Issue 7, 2016

Gold-catalyzed bis(stannylation) of propiolates

Abstract

The first example of gold-catalyzed addition of Sn–Sn bonds to alkynes is reported. A cationic gold(I) complex bearing a phosphite ligand is reported to efficiently catalyze the bis(stannylation) of propiolates with hexabutylditin under mild conditions.

Graphical abstract: Gold-catalyzed bis(stannylation) of propiolates

Supplementary files

Article information

Article type
Research Article
Submitted
28 mar. 2016
Accepted
05 may. 2016
First published
10 may. 2016

Org. Chem. Front., 2016,3, 856-860

Gold-catalyzed bis(stannylation) of propiolates

F. Chahdoura, N. Lassauque, D. Bourissou and A. Amgoune, Org. Chem. Front., 2016, 3, 856 DOI: 10.1039/C6QO00128A

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