Issue 23, 2023

Dimension-dependent intrinsic point defect characteristics of binary photovoltaic materials

Abstract

Point defects play a significant role in determining the crystallinity, optoelectronic properties, and carrier lifetime of photovoltaic materials. The open-circuit voltage (Voc) deficit associated with defects is one of the main factors limiting the power conversion efficiency (PCE) of solar cells. In particular, easily formed deep level defects within the bandgap act as electron–hole non-radiative recombination centers, resulting in Shockley–Read–Hall (SRH) recombination and leading to a large Voc loss. Generally, the formation of point defects in a semiconductor largely relies on its chemical structure. Compared with conventional 2D and 3D semiconductors, the complicated defects located in non-equivalent atomic sites with a low formation energy in asymmetric 1D structures give rise to a large Voc deficit, which is a great challenge towards further improving the solar cell efficiency. In this review, we introduce the dependence of defect properties on the dimensions among the binary compound semiconductors. Finally, effective strategies to improve the P-type conductivity of the material, as well as the mixing of 1D materials with other 2D or 3D materials to construct hybrid-dimensional semiconductor compounds, are proposed to enable defect control. From this, we provide guidance for breaking the bottlenecks of thin film solar cells.

Graphical abstract: Dimension-dependent intrinsic point defect characteristics of binary photovoltaic materials

Article information

Article type
Review Article
Submitted
31 mar. 2023
Accepted
04 ago. 2023
First published
25 ago. 2023

Mater. Chem. Front., 2023,7, 6188-6201

Dimension-dependent intrinsic point defect characteristics of binary photovoltaic materials

Z. Cai, Y. Gu, W. Liang, R. Tang and T. Chen, Mater. Chem. Front., 2023, 7, 6188 DOI: 10.1039/D3QM00333G

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