Themed collection Dehydrogenation and oxidation catalysis
Crystal facet engineering of spinel NiCo2O4 with enhanced activity and water resistance for tuneable catalytic methane oxidation
We use crystal facet engineering to develop NiCo2O4 hexagonal nanosheets with 2 different exposed crystal facets for complete CH4 oxidation. The {111} exposed facet has better resistance to humidity while the {112} facet has better activity.
EES. Catal., 2024,2, 638-646
https://doi.org/10.1039/D3EY00281K
Probing the structure–property relationships of supported copper oxide nanoclusters for methane activation
Amorphous metal-oxide nanoclusters are investigated using DFT and machine learning for selective oxidation of methane.
EES. Catal., 2024,2, 351-364
https://doi.org/10.1039/D3EY00234A
In situ investigation of the mechanochemically promoted Pd–Ce interaction under stoichiometric methane oxidation conditions
A stable Pd0/Pd2+ arrangement generated on Pd/CeO2 prepared by mechanochemistry enables high methane activation rates in the absence of excess oxygen being available.
EES. Catal., 2023,1, 144-152
https://doi.org/10.1039/D2EY00067A
ZSM-5-confined Cr1–O4 active sites boost methane direct oxidation to C1 oxygenates under mild conditions
Cr1–O4 as an active site in the Cr1/ZSM-5 SAC can catalyze the DOM to form value-added C1 oxygenated products with a productivity of 21 100 μmol gcat−1 h−1 and a selectivity of 99.8% at 50 °C within 30 min, which outperforms most state-of-the-art catalysts.
EES. Catal., 2023,1, 153-161
https://doi.org/10.1039/D2EY00080F
Descriptor-based identification of bimetallic-derived catalysts for selective activation of ethane with CO2
Ethane–CO2 reaction over a wide range of bimetallic-derived catalysts was adopted to unravel the structure–function relationship over two types of representative structures.
EES. Catal., 2023,1, 17-25
https://doi.org/10.1039/D2EY00051B
About this collection
EES Catalysis is the home of innovative catalytic technologies. Please find here the topic collection on dehydrogenation and oxidation catalysis. Many chemicals produced for our daily lives rely on dehydrogenation and oxidation catalysis, as well as processes for energy production. Research in this area can vary significantly depending on the reaction, but the collection looks to collate the different reactions to inspire ideas.