Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage

Ilich A. Ibarra; Sihai Yang; Xiang Lin; Alexander J. Blake; Pierre J. Rizkallah; Harriott Nowell; David R. Allan; Neil R. Champness; Peter Hubberstey; Martin Schröder

doi:10.1039/C1CC11168J

Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage†‡

Ilich A. Ibarra,^a Sihai Yang,^a Xiang Lin,^a Alexander J. Blake,^a Pierre J. Rizkallah,^b Harriott Nowell,^c David R. Allan,^c Neil R. Champness,*^a Peter Hubberstey^a and Martin Schröder*^a

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^a School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK
E-mail: M.Schroder@nottingham.ac.uk, Neil.Champness@nottingham.ac.uk
Fax: +44 115 9513563
Tel: +44 115 9513491

^b STFC Daresbury Laboratory, Daresbury Science and Innovation Campus, Warrington, Cheshire, UK

^c Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire, UK

Abstract

The metal–organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc₂(μ₂-OH)(O₂CR)₄] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m² g⁻¹ with a total H₂ uptake of 4.44 wt% at 77 K and 20 bar.

This article is part of the themed collection: Supramolecular Chemistry

Chemical Communications

Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage†‡

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Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage

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