Issue 38, 2023

Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions

Abstract

The intercalation of H into Pd-based nanocatalysts plays a crucial role in optimizing the catalytic performance by tailoring the structural and electronic properties. We herein present a comprehensive review about the recent progress of interstitial hydrogen atom modified Pd-based nanocatalysts for various energy-related electrocatalytic reactions. Before systematically manifesting the great potential of Pd-based hydrides for electrocatalytic applications, we have briefly illustrated the synthesis strategies and corresponding mechanisms for the Pd-based hydrides. This is followed by a comprehensive discussion about the fundamentals and functions of H intercalation in tailoring their physicochemical and electrochemical properties. Subsequently, we focus on the widespread application of Pd-based hydrides for electrocatalytic reactions, with the emphasis on the role of H intercalation played in determining electrocatalytic performance. Finally, the future direction and perspectives regarding the development of more efficient Pd-based hydrides are also manifested.

Graphical abstract: Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions

Article information

Article type
Perspective
Submitted
13 jul. 2023
Accepted
07 sep. 2023
First published
18 sep. 2023

Dalton Trans., 2023,52, 13452-13466

Recent advances of H-intercalated Pd-based nanocatalysts for electrocatalytic reactions

L. Li, H. Xu, Q. Zhu, X. Meng, J. Xu and M. Han, Dalton Trans., 2023, 52, 13452 DOI: 10.1039/D3DT02201C

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