Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[RuIV(tmc)O(Cl)]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

Chi-Ming Che; Kwok-Yin Wong; Thomas C. W. Mak

doi:10.1039/C39850000988

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Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(Cl)]ClO₄(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

Chi-Ming Che, Kwok-Yin Wong and Thomas C. W. Mak

Abstract

Ruthenium(V) mono-oxo complexes electrochemically generated from trans-[Ru^IVLO(Cl)]⁺(L = tmc or 15-tmc; tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane, 15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) are active oxidative catalysts for the conversion of alcohol into aldehyde; X-ray analysis of trans-[Ru^IV(tmc)O(Cl)]ClO₄ yielded Ru [double bond, length half m-dash] O 1.765(7)Å and Ru-Cl 2.505(3)Å.

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DOI: https://doi.org/10.1039/C39850000988
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1985, 988-990

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Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(Cl)]ClO₄(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

C. Che, K. Wong and T. C. W. Mak, J. Chem. Soc., Chem. Commun., 1985, 988 DOI: 10.1039/C39850000988

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Journal of the Chemical Society, Chemical Communications

Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(Cl)]ClO₄(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

Abstract

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Oxo-ruthenium(V) complexes of macrocyclic tetradentate tertiary amines that function as active electrochemical oxidative catalysts, and X-ray crystal structure of trans-[Ru^IV(tmc)O(Cl)]ClO₄(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

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