Issue 7, 2010
From the journal:

Chemical Communications

Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes†

Lei Jiao,a   Mu Lina  and  Zhi-Xiang Yu*a  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering, College of Chemistry, Peking University, Beijing, China
E-mail: yuzx@pku.edu.cn
Fax: +86-10-6275-1708
Tel: +86-10-6276-7735

Abstract

New Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne and 1-allene-vinylcyclopropanes have been developed, affording an efficient and versatile synthesis of cyclopentane- and cyclopentene-embedded bicyclic structures.

Graphical abstract: Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

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Article information

DOI
https://doi.org/10.1039/B922417C
Article type
Communication
Submitted
26 Oct 2009
Accepted
18 Nov 2009
First published
14 Dec 2009

Chem. Commun., 2010,46, 1059-1061

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Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes

L. Jiao, M. Lin and Z. Yu, Chem. Commun., 2010, 46, 1059 DOI: 10.1039/B922417C

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