Issue 41, 2019

Divergent pathway and reactivity control of intramolecular arene C–H vinylation by vinyl cations

Abstract

Vinyl cations exhibit remarkable reactivity towards arene C–H functionalizations. This computational study revealed the key mechanistic details of intramolecular C–H vinylation through a vinyl cation intermediate. Based on the reaction mechanism, the effects of substitution, ring strain and tether length on the reactivity of the vinyl cation were elucidated.

Graphical abstract: Divergent pathway and reactivity control of intramolecular arene C–H vinylation by vinyl cations

Supplementary files

Article information

Article type
Communication
Submitted
01 sep. 2019
Accepted
02 oct. 2019
First published
03 oct. 2019

Org. Biomol. Chem., 2019,17, 9135-9139

Divergent pathway and reactivity control of intramolecular arene C–H vinylation by vinyl cations

X. Li, S. Zhang and X. Hong, Org. Biomol. Chem., 2019, 17, 9135 DOI: 10.1039/C9OB01916B

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