Issue 24, 2024

Reactivities of phosphaalkynes towards diverse bis-silylenes

Abstract

Bis-silylenes do not only act as strong chelating σ-donor ligands, but also exhibit cooperative behaviour in the activation of small molecules. Three different P–Si containing molecules were prepared from the reaction between tBuC[triple bond, length as m-dash]P and different bis-silylenes, which are bridged by ferrocenediyl, diaminobenzene, or o-carborane.

Graphical abstract: Reactivities of phosphaalkynes towards diverse bis-silylenes

Supplementary files

Article information

Article type
Paper
Submitted
09 may. 2024
Accepted
28 may. 2024
First published
03 jun. 2024
This article is Open Access
Creative Commons BY license

Dalton Trans., 2024,53, 10220-10225

Reactivities of phosphaalkynes towards diverse bis-silylenes

X. Sun, D. Jin, S. Maier, A. Hinz and P. W. Roesky, Dalton Trans., 2024, 53, 10220 DOI: 10.1039/D4DT01367K

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