Issue 94, 2020

Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

Abstract

Catalytically relevant intermediates in carbene transfer reactions from a diazo precursor were investigated using cobalt corrole complexes. Two divergent mechanisms are proposed depending on the oxidation state of the cobalt center. Mechanistically driven factors for the usage of cobalt corroles in carbene transfer reactions are discussed.

Graphical abstract: Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

Supplementary files

Article information

Article type
Communication
Submitted
25 oct. 2020
Accepted
30 oct. 2020
First published
30 oct. 2020

Chem. Commun., 2020,56, 14881-14884

Bridging and axial carbene binding modes in cobalt corrole complexes: effect on carbene transfer

B. W. Musselman and N. Lehnert, Chem. Commun., 2020, 56, 14881 DOI: 10.1039/D0CC07073D

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