Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes

Nicolas Alexander Riensch; Maximilian Fest; Lars Fritze; Andreas Helbig; Ivo Krummenacher; Holger Braunschweig; Holger Helten

doi:10.1039/D0NJ04297H

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Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes†

Nicolas Alexander Riensch,^a Maximilian Fest,^a Lars Fritze,^a Andreas Helbig,^a Ivo Krummenacher,^a Holger Braunschweig

^a and Holger Helten

*^a

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* Corresponding authors

^a Institute of Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: holger.helten@uni-wuerzburg.de

Abstract

A series of bifuran-bridged bis(triarylboranes) have been synthesized via classical metathesis or catalytic silicon/boron exchange reactions, respectively. The products obtained are strongly luminescent, with quantum yields up to 85%, and reversibly twofold reduced via successive one-electron processes.

This article is part of the themed collection: Boron & Beyond - in celebration of Todd Marder

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DOI: https://doi.org/10.1039/D0NJ04297H
Article type: Communication
Submitted: 26 ago. 2020
Accepted: 23 sep. 2020
First published: 23 sep. 2020

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New J. Chem., 2021,45, 14920-14924

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Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes

N. A. Riensch, M. Fest, L. Fritze, A. Helbig, I. Krummenacher, H. Braunschweig and H. Helten, New J. Chem., 2021, 45, 14920 DOI: 10.1039/D0NJ04297H

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New Journal of Chemistry

Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes†

Abstract

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Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes

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