Issue 6, 2024

Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks

Abstract

Incremental, single-atom substitutions of Se-based chalcogen bond (Ch-bond) donors with stronger donating Te centers were implemented in two new triptycene tris(1,2,5-chalcogenadiazole) tectons. The appreciably more favorable Ch-bonding ability of the Te-based donors promotes assembly of low-density networks and more stable Ch-bonded organic frameworks (ChOFs).

Graphical abstract: Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
19 oct. 2023
Accepted
12 dic. 2023
First published
21 dic. 2023

Chem. Commun., 2024,60, 758-761

Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks

B. J. Eckstein, H. R. Martin, M. P. Moghadasnia, A. Halder, M. J. Melville, T. N. Buzinski, G. J. Balaich and C. M. McGuirk, Chem. Commun., 2024, 60, 758 DOI: 10.1039/D3CC05162E

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