Issue 3, 2003
From the journal:

Chemical Communications

Novel supramolecular architectures in group 13 perfluoroaryl complexes. Synthesis and structures of [AlMe(C6F5)(μ-Me)]2 and GaMe(C6F5)2†

Gregory S. Hair,a   Alan H. Cowley,*a   John D. Gorden,a   Jamie N. Jones,a   Richard A. Jones*a  and  Charles L. B. Macdonalda  

* Corresponding authors

a The University of Texas at Austin, Chem. & Biochem. Dept., 1 University Station A5300, Austin, Texas, USA
E-mail: cowley@mail.utexas.edu, rajones@mail.utexas.edu
Tel: 512 471 7484

Abstract

Novel supramolecular architectures are observed in the solid state structures of [AlMe(C6F5)(μ-Me)]2 (1) and Ga(C6F5)2Me (2) via π–π stacking between C6F5 rings and intermolecular aryl-F→Ga interactions, respectively.

Graphical abstract: Novel supramolecular architectures in group 13 perfluoroaryl complexes. Synthesis and structures of [AlMe(C6F5)(μ-Me)]2 and GaMe(C6F5)2

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Article information

DOI
https://doi.org/10.1039/B210024J
Article type
Communication
Submitted
05 Oct 2002
Accepted
12 Dec 2002
First published
15 Jan 2003

Chem. Commun., 2003, 424-425

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Novel supramolecular architectures in group 13 perfluoroaryl complexes. Synthesis and structures of [AlMe(C6F5)(μ-Me)]2 and GaMe(C6F5)2

G. S. Hair, A. H. Cowley, J. D. Gorden, J. N. Jones, R. A. Jones and C. L. B. Macdonald, Chem. Commun., 2003, 424 DOI: 10.1039/B210024J

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