Issue 6, 2023

Discerning subtle high-pressure phase transitions in glyphosate

Abstract

The common garden herbicide glyphosate, N-(phosphonomethyl)glycine, has been studied between ambient pressure and 5.17 GPa using single crystal X-ray diffraction. Glyphosate forms a structure composed of layers parallel to the (1 0 −2) planes. Hydrogen bonds form along the stacking direction, which are very incompressible so that the effects of pressure are accommodated mostly within the layers. This study has confirmed two high pressure phase transitions previously observed by Raman spectroscopy, enabling the structural signatures of the transitions to be identified. Both transitions are very subtle and second order, involving changes to the way the structure responds to pressure rather than changes to the structure. The first transition occurs between 0.93–1.21 GPa and corresponds to the onset of greater compressibility within the layers. The second transition between 3.78–4.23 GPa is an intramolecular feature signalling a deformation of the molecular backbone. In the absence of a first order phase transition, the packing remains in a compressed form of its ambient pressure form up until the highest pressure measured. A reconstructive phase transition occurs at 5.98 GPa forming a polycrystalline high-pressure phase.

Graphical abstract: Discerning subtle high-pressure phase transitions in glyphosate

Supplementary files

Article information

Article type
Paper
Submitted
02 dic. 2022
Accepted
11 ene. 2023
First published
11 ene. 2023
This article is Open Access
Creative Commons BY license

CrystEngComm, 2023,25, 988-997

Discerning subtle high-pressure phase transitions in glyphosate

C. J. G. Wilson, P. A. Wood and S. Parsons, CrystEngComm, 2023, 25, 988 DOI: 10.1039/D2CE01616H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements