Issue 7, 2017

A bifunctional covalent organic framework as an efficient platform for cascade catalysis

Abstract

A bifunctional covalent organic framework (COF) has been illustrated in the context of partial metalation of a highly porous and chemically robust pyridine containing COF (COF-TpPa-Py) with Pd species and by taking advantage of the base catalytic behavior of pyridine. The resultant bifunctionalized COF exhibits excellent performance in catalyzing one-pot cascade aerobic oxidation–Knoevenagel condensation reactions, outperforming the corresponding homogeneous and porous organic polymer based catalytic systems, thereby opening a new avenue for multifunctional COFs as a promising platform for heterogeneous cascade catalysis.

Graphical abstract: A bifunctional covalent organic framework as an efficient platform for cascade catalysis

Supplementary files

Article information

Article type
Research Article
Submitted
15 dic. 2016
Accepted
22 ene. 2017
First published
23 ene. 2017

Mater. Chem. Front., 2017,1, 1310-1316

A bifunctional covalent organic framework as an efficient platform for cascade catalysis

Q. Sun, B. Aguila and S. Ma, Mater. Chem. Front., 2017, 1, 1310 DOI: 10.1039/C6QM00363J

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