From the journal:

Chemical Communications

A neutral crystalline imino-substituted silyl radical†

Fiona J. Kiefer,a   Arseni Kostenko, ORCID logo a   Richard Holzner ORCID logo a  and  Shigeyoshi Inoue ORCID logo *a  

* Corresponding authors

a TUM School of Natural Sciences, Department of Chemistry, Wacker-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany
E-mail: s.inoue@tum.de

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Graphical abstract: A neutral crystalline imino-substituted silyl radical

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Article information

DOI
https://doi.org/10.1039/D4CC02167C
Article type
Communication
Submitted
04 may. 2024
Accepted
09 jul. 2024
First published
10 jul. 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024, Advance Article

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A neutral crystalline imino-substituted silyl radical

F. J. Kiefer, A. Kostenko, R. Holzner and S. Inoue, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC02167C

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