Issue 17, 2024

Magnetism of single-doped paramagnetic tin clusters studied using temperature-dependent Stern–Gerlach experiments with enhanced sensitivity: impact of the diamagnetic ligand field and paramagnetic dopant

Abstract

In this work, the magnetic properties of tetrel clusters SnNTM, which are singly doped with transition metals (TM), are investigated. On the one hand, the number of tetrel atoms (N = 11, 12, 14 and 17 with TM = Mn) is varied; on the other hand, different transition metals (N = 14, TM = Cr, Mn, Fe) are studied. Magnetic deflection experiments under cryogenic conditions show that the variation of the number of tetrel atoms strongly changes the magnetic properties of the Mn-doped clusters. It is observed that Sn12Mn, Sn11Mn and Sn14Mn partially show super-atomic behaviour, while spin relaxation occurs in Sn17Mn. Magnetic deflection experiments at higher nozzle temperatures were carried out for the first time enhanced by a second parallel-aligned Stern–Gerlach magnet to achieve larger deflections. The resulting temperature-dependent one-sided deflections are quantitatively analysed using Curie's law and show that Sn17Mn possesses the highest magnetic moment of these clusters, followed by Sn12Mn and Sn11Mn. Sn14Mn shows the lowest magnetic moment. The replacement of Mn by Cr in Sn14Mn leads to a diamagnetic singlet, i.e., the magnetic moment of Cr in Sn14Cr is completely quenched. The replacement of Mn by Fe in turn leads to a paramagnetic species, whereby Sn14Fe is most likely present as a triplet. On this basis, the geometrical and electronic structures are analysed using quantum chemical calculations, indicating an arachno-type structure for Sn14Cr, Sn14Mn and Sn14Fe, which has already been predicted in the literature for Si14Cr. This is experimentally confirmed by deflection of molecular beams with an electric field under cryogenic conditions, suggesting that the arachno-type geometry is crucial for the overall stability of the transition-metal-doped tetrel clusters Sn14TM with TM = Cr, Mn, Fe.

Graphical abstract: Magnetism of single-doped paramagnetic tin clusters studied using temperature-dependent Stern–Gerlach experiments with enhanced sensitivity: impact of the diamagnetic ligand field and paramagnetic dopant

Supplementary files

Article information

Article type
Paper
Submitted
29 feb. 2024
Accepted
26 mar. 2024
First published
19 abr. 2024

Phys. Chem. Chem. Phys., 2024,26, 12982-12992

Magnetism of single-doped paramagnetic tin clusters studied using temperature-dependent Stern–Gerlach experiments with enhanced sensitivity: impact of the diamagnetic ligand field and paramagnetic dopant

F. Rivic and R. Schäfer, Phys. Chem. Chem. Phys., 2024, 26, 12982 DOI: 10.1039/D4CP00890A

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