Issue 24, 2024

Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

Abstract

A general synthetic procedure to neutral homo- and heterobimetallic cage compounds exhibiting various structural motifs of the polypnictogen ligands starting from [Cp*Fe(η5-E5)] (E = P (1), As (2); Cp* = C5Me5) is reported. The impact of the implemented transition metal precursors {Cp′′′M} (M = Cr, Mn, Fe, Ni; Cp′′′ = 1,2,4-tBu3C5H2) emphasises the variability of the isolated complexes exhibiting a broad variety of structural motifs of the pnictogen ligands. Spectroscopic, crystallographic, and theoretical investigations provide insight into the structure of the partially unprecedented polypnictogen ligands.

Graphical abstract: Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

Supplementary files

Article information

Article type
Paper
Submitted
19 abr. 2024
Accepted
24 may. 2024
First published
27 may. 2024

Dalton Trans., 2024,53, 10201-10207

Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

S. B. Dinauer, R. Szlosek, M. Piesch, G. Balázs, S. Reichl, L. Prock, C. Riesinger, M. D. Walter and M. Scheer, Dalton Trans., 2024, 53, 10201 DOI: 10.1039/D4DT01160K

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