Non-flammable electrolytes for high-safety sodium-ion batteries

Sicheng Miao, Ya You, Zhi Wang, Yanan Zhao, Honghong Fan, Xinping Ai, Yuliang Cao and Yongjin Fang

Chem. Soc. Rev., 2025
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Development of non-fluorinated hybrid ester solvents for wide-temperature operation of lithium-ion batteries

Soung Jin Yang, Seungyeop Kang, Joo-Hyun Koo, Gil-Ju Lee, Seung-Gyu Lim, Joo-Seong Kim, Kyoungsuk Jin, Hyun Woo Kim, Hana Yoon and Dong-Joo Yoo

J. Mater. Chem. A, 2025, 13, 7692
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An all-fluorinated electrolyte based on a fluorinated cosolvent toward a high-voltage LRMO cathode

Yuyu Ban, Feng Hai, Weicheng Xue, Wentao Yan, Yunxiao Yang, Xin Gao and Mingtao Li

J. Mater. Chem. A, 2025
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Reviving ether-based electrolytes for sodium-ion batteries

Fangyuan Cheng, Jun Hu, Wen Zhang, Baiyu Guo, Peng Yu, Xueliang Sun and Jian Peng

Energy Environ. Sci., 2025, 18, 6874
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Revisiting the interfacial chemistry of calcium metal anodes: the importance of inorganic-rich solid/electrolyte interfaces derived from an aggregation-dominated electrolyte

Shu Yang, Xianshu Wang, Ruimin Li, Yiming Zhou, Haonan Huang, Mengyuan Zhou, Yunyun Gao, Wanyu Zhao, Yukui Gao, Zhenghui Pan and Xiaowei Yang

Energy Environ. Sci., 2025, 18, 1941
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Synergetic effects of cation and anion of Mg(NO3)2 as electrolyte additives in stabilizing Li metal anode

Hyerim Kim, Jimin Park, Hyokyeong Kang, Sunggun Lim, Shivam Kansara, Zhaowei Sun, Shizhao Xiong, Yun-Chae Jung, Chihyun Hwang, Marco Agostini and Jang-Yeon Hwang

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Revealing the dissolution mechanism of organic carbonyl electrodes in lithium–organic batteries

Shu Zhang, Weiwei Xie, Zhuo Yang, Shuo Xu, Qi Zhao, Yong Lu, Kai Zhang, Zhenhua Yan and Jun Chen

Chem. Sci., 2025, 16, 4335
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Fluorine-free electrolytes in batteries: principles, strategies, and advances

Boligarla Vinay, Yosef Nikodimos, Tripti Agnihotri, Shadab Ali Ahmed, Teklay Mezgebe Hagos, Rehbar Hasan, Elango Balaji Tamilarasan, Wei-Nien Su and Bing Joe Hwang

Energy Environ. Sci., 2025, 18, 7326
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Anion engineering in a single ether solvent electrolyte enables a 4.7 V high-voltage lithium metal battery

Yifan Li, Lipu Sun, Nan Chen, Mai Feng, Boyao Li, Feng Wu, Yuejiao Li and Renjie Chen

Sci. China Chem., 2025
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Research progress on diluents of localized high-concentration electrolytes for high performance lithium metal batteries

Wenjing Ni, Junjie Lu, Yuan Yang, Wanglei Chen, Yunpeng Fu, Zhiye Yuan, Yongkang Han and Jinglun Wang

Journal of Power Sources, 2025, 640, 236704
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Solvation structure manipulation of ester-based electrolyte by acetonitrile additive enables high-capacity and stable K-storage for phenazine-based anode

Xiaokang Chu, Ran Chen, Hang Chen, Hao Wang, Luanjie Nie, Haobo Xia, Qingxue Lai, Zixia Lin, Mengtao Ma, Hao Gong and Jing Zheng

Chemical Engineering Journal, 2024, 500, 157457
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Covariance of interphasic properties and fast chargeability of energy-dense lithium metal batteries

Hyeokjin Kwon, Seongyeong Kim, Jonghyun Hyun, Ha Eun Lee, Seong Su Kim, Yesom Kim, Il Ju Kim, Kyungjae Shin, Sejin Kim, Changhoon Park, Hongsin Kim, Dongseok Shin and Hee-Tak Kim

Nat Energy, 2025
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Multidentate ether modifies solvation structure in nonflammable phosphate electrolytes for wide-temperature lithium-ion batteries

Xiankun Yang, Ziqi Zeng, Mengchuang Liu, Shuping Wang, Changhao Li, Mingsheng Qin and Jia Xie

Commun Chem, 2025, 8
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Research progress and perspectives on rechargeable batteries

Gaojing Yang, Zhimeng Hao, Chun Fang, Wen Zhang, Xia-hui Zhang, Yuyu Li, Zhenhua Yan, Zhiyuan Wang, Tao Sun, Xiaofei Yang, Fei Wang, Chengzhi Zhang, Hongchang Jin, Shuaifeng Lou, Nan Chen, Yiju Li, Jia-Yan Liang, Le Yang, Shouyi Yuan, Jin Niu, Shuai Li, Xu Xu, Dong Wang, Song Jin, Bo-Quan Li, Meng Zhao, Changtai Zhao, Baoyu Sun, Xiaohong Wu, Yuruo Qi, Lili Wang, Nan Li, Bin Qin, Dong Yan, Xin Cao, Ting Jin, Peng Wei, Jing Zhang, Jiaojiao Liang, Li Liu, Ruimin Sun, Zengxi Wei, Xinxin Cao, Kaixiang Lei, Xiaoli Dong, Xijun Xu, Xiaohui Rong, Zhaomeng Liu, Hongbo Ding, Xuanpeng Wang, Zhanheng Yan, Guohui Qin, Guanghai Chen, Yaxin Chen, Ping Nie, Zhi Chang, Fang Wan, Minglei Mao, Zejing Lin, Anxing Zhou, Qiubo Guo, Wen Luo, Xiaodong Shi, Yan Guo, Longtao Ma, Xiangkun Ma, Jiangjiang Duan, Zhizhang Yuan, Jiafeng Lei, Hao Fan, Jinlin Yang, Chao Li, Tong Zhou, Jiabiao Lian, Jin Zhao, Huanxin Ju, Tinglu Song, Zulipiya Shadike, Weiguang Lv, Jiawei Wen, Lingxing Zeng and Jianmin Ma

Chinese Chemical Letters, 2025, 36, 111185
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Low‐Concentration Electrolyte Engineering for Rechargeable Batteries

Zijun Wang, Xiaolin Guo, Yueyao Dong, Wenjie Qu, Ke Wang, Liwei Dong, Chunhui Yang, Zuotao Lei and Jia‐Yan Liang

Advanced Materials, 2025, 37
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Dual-Anion-Modulated Solvation and Flame Retardant Additive Enable Efficient High-Voltage Lithium-Ion Batteries Based on Ni-Rich Cathodes

Chaoyang Zhang, Siyu Wu, Yifei Xiong, Shaoqing Liu, Ying Zhang, Haojie Wan, Yun Li, Rong Zeng and Jianwen Liu

ACS Appl. Energy Mater., 2025, 8, 11089
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Origin of Anion‐Rich Solvation Structures in Siloxane Electrolytes

Yao‐Peng Chen, Yi‐Lin Niu, Zhao Zheng, Xiang Chen, Yu‐Chen Gao, Nan Yao, Rui Zhang and Qiang Zhang

Angewandte Chemie, 2025, 137
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Facilitating ionic transport by bidirectional hydrogen-bond network in solid polymer electrolyte

Xiaobo Zhang, Xucheng Lv, Weihao Song, Wei Guo, Qi Wang and Yingchun Liu

Chemical Engineering Journal, 2025, 511, 161915
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Co‐sustained Release Strategy of Nonflammable Gel Polymer Electrolytes Enables Long‐Life Sodium Metal Batteries

Huiting Yang, Yanjin Chen, Wenyue Tian, Shaohui Yuan, Pei Liu, Qinglun Wang, Ting Jin and Lifang Jiao

Angew Chem Int Ed, 2025, 64
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Electrolyte exchange experiment in batteries: Failure analysis and prospect

Xiaoliang Guo, Hongliang Xie, Zheng Ma, Pushpendra Kumar, Zixu Zhang, Yuqi Wang, Yinghua Chen, Honghong Liang, Jia Wang, Qian Li and Jun Ming

Journal of Energy Chemistry, 2025, 103, 601
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Trace NaBF4 Modulated Ultralow‐Concentration Ether Electrolyte for Durable High‐Voltage Sodium‐Ion Batteries

Shuaiqi Li, Xinrui Song, Pengwei Jing, Xiyue Xiao, Yuecong Chen, Qing Sun, Maxiong Huang, Yiping Zhang, Guosheng Li, Pengyu Liu, Shan Xu, Qingyun Dou, Jian Zhu and Xingbin Yan

Adv Funct Materials, 2025, 35
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Ether‐Oxygen Groups Modified Carboxylic Ester Enabling High‐Voltage Lithium Metal Batteries

Shuang Li, Hongliang Xie, Pushpendra Kumar, Yinghua Chen, Jia Wang, Akang Huang, Wandi Wahyudi, Hui Zhu, Jiao Yin, Qian Li, Zheng Ma and Jun Ming

Angew Chem Int Ed, 2025, 64
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Unveiling the Li/Electrolyte Interface Behavior for Dendrite‐Free All‐Solid‐State Lithium Metal Batteries by Operando Nano‐Focus WAXS

Yuxin Liang, Fabian A.C. Apfelbeck, Kun Sun, Yingying Yan, Lyuyang Cheng, Guangjiu Pan, Tianle Zheng, Yajun Cheng, Anton Davydok, Christina Krywka and Peter Müller‐Buschbaum

Advanced Science, 2025, 12
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A Hybrid Ultrastrong Coordinating Solvent and an Ion-Conductive Diluent for High-Voltage Ether-Based Li-Metal Batteries

Xiaoxin Xie, Junjun Fu, Ruoxi Wang, Jinhui Han, Shu-Meng Hao and Weidong Zhou

J. Am. Chem. Soc., 2025
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A Non‐Concentrated Gradient‐Solvation Electrolyte Enables a High‐Voltage Lithium Metal Battery with 447.6 Wh Kg−1

Hao Wang, Dong Yan, Hongyu Liu, Shuai Li, Xiaobin Niu, Chuying Ouyang, Hong Li and Liping Wang

Advanced Materials, 2025
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Approaching fast ion transport via anion–dipole interaction in weakly solvated electrolytes enables stable Li-plating chemistry

Min Niu, Liwei Dong, Xingyu Chen, Rong-Juan Feng, Qian Li, Hang Qi, Sen Xin, Jia-Yan Liang, Chunhui Yang and Yu-Guo Guo

National Science Review, 2025, 12
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Co‐sustained Release Strategy of Nonflammable Gel Polymer Electrolytes Enables Long‐Life Sodium Metal Batteries

Huiting Yang, Yanjin Chen, Wenyue Tian, Shaohui Yuan, Pei Liu, Qinglun Wang, Ting Jin and Lifang Jiao

Angewandte Chemie, 2025, 137
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Non-clusters pseudo-bilayer solvation sheaths for driving low temperature high power lithium ion batteries

Zhijian Qiu, Yongpeng Cui, Li Zhou, Bingyu Li, Xiuli Gao, Xuejin Li, Pengyun Liu, Zifeng Yan, Qingzhong Xue and Wei Xing

Energy Storage Materials, 2025, 76, 104122
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High-rate, long-lifespan, sustainable potassium-ion batteries enabled by non-fluorinated solvents

Xurun Guo, Hongliang Xie, Pushpendra Kumar, Honghong Liang, Fei Zhao, Yuqi Wang, Tao Cai, Qian Li, Wandi Wahyudi, Hui Zhu, Jiao Yin, Zheng Ma and Jun Ming

Materials Science and Engineering: R: Reports, 2025, 166, 101063
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Interfacial Chemistry and Lithiophilicity Design for High Energy Hybrid Li‐Ion/Metal Batteries in a Wide Temperature Range

Taiyu Lyu, Meina Huang, Jinping Xu, Xin Lin, Xin Xiao, Lizhe Liang, Cheng Zhang, Dechao Wang and Zhifeng Zheng

Adv Funct Materials, 2025, 35
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Research Progress of Electrolytes and Electrodes for Lithium‐ and Sodium‐Ion Batteries at Extreme Temperatures

Xueyang He, Yuhang Ling, Yuhan Wu, Yong Lei, Dawei Cao and Chenglin Zhang

Small, 2025, 21
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Enhancing the Stability of Solid-State Polymer Lithium Metal Batteries by In Situ Construction of a Lithiophilic–Lithiophobic Gradient Solid Electrolyte Interphase

Xiaojuan Zhang, Dongni Zhao, Hui Wang, Liping Mao, Yu Zhu, Zhaoyang Xue, Ningshuang Zhang and Shiyou Li

ACS Appl. Energy Mater., 2025, 8, 8609
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Sulfone-Based Cosolvents Stabilize PF6– to Enable High-Voltage Lithium Metal Batteries

Zhuyu Wang, Zhenkang Wang, Yiwei Zheng, Lifang Zhang, Xi Zhou, Xiaowei Shen, Tianshu Zhang, Tao Qian, Jie Liu and Chenglin Yan

ACS Appl. Energy Mater., 2025, 8, 4784
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Multifunctional Polyfluoride Ionogel‐Encapsulated Lithium Anodes for Durable and Safe Pouch Cells under Harsh Conditions

Ting Li, Anjun Hu, Yuanjian Li, Borui Yang, Kun Li, Kai Chen, Jingyun Jiang, Fei Li, Zhi Wei Seh, Jian Wang and Jianping Long

Adv Funct Materials, 2025
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Origin of Anion‐Rich Solvation Structures in Siloxane Electrolytes

Yao‐Peng Chen, Yi‐Lin Niu, Zhao Zheng, Xiang Chen, Yu‐Chen Gao, Nan Yao, Rui Zhang and Qiang Zhang

Angew Chem Int Ed, 2025, 64
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Competitive Ion Coordination in Gel Polymer Electrolytes Enables Decoupling of Mechanical Strength and Ionic Conductivity

Haonan Wang, Jiaojiao Yang, Xinyan Xu, Jia Geng, Xing Lin, Henghui Xu and Yunhui Huang

Advanced Materials, 2025
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Electrolyte Solvent‐Ion Configuration Deciphering Lithium Plating/Stripping Chemistry for High‐Performance Lithium Metal Battery

Qian Li, Gang Liu, Yinghua Chen, Jia Wang, Pushpendra Kumar, Hongliang Xie, Wandi Wahyudi, Hao Yu, Zexu Wang, Zheng Ma and Jun Ming

Adv Funct Materials, 2025, 35
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Development of PFAS-Free Locally Concentrated Ionic Liquid Electrolytes for High-Energy Lithium and Aluminum Metal Batteries

Xu Liu, Cheng Xu, Henry Adenusi, Yuping Wu and Stefano Passerini

Acc. Chem. Res., 2025, 58, 354
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Anion-diluent synergistic strategy for improved interfacial stability in lithium metal batteries

Xinjing Huang, Xiaozhi Jiang, Chenyang Shi, Mengran Wang, Yangen Zhou, Bo Hong, Jie Li and Yanqing Lai

Energy Storage Materials, 2025, 78, 104239
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Synergistic Ti3C2Tx MXene quantum dot/nanosheet Hybrid: Elevating supercapacitor performance

Bheem Kumar, Avinash Rundla, Priyanka, Mahaveer Singh, Divya Rani, Pushpendra Kumar and Kedar Singh

Journal of Power Sources, 2025, 652, 237603
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Integrating Ethereal Molecular Backbones into the Ester Solvent with High Solubility of Nitrate for High‐Voltage Li Metal Batteries

Yun Shen, Tevin Li, Kaixin Ren, Shouyi Yuan, Kai Ding, Kebao Xia, Junwei Lucas Bao and Yonggang Wang

Advanced Materials, 2025, 37
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Formulating PEO-polycarbonate blends as solid polymer electrolytes by solvent-free extrusion

Francesco Gambino, Matteo Gastaldi, Alia Jouhara, Samuel Malburet, Simone Galliano, Nicola Cavallini, Giovanna Colucci, Marco Zanetti, Alberto Fina, Giuseppe Antonio Elia and Claudio Gerbaldi

Journal of Power Sources Advances, 2024, 30, 100160
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Chemically Active Sulfonate Additive with Transition Metal and Oxygen Dual-Site Deactivation for High-Voltage LiCoO2

Haoyi Yang, Yajun Zhao, Tian Qin, Hongyi Pan, Shuhang Feng, Quan Li, Xuelong Wang, Xiqian Yu and Hong Li

ACS Energy Lett., 2024, 9, 4475
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Ultra-low concentration and flame-retardant electrolyte for next-generation lithium metal batteries

Ziye Wang, Qianchen Wang, Yingshuai Wang, Tinglu Song, Yuhang Xin, Qingbo Zhou, Lei Liu, Amna Safdar, Feng Wu and Hongcai Gao

Journal of Colloid and Interface Science, 2025, 697, 137949
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Localized high-concentration electrolytes for rechargeable batteries

Wanjie Gao, Yi Peng, Yinxu Lu, Xi Liu, Yubo Xu, Kexin Yang, Yuping Wu and Jiarui He

Energy Storage Materials, 2025, 80, 104378
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Strong association dual lithium salts for ether-based electrolyte enable 4.5 V high-voltage lithium metal battery

Lipu Sun, Nan Chen, Yifan Li, Jianing Tian, Binbin Yang, Ziyi Chen, Nuo Chen, Feng Wu, Yuejiao Li and Renjie Chen

Energy Storage Materials, 2025, 78, 104264
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Low-Concentration Electrolyte Design for Wide-Temperature Operation in Sodium Metal Batteries

Qipeng Zhang, Xin Wang, Hao Li and Rui Qiao

J. Electrochem. Soc., 2025, 172, 010501
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Ultralow Concentration Nonflammable Electrolytes Mediated by Intermolecular Interactions for Safer Potassium‐Ion Sulfur Batteries

Qian Li, Gang Liu, Pushpendra Kumar, Fei Zhao, Yuqi Wang, Tao Cai, Yinghua Chen, Hongliang Xie, Wandi Wahyudi, Zheng Ma and Jun Ming

Adv Funct Materials, 2025, 35
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Electrolyte engineering via non-fluorinated solvent for high-performance lithium metal batteries

Dequan Huang, Yi Liang, Tao Wei, Guangda Yin, Yangtao Zhou, Sijiang Hu, Qichang Pan, Fenghua Zheng, Qingyu Li, Yuanhua Chen and Hongqiang Wang

Journal of Colloid and Interface Science, 2025, 690, 137300
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Ether‐Oxygen Groups Modified Carboxylic Ester Enabling High‐Voltage Lithium Metal Batteries

Shuang Li, Hongliang Xie, Pushpendra Kumar, Yinghua Chen, Jia Wang, Akang Huang, Wandi Wahyudi, Hui Zhu, Jiao Yin, Qian Li, Zheng Ma and Jun Ming

Angewandte Chemie, 2025, 137
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Boosting High-Rate Lithium Metal Batteries by Using Ether-Based Gel Polymer Electrolyte

Chenchen Zhang, Zuohang Li, Su Wang, Chen Li, Yuchang Si, Yue Ma, Dawei Song, Hongzhou Zhang, Xixi Shi and Lianqi Zhang

Energy Mater Adv, 2025, 6
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Molecular Engineering of Electrolyte Solvents for Lithium Metal Batteries: Strategies, Challenges, and Prospects

Xiao Zhu and Xiaoli Dong

Batteries & Supercaps, 2025
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Synergistic solvation and interphase design via a steric-electronic additive for ultra-long cycling lithium metal batteries

Min Cheng, Xu Zhou, Yuhang Liang and Yuanhui Zheng

Journal of Energy Chemistry, 2025, 108, 759
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A screening method for film-forming additive in high-voltage graphite/LiCoO2

Siwu Wang, Huajun Guo, Xinhai Li, Zhixing Wang, Wenjie Peng, Jiexi Wang, Hui Duan, Guangchao Li and Guochun Yan

Journal of Electroanalytical Chemistry, 2025, 976, 118788
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Understanding ion-selective Li/Na metal plating behavior in hybrid Li-Na battery

Jehee Park, Kyojin Ku, Seoung-Bum Son, Jihyeon Gim, Stephen E. Trask, Jinhyup Han, Christopher S. Johnson and Eungje Lee

Journal of Power Sources, 2025, 630, 236059
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