The interaction of (Ph2P)NC(Ph)[N(SiMe3)2] with 1 equivalent of [RuCl2(PPh3)3] in tetrahydrofuran gave [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe3) imino group.
W. Wong, T. Jiang and W. Wong, J. Chem. Soc., Dalton Trans., 1995, 3087 DOI: 10.1039/DT9950003087
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