ansa-Half-sandwich complexes of the group 14 elements germanium, tin and lead are reported, which represent a new class of Lewis amphiphilic tetrylenes and bridge the gap between classical N-heterocyclic systems and group 14 metallocenes. These compounds can form complexes both with carbenes and transition metal fragments.
I. Bischoff, B. Morgenstern and A. Schäfer, Chem. Commun., 2022, 58, 8934 DOI: 10.1039/D2CC03107H
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