A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO2

Abstract

A reduced polyoxometalate-based organo-metallophosphate (MOPO) framework formulated as [Co₄(PO₄)(C₇H₈N₄)₆](PW^VI₁₀W^V₂O₄₀) (Co-PO₄-PW₁₂) with an ultra-high CO production rate of 13 676 μmol g⁻¹ h⁻¹ has been presented through photocatalytic CO₂ reduction investigations.