A chiral tetra-NHC iron(II) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(II) complex yielding three distinct products: an iron(IV) imide, an iron(IV) tetrazene, and a surprising and unprecedented double imide insertion complex.
J. J. Russell, J. F. DeJesus, B. A. Smith, P. Nalaoh, K. D. Vogiatzis and D. M. Jenkins, Dalton Trans., 2024, 53, 10819 DOI: 10.1039/D4DT01422G
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