Haigen Shen, Xianrong Zeng and Zhaobin Wang

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401103

A Computational Study of the Mechanism of Hydrogen Evolution by Cobalt(Diimine‐Dioxime) Catalysts

Anirban Bhattacharjee, Eugen S. Andreiadis, Murielle Chavarot‐Kerlidou, Marc Fontecave, Martin J. Field and Vincent Artero

Chemistry A European J, 2013, 19, 15166
DOI: 10.1002/chem.201301860

Harnessing the Cobalt-Catalyzed Hydrogen Evolution Reaction through a Data-Driven Approach

Guangchao Liang and Min Zhang

Inorg. Chem., 2025, 64, 2737
DOI: 10.1021/acs.inorgchem.4c04645

Effects of Ligand Modification and Protonation on Metal Oxime Hydrogen Evolution Electrocatalysts

Brian H. Solis, Yinxi Yu and Sharon Hammes-Schiffer

Inorg. Chem., 2013, 52, 6994
DOI: 10.1021/ic400490y

Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential

Charles W. Machan, Steven A. Chabolla, Jian Yin, Michael K. Gilson, F. Akif Tezcan and Clifford P. Kubiak

J. Am. Chem. Soc., 2014, 136, 14598
DOI: 10.1021/ja5085282

Recent Progress on Exploring Stable Metal–Organic Frameworks for Photocatalytic Solar Fuel Production

Xu‐Sheng Wang, Lan Li, Dan Li and Jinhua Ye

Solar RRL, 2020, 4
DOI: 10.1002/solr.201900547

Electrocatalytic and Optical Properties of Cobaloxime Catalysts Immobilized at a Surface-Grafted Polymer Interface

Brian L. Wadsworth, Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

ACS Catal., 2016, 6, 8048
DOI: 10.1021/acscatal.6b02194

Using Molecular Design to Control the Performance of Hydrogen-Producing Polymer-Brush-Modified Photocathodes

Diana Cedeno, Alexandra Krawicz, Peter Doak, Min Yu, Jeffrey B. Neaton and Gary F. Moore

J. Phys. Chem. Lett., 2014, 5, 3222
DOI: 10.1021/jz5016394

A cobalt complex of bis(methylthioether)pyridine, a new catalyst for hydrogen evolution

Chun-Li Wang, Wei-Xia Liu and Shu-Zhong Zhan

Polyhedron, 2020, 192, 114863
DOI: 10.1016/j.poly.2020.114863

Hybrid photocathodes for solar fuel production: coupling molecular fuel-production catalysts with solid-state light harvesting and conversion technologies

Diana Cedeno, Alexandra Krawicz and Gary F. Moore

Interface Focus, 2015, 5
DOI: 10.1098/rsfs.2014.0085

Design of macrocycles mono- and multinuclear nickel complexes based 1,4,7,10-tetraazacyclododecane and electrocatalytic activities for hydrogen evolution

Yan Zhang, Xiao-Fang Qi, Sheng-Qiao Guan and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2023, 156, 111150
DOI: 10.1016/j.inoche.2023.111150

Electrocatalytic Proton Reduction by a Dicobalt Tetrakis-Schiff Base Macrocycle in Nonaqueous Electrolyte

Subhadeep Kal, Alexander S. Filatov and Peter H. Dinolfo

Inorg. Chem., 2014, 53, 7137
DOI: 10.1021/ic500121f

Reengineering cyt b562 for hydrogen production: A facile route to artificial hydrogenases

Dayn Joseph Sommer, Michael David Vaughn, Brett Colby Clark, John Tomlin, Anindya Roy and Giovanna Ghirlanda

Biochimica et Biophysica Acta (BBA) - Bioenergetics, 2016, 1857, 598
DOI: 10.1016/j.bbabio.2015.09.001

A Heterogenised Molecular Electrocatalyst for Round‐the‐Clock Green Hydrogen Production by Solar‐Electrolyser and Zinc–Air Batteries

Sukanta Saha, Yashwant Pratap Kharwar, Santanu Ghorai, Harshini V. Annadata, Suhana Karim and Arnab Dutta

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202516482

Molecular engineering of a cobalt-based electrocatalytic nanomaterial for H2 evolution under fully aqueous conditions

Eugen S. Andreiadis, Pierre-André Jacques, Phong D. Tran, Adeline Leyris, Murielle Chavarot-Kerlidou, Bruno Jousselme, Muriel Matheron, Jacques Pécaut, Serge Palacin, Marc Fontecave and Vincent Artero

Nature Chem, 2013, 5, 48
DOI: 10.1038/nchem.1481

Thermodynamic Hydricity of Transition Metal Hydrides

Eric S. Wiedner, Matthew B. Chambers, Catherine L. Pitman, R. Morris Bullock, Alexander J. M. Miller and Aaron M. Appel

Chem. Rev., 2016, 116, 8655
DOI: 10.1021/acs.chemrev.6b00168

Cobaloxime-Based Artificial Hydrogenases

Marine Bacchi, Gustav Berggren, Jens Niklas, Elias Veinberg, Michael W. Mara, Megan L. Shelby, Oleg G. Poluektov, Lin X. Chen, David M. Tiede, Christine Cavazza, Martin J. Field, Marc Fontecave and Vincent Artero

Inorg. Chem., 2014, 53, 8071
DOI: 10.1021/ic501014c

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine‐Rich Environments

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Habib Baydoun, Jens Niklas, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Angewandte Chemie, 2015, 127, 2133
DOI: 10.1002/ange.201409813

Single-Site Photocatalytic H2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts

Tanmay Banerjee, Frederik Haase, Gökcen Savasci, Kerstin Gottschling, Christian Ochsenfeld and Bettina V. Lotsch

J. Am. Chem. Soc., 2017, 139, 16228
DOI: 10.1021/jacs.7b07489

Catalytic hydrogen evolution from a covalently linked dicobaloxime

Carolyn N. Valdez, Jillian L. Dempsey, Bruce S. Brunschwig, Jay R. Winkler and Harry B. Gray

Proc. Natl. Acad. Sci. U.S.A., 2012, 109, 15589
DOI: 10.1073/pnas.1118329109

Mechanism of Photocatalytic Hydrogen Generation by a Polypyridyl-Based Cobalt Catalyst in Aqueous Solution

Alexander Rodenberg, Margherita Orazietti, Benjamin Probst, Cyril Bachmann, Roger Alberto, Kim K. Baldridge and Peter Hamm

Inorg. Chem., 2015, 54, 646
DOI: 10.1021/ic502591a

Photofunctional Construct That Interfaces Molecular Cobalt-Based Catalysts for H2 Production to a Visible-Light-Absorbing Semiconductor

Alexandra Krawicz, Jinhui Yang, Eitan Anzenberg, Junko Yano, Ian D. Sharp and Gary F. Moore

J. Am. Chem. Soc., 2013, 135, 11861
DOI: 10.1021/ja404158r

Correlation and Prediction of Redox Potentials of Hydrogen Evolution Mononuclear Cobalt Catalysts via Molecular Electrostatic Potential: A DFT Study

Bai Amutha Anjali, Fareed Bhasha Sayyed and Cherumuttathu H. Suresh

J. Phys. Chem. A, 2016, 120, 1112
DOI: 10.1021/acs.jpca.5b11543

Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts

Nicolas Queyriaux, Reuben T. Jane, Julien Massin, Vincent Artero and Murielle Chavarot-Kerlidou

Coordination Chemistry Reviews, 2015, 304-305, 3
DOI: 10.1016/j.ccr.2015.03.014

Elucidating the Key Role of pH on Light-Driven Hydrogen Evolution by a Molecular Cobalt Catalyst

Mirco Natali

ACS Catal., 2017, 7, 1330
DOI: 10.1021/acscatal.6b03087

Structure of the CoI Intermediate of a Cobalt Pentapyridyl Catalyst for Hydrogen Evolution Revealed by Time‐Resolved X‐ray Spectroscopy

Grigory Smolentsev, Mikhail A. Soldatov, Benjamin Probst, Cyril Bachmann, Nicolo Azzaroli, Roger Alberto, Maarten Nachtegaal and Jeroen A. van Bokhoven

ChemSusChem, 2018, 11, 3087
DOI: 10.1002/cssc.201801140

Interrogation of cobaloxime-based supramolecular photocatalyst architectures

Karen L. Mulfort

Comptes Rendus. Chimie, 2016, 20, 221
DOI: 10.1016/j.crci.2015.12.010

Reductive chemistry of pyrrolic macrocycles: A PCET dichotomy between metal and ligand

Dilek K. Dogutan and Daniel G. Nocera

J. Porphyrins Phthalocyanines, 2023, 27, 958
DOI: 10.1142/S1088424623300070

Tracking the Structural and Electronic Configurations of a Cobalt Proton Reduction Catalyst in Water

Dooshaye Moonshiram, Carolina Gimbert-Suriñach, Alexander Guda, Antonio Picon, C. Stefan Lehmann, Xiaoyi Zhang, Gilles Doumy, Anne Marie March, Jordi Benet-Buchholz, Alexander Soldatov, Antoni Llobet and Stephen H. Southworth

J. Am. Chem. Soc., 2016, 138, 10586
DOI: 10.1021/jacs.6b05680

Chemistry at the Interface: Polymer-Functionalized GaP Semiconductors for Solar Hydrogen Production

Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

Ind. Eng. Chem. Res., 2016, 55, 5306
DOI: 10.1021/acs.iecr.6b00478

An efficient catalyst based on a water‐soluble cobalt(II) complex of S,S′‐bis(2‐pyridylmethyl)‐1,2‐thiobenzene for electrochemical‐ and photochemical‐driven hydrogen evolution

Zhen‐Lang Xie, Wen‐Xing Jiang, Nan‐Shu Wang and Shu‐Zhong Zhan

Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5390

Visible-light-driven hydrogen evolution from water using a noble-metal-free polyoxometalate catalyst

Hongjin Lv, Jie Song, Haiming Zhu, Yurii V. Geletii, John Bacsa, Chongchao Zhao, Tianquan Lian, Djamaladdin G. Musaev and Craig L. Hill

Journal of Catalysis, 2013, 307, 48
DOI: 10.1016/j.jcat.2013.06.028

Synthesis, structure and electrochemical properties of a cobalt(II) complex supported by 2-tetrahydrofurfurylamino-N,N-bis(2-methylene-4-tert-butyl-6-methyl)phenol

Chen-Neng Lin, Ling-Ling Zhou, Ling-Zhi Fu, Shu-Zhong Zhan and Cai-Hong Chen

Inorganic Chemistry Communications, 2015, 61, 97
DOI: 10.1016/j.inoche.2015.08.017

Unusual Stability of a Bacteriochlorin Electrocatalyst under Reductive Conditions. A Case Study on CO2 Conversion to CO

Jianbing Jiang, Adam J. Matula, John R. Swierk, Neyen Romano, Yueshen Wu, Victor S. Batista, Robert H. Crabtree, Jonathan S. Lindsey, Hailiang Wang and Gary W. Brudvig

ACS Catal., 2018, 8, 10131
DOI: 10.1021/acscatal.8b02991

Synthesis of an electro-catalyst based on a cobalt(II) complex with dimethylaminoethylamino-N,N-bis(2-methylene-4-tert-butyl-6-methylphenol)

Ling-Ling Zhou, Ling-Zhi Fu, Qian-Nan Liang, Chang Fang and Shu-Zhong Zhan

Journal of Coordination Chemistry, 2016, 69, 628
DOI: 10.1080/00958972.2015.1134791

Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts

Katherine J. Lee, Noémie Elgrishi, Banu Kandemir and Jillian L. Dempsey

Nat Rev Chem, 2017, 1
DOI: 10.1038/s41570-017-0039

DFT Computational Studies on Some Cobaloximes

Ayşin ZÜLFİKAROĞLU

Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 2020, 13, 1299
DOI: 10.18185/erzifbed.828235

Electrocatalytic H2 Evolution by Supramolecular RuII–RhIII–RuII Complexes: Importance of Ligands as Electron Reservoirs and Speciation upon Reduction

Gerald F. Manbeck, Theodore Canterbury, Rongwei Zhou, Skye King, Geewoo Nam and Karen J. Brewer

Inorg. Chem., 2015, 54, 8148
DOI: 10.1021/acs.inorgchem.5b01536

Computational Study on the Proton Reduction Potential of Co, Rh, and Ir Molecular Electrocatalysts for the Hydrogen Evolution Reaction

Murugesan Panneerselvam, Madhavan Jaccob and Luciano T. Costa

ACS Omega, 2024, 9, 48766
DOI: 10.1021/acsomega.4c03260

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine‐Rich Environments

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Habib Baydoun, Jens Niklas, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Angew Chem Int Ed, 2015, 54, 2105
DOI: 10.1002/anie.201409813

Ein robuster mesoionischer Pyridylcarben‐Cobalt‐Komplex als Elektrokatalysator für die Wasserstoff‐Produktion

Margarethe van der Meer, Estelle Glais, Inke Siewert and Biprajit Sarkar

Angewandte Chemie, 2015, 127, 13997
DOI: 10.1002/ange.201506061

[Fe]-Hydrogenase-Inspired Proton-Shuttle Installation in a Molecular Cobalt Complex for High-Efficiency H2 Evolution Reaction

Sanajit Kumar Mandal, Chandana Sunil and Joyanta Choudhury

ACS Catal., 2024, 14, 2058
DOI: 10.1021/acscatal.3c04879

Charge migration and charge transfer in molecular systems

Hans Jakob Wörner, Christopher A. Arrell, Natalie Banerji, Andrea Cannizzo, Majed Chergui, Akshaya K. Das, Peter Hamm, Ursula Keller, Peter M. Kraus, Elisa Liberatore, Pablo Lopez-Tarifa, Matteo Lucchini, Markus Meuwly, Chris Milne, Jacques-E. Moser, Ursula Rothlisberger, Grigory Smolentsev, Joël Teuscher, Jeroen A. van Bokhoven and Oliver Wenger

Structural Dynamics, 2017, 4
DOI: 10.1063/1.4996505

Directing the reactivity of metal hydrides for selective CO 2 reduction

Bianca M. Ceballos and Jenny Y. Yang

Proc. Natl. Acad. Sci. U.S.A., 2018, 115, 12686
DOI: 10.1073/pnas.1811396115

Theoretical study of cobalt and nickel complexes involved in methyl transfer reactions: structures, redox potentials and methyl binding energies

Patrycja Sitek, Aleksandra Chmielowska, Maria Jaworska, Piotr Lodowski and Marzena Szczepańska

Struct Chem, 2019, 30, 1957
DOI: 10.1007/s11224-019-01384-z

Synthesis, structure and electrolytic properties of a dinuclear cobalt(III) complex with amine-bis(phenolate) ligands

Yun-Xiao Zhang, Ling-Zhi Fu, Ling-Ling Zhou, Shu-Zhong Zhan and Wei Li

Synthetic Metals, 2016, 212, 69
DOI: 10.1016/j.synthmet.2015.12.003

Electrochemical and photocatalytic hydrogen evolution by an electron‐deficient cobalt tris(ethoxycarbonyl)corrole complex

Hui‐Qing Yuan, Hua‐Hua Wang, Jaipal Kandhadi, Hui Wang, Shu‐Zhong Zhan and Hai‐Yang Liu

Applied Organom Chemis, 2017, 31
DOI: 10.1002/aoc.3773

Molecular Catalysts Immobilized on Semiconductor Photosensitizers for Proton Reduction toward Visible‐Light‐Driven Overall Water Splitting

Takeshi Morikawa, Shunsuke Sato, Keita Sekizawa, Takeo Arai and Tomiko M. Suzuki

ChemSusChem, 2019, 12, 1807
DOI: 10.1002/cssc.201900441

Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species

Robin Gueret, Carmen E. Castillo, Mateusz Rebarz, Fabrice Thomas, Michel Sliwa, Jérôme Chauvin, Baptiste Dautreppe, Jacques Pécaut, Jérôme Fortage and Marie-Noëlle Collomb

Inorg. Chem., 2019, 58, 9043
DOI: 10.1021/acs.inorgchem.9b00447

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear CoII–CoII complex

Ling-Zhi Fu, Ling-Ling Zhou, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

Journal of Power Sources, 2015, 280, 453
DOI: 10.1016/j.jpowsour.2015.01.121

Tetra- and Heptametallic Ru(II),Rh(III) Supramolecular Hydrogen Production Photocatalysts

Gerald F. Manbeck, Etsuko Fujita and Karen J. Brewer

J. Am. Chem. Soc., 2017, 139, 7843
DOI: 10.1021/jacs.7b02142

Synthesis and electrocatalytic properties of a nickel(II) complex supported by bis(diphenylphosphino)methane

Chen-Neng Lin, Shi-Tao Ren, Li-Ping Ye, Cai-Hong Chen and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2016, 69, 24
DOI: 10.1016/j.inoche.2016.04.030

Mechanism of the Electrocatalytic Reduction of Protons with Diaryldithiolene Cobalt Complexes

Christopher S. Letko, Julien A. Panetier, Martin Head-Gordon and T. Don Tilley

J. Am. Chem. Soc., 2014, 136, 9364
DOI: 10.1021/ja5019755

Microsecond X‐ray Absorption Spectroscopy Identification of CoI Intermediates in Cobaloxime‐Catalyzed Hydrogen Evolution

Grigory Smolentsev, Bianca Cecconi, Alexander Guda, Murielle Chavarot‐Kerlidou, Jeroen A. van Bokhoven, Maarten Nachtegaal and Vincent Artero

Chemistry A European J, 2015, 21, 15158
DOI: 10.1002/chem.201502900

Two routes to hydrogen evolution for a Co-polypyridyl complex with two open sites

Liqin Xue Toro, Sofia Kiriakidi, Anders Thapper, Sascha Ott and Marcus Lundberg

Electron. Struct., 2022, 4, 034002
DOI: 10.1088/2516-1075/ac7bca

Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

D. Kwabena Bediako, Brian H. Solis, Dilek K. Dogutan, Manolis M. Roubelakis, Andrew G. Maher, Chang Hoon Lee, Matthew B. Chambers, Sharon Hammes-Schiffer and Daniel G. Nocera

Proc. Natl. Acad. Sci. U.S.A., 2014, 111, 15001
DOI: 10.1073/pnas.1414908111

Rationalizing Photo‐Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands

Fiorella Lucarini, David Bongni, Philippe Schiel, Gabriele Bevini, Elisabetta Benazzi, Euro Solari, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Marco Marazzi, Mirco Natali, Mariachiara Pastore and Albert Ruggi

ChemSusChem, 2021, 14, 1874
DOI: 10.1002/cssc.202100161

Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme

Jennifer M. Le, Georgios Alachouzos, Marco Chino, Alison J. Frontier, Angela Lombardi and Kara L. Bren

Biochemistry, 2020, 59, 1289
DOI: 10.1021/acs.biochem.0c00060

Photoredox/Cobalt Dual‐Catalyzed Decarboxylative Elimination of Carboxylic Acids: Development and Mechanistic Insight

Kaitie C. Cartwright, Ebbin Joseph, Chelsea G. Comadoll and Jon A. Tunge

Chemistry A European J, 2020, 26, 12454
DOI: 10.1002/chem.202001952

Unraveling a Single-Step Simultaneous Two-Electron Transfer Process from Semiconductor to Molecular Catalyst in a CoPy/CdS Hybrid System for Photocatalytic H2 Evolution under Strong Alkaline Conditions

Yuxing Xu, Yun Ye, Taifeng Liu, Xiuli Wang, Bingqing Zhang, Mei Wang, Hongxian Han and Can Li

J. Am. Chem. Soc., 2016, 138, 10726
DOI: 10.1021/jacs.6b04080

Electro- and photo-chemical driven water reduction catalyzed by a cobalt(III) complex with high turnover number

Ling-Ling Zhou, Ling-Zhi Fu and Shu-Zhong Zhan

Journal of Molecular Catalysis A: Chemical, 2015, 404-405, 227
DOI: 10.1016/j.molcata.2015.05.003

Toward Quantitatively Accurate Calculation of the Redox-Associated Acid–Base and Ligand Binding Equilibria of Aquacobalamin

Ryne C. Johnston, Jing Zhou, Jeremy C. Smith and Jerry M. Parks

J. Phys. Chem. B, 2016, 120, 7307
DOI: 10.1021/acs.jpcb.6b02701

Recent progress on metalloporphyrin-based hydrogen evolution catalysis

Belete B. Beyene and Chen-Hsiung Hung

Coordination Chemistry Reviews, 2020, 410, 213234
DOI: 10.1016/j.ccr.2020.213234

Nachweis der Zwischenstufen bei der sequenziellen Elektronen‐ und Wasserstoffabgabe aus einem Dicarbonylcobalthydrid‐Komplex

Michael J. Krafft, Martina Bubrin, Alexa Paretzki, Falk Lissner, Jan Fiedler, Stanislav Záliš and Wolfgang Kaim

Angewandte Chemie, 2013, 125, 6914
DOI: 10.1002/ange.201301706

Rational development of molecular earth-abundant metal complexes for electrocatalytic hydrogen production

John Daniel McCool, Shiyuan Zhang, Inen Cheng and Xuan Zhao

Chinese Journal of Catalysis, 2022, 43, 3019
DOI: 10.1016/S1872-2067(22)64150-0

Synthesis and electrocatalytic function for hydrogen generation of cobalt and nickel complexes supported by phenylenediamine ligand

Yun-Xiao Zhang, Ling-Zhi Tang, Yuan-Fu Deng and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2016, 72, 100
DOI: 10.1016/j.inoche.2016.08.022

Buffer pKa Impacts the Mechanism of Hydrogen Evolution Catalyzed by a Cobalt Porphyrin-Peptide

Jose L. Alvarez-Hernandez, Andrew E. Sopchak and Kara L. Bren

Inorg. Chem., 2020, 59, 8061
DOI: 10.1021/acs.inorgchem.0c00362

Deciphering Reversible Homogeneous Catalysis of the Electrochemical H2 Evolution and Oxidation: Role of Proton Relays and Local Concentration Effects**

Bertrand Reuillard, Cyrille Costentin and Vincent Artero

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202302779

Selective Reduction of Aqueous Protons to Hydrogen with a Synthetic Cobaloxime Catalyst in the Presence of Atmospheric Oxygen

Fezile Lakadamyali, Masaru Kato, Nicoleta M. Muresan and Erwin Reisner

Angewandte Chemie, 2012, 124, 9515
DOI: 10.1002/ange.201204180

Electrocatalytic Hydrogen Evolution under Acidic Aqueous Conditions and Mechanistic Studies of a Highly Stable Molecular Catalyst

Charlene Tsay and Jenny Y. Yang

J. Am. Chem. Soc., 2016, 138, 14174
DOI: 10.1021/jacs.6b05851

Identifying Intermediates of Sequential Electron and Hydrogen Loss from a Dicarbonylcobalt Hydride Complex

Michael J. Krafft, Martina Bubrin, Alexa Paretzki, Falk Lissner, Jan Fiedler, Stanislav Záliš and Wolfgang Kaim

Angew Chem Int Ed, 2013, 52, 6781
DOI: 10.1002/anie.201301706

Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

Bing Jiang, Marcos Gil‐Sepulcre, Pablo Garrido‐Barros, Carolina Gimbert‐Suriñach, Jia‐Wei Wang, Jordi Garcia‐Anton, Pau Nolis, Jordi Benet‐Buchholz, Nuria Romero, Xavier Sala and Antoni Llobet

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202209075

Hydrogen production based on hexacoordinated cobalt scaffolds as electrocatalysts for acid-proton reduction: Electrochemistry and mechanisms

Ibukun O. Shotonwa, Onome Ejeromedoghene, Adedoyin O. Adesoji, Yakubu A. Alli, Caroline Akinremi and Sheriff Adewuyi

Journal of Electroanalytical Chemistry, 2024, 963, 118228
DOI: 10.1016/j.jelechem.2024.118228

Synthesis, Characterization, and Photocatalytic H2-Evolving Activity of a Family of [Co(N4Py)(X)]n+ Complexes in Aqueous Solution

Warrick K. C. Lo, Carmen E. Castillo, Robin Gueret, Jérôme Fortage, Mateusz Rebarz, Michel Sliwa, Fabrice Thomas, C. John McAdam, Geoffrey B. Jameson, David A. McMorran, James D. Crowley, Marie-Noëlle Collomb and Allan G. Blackman

Inorg. Chem., 2016, 55, 4564
DOI: 10.1021/acs.inorgchem.6b00391

Density Functional Theory-Based Approaches to Improving Hydrogen Storage in Graphene-Based Materials

Heriberto Cruz-Martínez, Brenda García-Hilerio, Fernando Montejo-Alvaro, Amado Gazga-Villalobos, Hugo Rojas-Chávez and Elvia P. Sánchez-Rodríguez

Molecules, 2024, 29, 436
DOI: 10.3390/molecules29020436

Cobaloxime‐Catalyzed Hydrogen Evolution in Photoredox‐Facilitated Small‐Molecule Functionalization

Kaitie C. Cartwright, Alex M. Davies and Jon A. Tunge

Eur J Org Chem, 2020, 2020, 1245
DOI: 10.1002/ejoc.201901170

Modular Homogeneous Chromophore–Catalyst Assemblies

Karen L. Mulfort and Lisa M. Utschig

Acc. Chem. Res., 2016, 49, 835
DOI: 10.1021/acs.accounts.5b00539

Bimetallic Cooperativity in Proton Reduction with an Amido‐Bridged Cobalt Catalyst

Kenneth K. Kpogo, Shivnath Mazumder, Denan Wang, H. Bernhard Schlegel, Adam T. Fiedler and Cláudio N. Verani

Chemistry A European J, 2017, 23, 9272
DOI: 10.1002/chem.201701982

H2-Evolving Cobalt–Protic-NHC Catalysts: Kinetic Zone Diagram Analysis and Mechanistic Insights

Sanajit Kumar Mandal, Anusha Gupta and Joyanta Choudhury

ACS Catal., 2024, 14, 17263
DOI: 10.1021/acscatal.4c05104

Structural and Electronic Influences on Rates of Tertpyridine−Amine CoIII−H Formation During Catalytic H2 Evolution in an Aqueous Environment

Brian N. DiMarco, Dmitry E. Polyansky, David C. Grills, Ping Wang, Yutaka Kuwahara, Xuan Zhao and Etsuko Fujita

ChemPhysChem, 2021, 22, 1478
DOI: 10.1002/cphc.202100295

Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex

Anna Lewandowska-Andralojc, Teera Baine, Xuan Zhao, James T. Muckerman, Etsuko Fujita and Dmitry E. Polyansky

Inorg. Chem., 2015, 54, 4310
DOI: 10.1021/ic5031137

Effects of different dithiolate ligands on electrocatalytic hydrogen production of nickel complexes in acetic acid or water

Hao-Jun Yin, Zhi-Hao Gan, Zong Wang, Xiao-Ting Zheng, Li-Yuan Huang, Yi-Chun Chen, Jia-Rong Zhou, Chun-Lin Ni and Wei Liu

Journal of Molecular Structure, 2023, 1287, 135659
DOI: 10.1016/j.molstruc.2023.135659

A Heterogenised Molecular Electrocatalyst for Round‐the‐Clock Green Hydrogen Production by Solar‐Electrolyser and Zinc–Air Batteries

Sukanta Saha, Yashwant Pratap Kharwar, Santanu Ghorai, Harshini V. Annadata, Suhana Karim and Arnab Dutta

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202516482

Visible-Light-Driven H2 Evolution with Cobalt Complexes in Aqueous Solution: Theoretical and Experimental Study

Qinghua Deng, Yun Xu, Ziqun Wang, Tifang Miao, Xianliang Fu and Liancai Xu

J. Phys. Chem. C, 2019, 123, 30351
DOI: 10.1021/acs.jpcc.9b08074

Electrochemical Generation and Spectroscopic Characterization of the Key Rhodium(III) Hydride Intermediates of Rhodium Poly(bipyridyl) H2-Evolving Catalysts

Carmen E. Castillo, Thibaut Stoll, Martina Sandroni, Robin Gueret, Jérôme Fortage, Megumi Kayanuma, Chantal Daniel, Fabrice Odobel, Alain Deronzier and Marie-Noëlle Collomb

Inorg. Chem., 2018, 57, 11225
DOI: 10.1021/acs.inorgchem.8b01811

Synthesis, characterization, magnetic anisotropy and catalytic behaviors of a cobalt complex of S,S′-bis(2-pyridylmethyl)-1,2-thiobenzene

Wei-Xia Liu, Zhen-Lang Xie, Jun-Zheng Zhan, Shu-Zhong Zhan and Song-Ping Wu

Inorganica Chimica Acta, 2020, 503, 119400
DOI: 10.1016/j.ica.2019.119400

Molecular mechanisms of cobalt-catalyzed hydrogen evolution

Smaranda C. Marinescu, Jay R. Winkler and Harry B. Gray

Proc. Natl. Acad. Sci. U.S.A., 2012, 109, 15127
DOI: 10.1073/pnas.1213442109

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear cobalt(II)–triazenido complex with high turnover number

Ling-Ling Zhou, Ling-Zhi Fu, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2015, 40, 5099
DOI: 10.1016/j.ijhydene.2015.02.072

Photoinduced Hydrogen Evolution Catalyzed by Co(II) Complexes of N5‐Donor Ligands

Chuanshuai Li, Yong Li, Yusen Luo, Klaudia Michaliszyn, Iria Bolaño Losada, Md. Kamal Hossain, Fatma Elantabli, Meiyuan Guo, Lintang Hizbullah, Derek A. Tocher, Matti Haukka, Petter Persson, Julio Lloret‐Fillol, Benjamin Dietzek‐Ivanšić and Ebbe Nordlander

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404499

Insights into the Mechanism of a Covalently Linked Organic Dye–Cobaloxime Catalyst System for Dye‐Sensitized Solar Fuel Devices

Palas Baran Pati, Lei Zhang, Bertrand Philippe, Ricardo Fernández‐Terán, Sareh Ahmadi, Lei Tian, Håkan Rensmo, Leif Hammarström and Haining Tian

ChemSusChem, 2017, 10, 2480
DOI: 10.1002/cssc.201700285

Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability

Nicolas Queyriaux, Dongyue Sun, Jennifer Fize, Jacques Pécaut, Martin J. Field, Murielle Chavarot-Kerlidou and Vincent Artero

J. Am. Chem. Soc., 2020, 142, 274
DOI: 10.1021/jacs.9b10407

The Hydrogen Catalyst Cobaloxime: A Multifrequency EPR and DFT Study of Cobaloxime’s Electronic Structure

Jens Niklas, Kristy L. Mardis, Rakhim R. Rakhimov, Karen L. Mulfort, David M. Tiede and Oleg G. Poluektov

J. Phys. Chem. B, 2012, 116, 2943
DOI: 10.1021/jp209395n

Deciphering Reaction Mechanisms of Molecular Proton Reduction Catalysts with Cyclic Voltammetry: Kinetic vs Thermodynamic Control

Jillian L. Dempsey

Acc. Chem. Res., 2025, 58, 947
DOI: 10.1021/acs.accounts.5c00002

Phosphine Coordination to a Cobalt Diimine–Dioxime Catalyst Increases Stability during Light-Driven H2 Production

Pan Zhang, Pierre-André Jacques, Murielle Chavarot-Kerlidou, Mei Wang, Licheng Sun, Marc Fontecave and Vincent Artero

Inorg. Chem., 2012, 51, 2115
DOI: 10.1021/ic2019132

Electrochemical-driven water splitting catalyzed by a water-soluble cobalt(II) complex supported by N,N′-bis(2′-pyridinecarboxamide)-1,2-benzene with high turnover frequency

Zhuo-Qiang Wang, Ling-Zhi Tang, Yun-Xiao Zhang, Shu-Zhong Zhan and Jian-Shan Ye

Journal of Power Sources, 2015, 287, 50
DOI: 10.1016/j.jpowsour.2015.04.031

Electronic Structure and Hydration of Tetramine Cobalt Hydride Complexes

Anirban Bhattacharjee, Alexander K. H. Weiss, Vincent Artero, Martin J. Field and Thomas S. Hofer

J. Phys. Chem. B, 2014, 118, 5551
DOI: 10.1021/jp502651s

Molecular Engineering of Electrocatalytic Nanomaterials for Hydrogen Evolution: The Impact of Structural and Electronic Modifications of Anchoring Linkers on Electrocatalysis

Andrew J. Bagnall, Matthieu Haake, Sergi Grau, Tatiana Straistari, Matthieu Koepf, Navid Jameei Moghaddam, Carolina Gimbert-Suriñach, Jordi Benet-Buchholz, Antoni Llobet, Murielle Chavarot-Kerlidou, Bertrand Reuillard and Vincent Artero

ACS Catal., 2024, 14, 5630
DOI: 10.1021/acscatal.4c00336

Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production

Eric S. Wiedner and R. Morris Bullock

J. Am. Chem. Soc., 2016, 138, 8309
DOI: 10.1021/jacs.6b04779

Theoretical investigation of efficiency of [Co (PMe2NPh2)2]2+ structure as a possible hydrogen evolution catalyst

Masoumeh Molaei, Fatemeh Ahmadi and S Morteza Mousavi-Khoshdel

Mater. Res. Express, 2018, 5, 095502
DOI: 10.1088/2053-1591/aad57a

Homolytic versus Heterolytic Hydrogen Evolution Reaction Steered by a Steric Effect

Xiaojun Guo, Ni Wang, Xialiang Li, Zongyao Zhang, Jianping Zhao, Wanjie Ren, Shuping Ding, Gelun Xu, Jianfeng Li, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angew Chem Int Ed, 2020, 59, 8941
DOI: 10.1002/anie.202002311

Selective Reduction of Aqueous Protons to Hydrogen with a Synthetic Cobaloxime Catalyst in the Presence of Atmospheric Oxygen

Fezile Lakadamyali, Masaru Kato, Nicoleta M. Muresan and Erwin Reisner

Angew Chem Int Ed, 2012, 51, 9381
DOI: 10.1002/anie.201204180

Paramagnetic Transition Metal Hydride Complexes

Adi Fishkin and Robert H. Morris

Chem. Rev., 2026, 126, 204
DOI: 10.1021/acs.chemrev.5c00531

Catalysis of Proton Reduction by a [BO4]-Bridged Dicobalt Glyoxime

Stephanie M. Laga, James D. Blakemore, Lawrence M. Henling, Bruce S. Brunschwig and Harry B. Gray

Inorg. Chem., 2014, 53, 12668
DOI: 10.1021/ic501804h

Electronic Effects on a Mononuclear Co Complex with a Pentadentate Ligand for Catalytic H2Evolution

Manohar Vennampalli, Guangchao Liang, Lakshmi Katta, Charles Edwin Webster and Xuan Zhao

Inorg. Chem., 2014, 53, 10094
DOI: 10.1021/ic500840e

Cobalt complexes as artificial hydrogenases for the reductive side of water splitting

William T. Eckenhoff, William R. McNamara, Pingwu Du and Richard Eisenberg

Biochimica et Biophysica Acta (BBA) - Bioenergetics, 2013, 1827, 958
DOI: 10.1016/j.bbabio.2013.05.003

Combined Experimental–Theoretical Characterization of the Hydrido-Cobaloxime [HCo(dmgH)2(PnBu3)]

Anirban Bhattacharjee, Murielle Chavarot-Kerlidou, Eugen. S. Andreiadis, Marc Fontecave, Martin J. Field and Vincent Artero

Inorg. Chem., 2012, 51, 7087
DOI: 10.1021/ic2024204

Photocatalytic H2-Production by Complexes Made from Earth Abundant Metals Stabilized by Phosphane-Ligands

Christof M. Strabler, Johannes Prock, Wolfgang Viertl, Richard Pehn, Alexander Weninger, Holger Kopacka, Dagmar Obendorf and Peter Brüggeller

Materials Today: Proceedings, 2016, 3, 183
DOI: 10.1016/j.matpr.2016.01.054

Solar Hydrogen Production Using Molecular Catalysts Immobilized on Gallium Phosphide (111)A and (111)B Polymer-Modified Photocathodes

Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

ACS Appl. Mater. Interfaces, 2016, 8, 10038
DOI: 10.1021/acsami.6b01557

Enzyme‐Inspired Design of CoII‐Based H2 Generation Catalysts: A Toolbox with Guiding Principles Revealed by a Systematic DFT Study

Neha Rani and Shivnath Mazumder

Eur J Inorg Chem, 2021, 2021, 2739
DOI: 10.1002/ejic.202100365

Ab initio study of ligand dissociation/exchange and the hydrogen production process of the Co(dmgH)2(py)Cl cobaloxime in the acetonitrile-water solvent

Jinfan Chen and Patrick H.-L. Sit

Catalysis Today, 2018, 314, 179
DOI: 10.1016/j.cattod.2018.03.058

Time-resolved X-ray absorption spectroscopy for the study of molecular systems relevant for artificial photosynthesis

G. Smolentsev and V. Sundström

Coordination Chemistry Reviews, 2015, 304-305, 117
DOI: 10.1016/j.ccr.2015.03.001

Electrochemical-driven water reduction catalyzed by a water soluble cobalt(III) complex with Schiff base ligand

Ting Fang, Ling-Zhi Fu, Ling-Ling Zhou, Shu-Zhong Zhan and Shaowei Chen

Electrochimica Acta, 2015, 178, 368
DOI: 10.1016/j.electacta.2015.07.180

Cobalt-based Metalloporphyrins As Efficient Electro-catalysts for Hydrogen Evolution From Acetic Acid and Water

Zong Wang, Yin Liu, Ting Li, Yong-Zhen He, Er-Chen Han, Yan-Lin Chen, Xin-Yi Jiang, Chun-Lin Ni, Le-Min Yang and Wei Liu

Electrocatalysis, 2023, 14, 752
DOI: 10.1007/s12678-023-00832-z

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

David Schilter, James M. Camara, Mioy T. Huynh, Sharon Hammes-Schiffer and Thomas B. Rauchfuss

Chem. Rev., 2016, 116, 8693
DOI: 10.1021/acs.chemrev.6b00180

New types of the hybrid functional materials based on cage metal complexes for (electro) catalytic hydrogen production

Yan Z. Voloshin, Vyacheslav M. Buznik and Alexey G. Dedov

Pure and Applied Chemistry, 2020, 92, 1159
DOI: 10.1515/pac-2019-1105

Synthesis and electro- and photo-catalytic properties of a dinuclear cobalt(III) complex supported by 2-pyridylamino-N,N-bis(2-methylene-4,6-bimethyl)phenol

Ling-Zhi Fu, Ling-Ling Zhou, Qian-Nan Liang, Chang Fang and Shu-Zhong Zhan

Polyhedron, 2016, 107, 83
DOI: 10.1016/j.poly.2015.11.019

Thermodynamic Properties of Hydrogen-Producing Cobaloxime Catalysts: A Density Functional Theory Analysis

Jinfan Chen and Patrick H.-L. Sit

ACS Omega, 2019, 4, 582
DOI: 10.1021/acsomega.8b02107

A Nickel Dithiolate Water Reduction Catalyst Providing Ligand‐Based Proton‐Coupled Electron‐Transfer Pathways

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Angew Chem Int Ed, 2017, 56, 4247
DOI: 10.1002/anie.201700927

Photo- and electrocatalytic H₂ evolution with cobalt oxime complexes

Janina Willkomm and Erwin Reisner

Bull. Jpn. Soc. Coord. Chem., 2018, 71, 18
DOI: 10.4019/bjscc.71.18

High-Throughput Screening of Earth-Abundant Water Reduction Catalysts toward Photocatalytic Hydrogen Evolution

Rachel N. Motz, Eric M. Lopato, Timothy U. Connell and Stefan Bernhard

Inorg. Chem., 2021, 60, 774
DOI: 10.1021/acs.inorgchem.0c02790

Homolytic versus Heterolytic Hydrogen Evolution Reaction Steered by a Steric Effect

Xiaojun Guo, Ni Wang, Xialiang Li, Zongyao Zhang, Jianping Zhao, Wanjie Ren, Shuping Ding, Gelun Xu, Jianfeng Li, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angewandte Chemie, 2020, 132, 9026
DOI: 10.1002/ange.202002311

Efficient Electrocatalytic H2 Production by Immobilized Co(III)‐myoglobin

Mirco Meglioli, Giulia Di Rocco, Antonio Ranieri, Carlo Augusto Bortolotti, Marco Sola, Gianantonio Battistuzzi and Marco Borsari

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202300821

Hydrogen Evolution Catalyzed by Cobalt Diimine–Dioxime Complexes

Nicolas Kaeffer, Murielle Chavarot-Kerlidou and Vincent Artero

Acc. Chem. Res., 2015, 48, 1286
DOI: 10.1021/acs.accounts.5b00058

Molecular Catalysis of H2 Evolution: Diagnosing Heterolytic versus Homolytic Pathways

Cyrille Costentin, Hachem Dridi and Jean-Michel Savéant

J. Am. Chem. Soc., 2014, 136, 13727
DOI: 10.1021/ja505845t

Computational Study of Fluorinated Diglyoxime-Iron Complexes: Tuning the Electrocatalytic Pathways for Hydrogen Evolution

Aparna Karippara Harshan, Brian H. Solis, Jay R. Winkler, Harry B. Gray and Sharon Hammes-Schiffer

Inorg. Chem., 2016, 55, 2934
DOI: 10.1021/acs.inorgchem.5b02857

Tracking Co(I) Intermediate in Operando in Photocatalytic Hydrogen Evolution by X-ray Transient Absorption Spectroscopy and DFT Calculation

Zhi-Jun Li, Fei Zhan, Hongyan Xiao, Xiaoyi Zhang, Qing-Yu Kong, Xiang-Bing Fan, Wen-Qiang Liu, Mao-Yong Huang, Cheng Huang, Yu-Ji Gao, Xu-Bing Li, Qing-Yuan Meng, Ke Feng, Bin Chen, Chen-Ho Tung, Hai-Feng Zhao, Ye Tao and Li-Zhu Wu

J. Phys. Chem. Lett., 2016, 7, 5253
DOI: 10.1021/acs.jpclett.6b02479

Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines

Eric S. Wiedner, Aaron M. Appel, Daniel L. DuBois and R. Morris Bullock

Inorg. Chem., 2013, 52, 14391
DOI: 10.1021/ic4025475

Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines

Eric S. Wiedner, Aaron M. Appel, Simone Raugei, Wendy J. Shaw and R. Morris Bullock

Chem. Rev., 2022, 122, 12427
DOI: 10.1021/acs.chemrev.1c01001

Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

Bing Jiang, Marcos Gil‐Sepulcre, Pablo Garrido‐Barros, Carolina Gimbert‐Suriñach, Jia‐Wei Wang, Jordi Garcia‐Anton, Pau Nolis, Jordi Benet‐Buchholz, Nuria Romero, Xavier Sala and Antoni Llobet

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202209075

Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes

Noémie Elgrishi, Brian D. McCarthy, Eric S. Rountree and Jillian L. Dempsey

ACS Catal., 2016, 6, 3644
DOI: 10.1021/acscatal.6b00778

Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO2 Reduction by fac-Re(bpy)(CO)3Cl

John A. Keith, Kyle A. Grice, Clifford P. Kubiak and Emily A. Carter

J. Am. Chem. Soc., 2013, 135, 15823
DOI: 10.1021/ja406456g

Electronic and Steric Tuning of Catalytic H2 Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands

Ping Wang, Guangchao Liang, M. Ramana Reddy, Melissa Long, Kandria Driskill, Christian Lyons, Bruno Donnadieu, John C. Bollinger, Charles Edwin Webster and Xuan Zhao

J. Am. Chem. Soc., 2018, 140, 9219
DOI: 10.1021/jacs.8b05108

Distinct Proton and Water Reduction Behavior with a Cobalt(III) Electrocatalyst Based on Pentadentate Oximes

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Richard J. Staples, H. Bernhard Schlegel and Cláudio N. Verani

Angewandte Chemie, 2015, 127, 7245
DOI: 10.1002/ange.201501410

Density Functional Theory and Car–Parrinello Molecular Dynamics Study of the Hydrogen-Producing Mechanism of the Co(dmgBF2)2 and Co(dmgH)2 Cobaloxime Complexes in Acetonitrile–Water Solvent

Jinfan Chen and Patrick H.-L. Sit

J. Phys. Chem. A, 2017, 121, 3515
DOI: 10.1021/acs.jpca.7b00163

Proton-Coupled Electron Transfer in Molecular Electrocatalysis: Theoretical Methods and Design Principles

Brian H. Solis and Sharon Hammes-Schiffer

Inorg. Chem., 2014, 53, 6427
DOI: 10.1021/ic5002896

Meso-Formyl Functionalization Enhances Electrocatalytic Hydrogen Evolution Activity of Nickel(II) Octaethylporphyrin

Tilahun Wubalem Tsega, Danicah T. Agub, Susan D. Arco, Chi-Kwong Chang and Chen-Hsiung Hung

Inorg. Chem., 2025, 64, 10792
DOI: 10.1021/acs.inorgchem.5c00498

Hydrogen Evolution Catalysis by a Sparsely Substituted Cobalt Chlorin

Andrew G. Maher, Guillaume Passard, Dilek K. Dogutan, Robert L. Halbach, Bryce L. Anderson, Christopher J. Gagliardi, Masahiko Taniguchi, Jonathan S. Lindsey and Daniel G. Nocera

ACS Catal., 2017, 7, 3597
DOI: 10.1021/acscatal.7b00969

Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons

Hao Tang, Edward N. Brothers, Craig A. Grapperhaus and Michael B. Hall

ACS Catal., 2020, 10, 3778
DOI: 10.1021/acscatal.9b04579

Deciphering Reversible Homogeneous Catalysis of the Electrochemical H2 Evolution and Oxidation: Role of Proton Relays and Local Concentration Effects**

Bertrand Reuillard, Cyrille Costentin and Vincent Artero

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202302779

B12‐TiO2 Hybrid Catalyst for Light‐Driven Hydrogen Production and Hydrogenation of CC Multiple Bonds

Hisashi Shimakoshi and Yoshio Hisaeda

ChemPlusChem, 2014, 79, 1250
DOI: 10.1002/cplu.201402081

A Hybrid Catalyst for Light‐Driven Green Molecular Transformations

Hisashi Shimakoshi and Yoshio Hisaeda

ChemPlusChem, 2017, 82, 18
DOI: 10.1002/cplu.201600303

Distinct Proton and Water Reduction Behavior with a Cobalt(III) Electrocatalyst Based on Pentadentate Oximes

Debashis Basu, Shivnath Mazumder, Xuetao Shi, Richard J. Staples, H. Bernhard Schlegel and Cláudio N. Verani

Angew Chem Int Ed, 2015, 54, 7139
DOI: 10.1002/anie.201501410

Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst

Eric S. Rountree, Daniel J. Martin, Brian D. McCarthy and Jillian L. Dempsey

ACS Catal., 2016, 6, 3326
DOI: 10.1021/acscatal.6b00667

Breaking the Correlation between Energy Costs and Kinetic Barriers in Hydrogen Evolution via a Cobalt Pyridine-Diimine-Dioxime Catalyst

Pengfei Huo, Christopher Uyeda, Jason D. Goodpaster, Jonas C. Peters and Thomas F. Miller

ACS Catal., 2016, 6, 6114
DOI: 10.1021/acscatal.6b01387

Density Functional Theory Prediction of the Electrocatalytic Mechanism of Proton Reduction by a Dicobalt Tetrakis(Schiff Base) Macrocycle

Tyler LeBlond and Peter H. Dinolfo

Inorg. Chem., 2020, 59, 3764
DOI: 10.1021/acs.inorgchem.9b03411

Role of Anation on the Mechanism of Proton Reduction Involving a Pentapyridine Cobalt Complex: A Theoretical Study

Murugesan Panneerselvam and Madhavan Jaccob

Inorg. Chem., 2018, 57, 8116
DOI: 10.1021/acs.inorgchem.8b00286

Degrade-Repair Cycle of a Fuel-Forming Photoelectrode

Nghi P. Nguyen, Lillian K. Hensleigh, Daiki Nishiori, Edgar A. Reyes Cruz and Gary F. Moore

ACS Appl. Energy Mater., 2022, 5, 13128
DOI: 10.1021/acsaem.2c02367

Synthesis and Electrochemical Studies of Cobalt(III) Monohydride Complexes Containing Pendant Amines

Eric S. Wiedner, John A. S. Roberts, William G. Dougherty, W. Scott Kassel, Daniel L. DuBois and R. Morris Bullock

Inorg. Chem., 2013, 52, 9975
DOI: 10.1021/ic401232g

Electrocatalytic Dihydrogen Production with a Robust Mesoionic Pyridylcarbene Cobalt Catalyst

Margarethe van der Meer, Estelle Glais, Inke Siewert and Biprajit Sarkar

Angew Chem Int Ed, 2015, 54, 13792
DOI: 10.1002/anie.201506061

Proton-Coupled Electron Transfer: Moving Together and Charging Forward

Sharon Hammes-Schiffer

J. Am. Chem. Soc., 2015, 137, 8860
DOI: 10.1021/jacs.5b04087

Theoretical Modeling of Low‐Energy Electronic Absorption Bands in Reduced Cobaloximes

Anirban Bhattacharjee, Murielle Chavarot‐Kerlidou, Jillian L. Dempsey, Harry B. Gray, Etsuko Fujita, James T. Muckerman, Marc Fontecave, Vincent Artero, Guilherme M. Arantes and Martin J. Field

ChemPhysChem, 2014, 15, 2951
DOI: 10.1002/cphc.201402398

The impact of modifying the ligands on hydrogen production electro-catalyzed by meso-tetra-p-X-phenylporphin cobalt complexes, CoT(X)PP

Yin Liu, Ling-Zhi Fu, Le-Min Yang, Xiao-Ping Liu, Shu-Zhong Zhan and Chun-Lin Ni

Journal of Molecular Catalysis A: Chemical, 2016, 417, 101
DOI: 10.1016/j.molcata.2016.03.020

Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H2 Production

Ming Fang, Eric S. Wiedner, William G. Dougherty, W. Scott Kassel, Tianbiao Liu, Daniel L. DuBois and R. Morris Bullock

Organometallics, 2014, 33, 5820
DOI: 10.1021/om5004607

Electro- and Photocatalytic Hydrogen Production by Molecular Cobalt Complexes With Pentadentate Ligands

Xuan Zhao, Ping Wang and Melissa Long

Comments on Inorganic Chemistry, 2017, 37, 238
DOI: 10.1080/02603594.2016.1266618

The Cobalt Hydride that Never Was: Revisiting Schrauzer’s “Hydridocobaloxime”

David C. Lacy, Gerri M. Roberts and Jonas C. Peters

J. Am. Chem. Soc., 2015, 137, 4860
DOI: 10.1021/jacs.5b01838

A Nickel Dithiolate Water Reduction Catalyst Providing Ligand‐Based Proton‐Coupled Electron‐Transfer Pathways

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Angewandte Chemie, 2017, 129, 4311
DOI: 10.1002/ange.201700927

The Reaction of Cobaloximes with Hydrogen: Products and Thermodynamics

Deven P. Estes, David C. Grills and Jack R. Norton

J. Am. Chem. Soc., 2014, 136, 17362
DOI: 10.1021/ja508200g

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

Ling-Zhi Fu, Ling-Ling Zhou and Shu-Zhong Zhan

Catalysis Communications, 2015, 70, 26
DOI: 10.1016/j.catcom.2015.07.010