Issue 37, 2016

A mononuclear nonheme cobalt(iii)–hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Abstract

A mononuclear nonheme cobalt(III)–hydroperoxide complex bearing a tetramethylated cyclam ligand, [(12-TMC)CoIII(OOH)]2+, was synthesized and characterized spectroscopically and computationally; the cobalt(III)–hydroperoxide complex exhibited an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions.

Graphical abstract: A mononuclear nonheme cobalt(iii)–hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

Supplementary files

Article information

Article type
Communication
Submitted
28 mar. 2016
Accepted
10 may. 2016
First published
10 may. 2016

Dalton Trans., 2016,45, 14511-14515

A mononuclear nonheme cobalt(III)–hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions

W. Tcho, B. Wang, Y. Lee, K. Cho, J. Shearer and W. Nam, Dalton Trans., 2016, 45, 14511 DOI: 10.1039/C6DT01194B

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