Issue 2, 2014

Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate

Abstract

Functionalized cyclic carbonate monomers were synthesized via a two step route featuring a novel cyclic carbonate intermediate possessing a pendent activated pentafluorophenyl carbonate group (MTC-PFPC). The pentafluorophenyl carbonate of MTC-PFPC was selectively substituted with suitable nucleophiles such as alcohols, amines and thiols generating functionalized cyclic carbonates in moderate to high yield.

Graphical abstract: Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate

Supplementary files

Article information

Article type
Communication
Submitted
21 ago. 2013
Accepted
15 sep. 2013
First published
23 sep. 2013

Polym. Chem., 2014,5, 327-329

Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate

D. P. Sanders, D. J. Coady, M. Yasumoto, M. Fujiwara, H. Sardon and J. L. Hedrick, Polym. Chem., 2014, 5, 327 DOI: 10.1039/C3PY01128C

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