Cross Reference Logo
Citations to this article as recorded by CrossRef and RSC Journals (475 citations).

Direct arylation of alkyl fluorides using in situ mechanochemically generated calcium-based heavy Grignard reagents
Pan Gao, Julong Jiang, Yamato Fukuzawa, Satoshi Maeda, Koji Kubota and Hajime Ito
RSC Mechanochem., 2024, 1, 486
DOI: 10.1039/D4MR00067F

Cationic strontium hydride complexes supported by an NNNN-type macrocycle
Thomas Höllerhage, Ambre Carpentier, Thomas P. Spaniol, Laurent Maron, Ulli Englert and Jun Okuda
Chem. Commun., 2021, 57, 6316
DOI: 10.1039/D1CC02040D

Phosphido complexes derived from 1,1′-ferrocenediyl-bridged secondary diphosphines
Sandra Hitzel, Christian Färber, Clemens Bruhn and Ulrich Siemeling
Dalton Trans., 2017, 46, 6333
DOI: 10.1039/C7DT00941K

Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane
Milan Kumar Bisai, Sanjukta Pahar, Tamal Das, Kumar Vanka and Sakya S. Sen
Dalton Trans., 2017, 46, 2420
DOI: 10.1039/C6DT04893E

Aluminium complex as an efficient catalyst for the chemo-selective reduction of amides to amines
Suman Das, Himadri Karmakar, Jayeeta Bhattacharjee and Tarun K. Panda
Dalton Trans., 2019, 48, 11978
DOI: 10.1039/C9DT01806A

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates
Laia Davin, Alberto Hernán-Gómez, Calum McLaughlin, Alan R. Kennedy, Ross McLellan and Eva Hevia
Dalton Trans., 2019, 48, 8122
DOI: 10.1039/C9DT00923J

Lithium diisobutyl-tert-butoxyaluminum hydride (LDBBA) catalyzed hydroboration of alkynes and imines with pinacolborane
Ashok Kumar Jaladi, Hanbi Kim, Ji Hye Lee, Won Kyu Shin, Hyonseok Hwang and Duk Keun An
New J. Chem., 2019, 43, 16524
DOI: 10.1039/C9NJ03931G

Calcium stannyl formation by organostannane dehydrogenation
Louis J. Morris, Michael S. Hill, Ian Manners, Claire L. McMullin, Mary F. Mahon and Nasir A. Rajabi
Chem. Commun., 2019, 55, 12964
DOI: 10.1039/C9CC07289F

A series of neutral alkaline earth metal hydride complexes supported by a bulky, unsymmetrical β-diketiminate ligand, [{(Dip/TCHPNacnac)M(μ-H)}2] (M = Mg, Ca, Sr or Ba)
Dominic B. Kennedy, Matthew J. Evans, Dafydd D. L. Jones, Joseph M. Parr, Michael S. Hill and Cameron Jones
Chem. Commun., 2024, 60, 10894
DOI: 10.1039/D4CC04286G

Beryllium coordination chemistry and its implications on the understanding of metal induced immune responses
Magnus R. Buchner
Chem. Commun., 2020, 56, 8895
DOI: 10.1039/D0CC03802D

Selective homo- and cross-desilacoupling of aryl and benzyl primary silanes catalyzed by a barium complex
Zhizhou Liu, Xianghui Shi and Jianhua Cheng
Dalton Trans., 2020, 49, 8340
DOI: 10.1039/D0DT01158D

Magnesium amide catalyzed selective hydroboration of esters
Milan Kr. Barman, Ashim Baishya and Sharanappa Nembenna
Dalton Trans., 2017, 46, 4152
DOI: 10.1039/C7DT00556C

Hydrophosphination using [GeCl{N(SiMe3)2}3] as a pre-catalyst
A. N. Barrett, H. J. Sanderson, M. F. Mahon and R. L. Webster
Chem. Commun., 2020, 56, 13623
DOI: 10.1039/D0CC05792D

Simple ZnEt2as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies
Antonio Martínez, Sonia Moreno-Blázquez, Antonio Rodríguez-Diéguez, Alberto Ramos, Rafael Fernández-Galán, Antonio Antiñolo and Fernando Carrillo-Hermosilla
Dalton Trans., 2017, 46, 12923
DOI: 10.1039/C7DT02700A

Synthesis and catalytic activity of tridentate N-(2-pyridylethyl)-substituted bulky amidinates of calcium and strontium
Sven Krieck, Diana Kalden, Ansgar Oberheide, Lydia Seyfarth, Hans-Dieter Arndt, Helmar Görls and Matthias Westerhausen
Dalton Trans., 2019, 48, 2479
DOI: 10.1039/C8DT04905J

Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide
Erwann le Coz, Hanieh Roueindeji, Vincent Dorcet, Thierry Roisnel, Jean-François Carpentier and Yann Sarazin
Dalton Trans., 2019, 48, 5500
DOI: 10.1039/C9DT00771G

Lewis acidic alkaline earth metal complexes with a perfluorinated diphenylamide ligand
Christian A. Fischer, Andreas Rösch, Holger Elsen, Gerd Ballmann, Michael Wiesinger, Jens Langer, Christian Färber and Sjoerd Harder
Dalton Trans., 2019, 48, 6757
DOI: 10.1039/C9DT01272A

Barium complexes with crown-ether-functionalised amidinate and iminoanilide ligands for the hydrophosphination of vinylarenes
Erwann Le Coz, Hanieh Roueindeji, Thierry Roisnel, Vincent Dorcet, Jean-François Carpentier and Yann Sarazin
Dalton Trans., 2019, 48, 9173
DOI: 10.1039/C9DT01512D

Tri-coordinated zinc alkyl complexes with N^S/Se coordination of imino-phosphanamidinate chalcogenide ligands as precursors for efficient hydroboration of nitriles and esters
Himadri Karmakar, Gobbilla Sai Kumar, Kuntal Pal, Vadapalli Chandrasekhar and Tarun K. Panda
Dalton Trans., 2024, 53, 10592
DOI: 10.1039/D4DT00840E

Catalytic active centers beyond transition metals: atomically dispersed alkaline-earth metals for the electroreduction of nitrate to ammonia
Donghai Wu, Peng Lv, Jiarui Wu, Bingling He, Xue Li, Ke Chu, Yu Jia and Dongwei Ma
J. Mater. Chem. A, 2023, 11, 1817
DOI: 10.1039/D2TA08027C

Stoichiometric reactions and catalytic dehydrogenations of amine–boranes with calcium aryloxide
Xizhou Zheng, Jiasu Huang, Yingming Yao and Xin Xu
Chem. Commun., 2019, 55, 9152
DOI: 10.1039/C9CC04698D

Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene
Leon Kapp, Christoph Wölper, Hannah Siera, Gebhard Haberhauer and Stephan Schulz
Chem. Sci., 2024, 15, 4161
DOI: 10.1039/D3SC06842K

Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds
A. A. Trifonov, I. V. Basalov and A. A. Kissel
Dalton Trans., 2016, 45, 19172
DOI: 10.1039/C6DT03913H

Hydrosilylation and hydroboration in a sustainable manner: from Earth-abundant catalysts to catalyst-free solutions
Krzysztof Kuciński and Grzegorz Hreczycho
Green Chem., 2020, 22, 5210
DOI: 10.1039/D0GC01430C

Synthesis of heteroleptic calcium amide complexes via manipulation of the Schlenk equilibrium
Matthew de Vere-Tucker, Alexandra M. Z. Slawin, David B. Cordes and Andreas Stasch
Dalton Trans., 2026, 55, 1708
DOI: 10.1039/D5DT02949J

The complex reactivity of β-diketiminato magnesium(i) dimers towards pinacolborane: implications for catalysis
Dafydd D. L. Jones, Aidan J. R. Matthews and Cameron Jones
Dalton Trans., 2019, 48, 5785
DOI: 10.1039/C9DT01085H

Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study
Dongdong Xu, Chunhui Shan, Yingzi Li, Xiaotian Qi, Xiaoling Luo, Ruopeng Bai and Yu Lan
Inorg. Chem. Front., 2017, 4, 1813
DOI: 10.1039/C7QI00459A

Two-dimensional alkaline-earth metal monohalides in unusually low oxidation states with high performance for ion batteries and electrochemical water splitting
Linlin Liu, Bowen Jiang, Dan Sun, Hanyu Liu, Congwei Xie, Keith Butler and Yu Xie
J. Mater. Chem. A, 2024, 12, 30041
DOI: 10.1039/D4TA05559D

1,4-Dihydropyridyl complexes of magnesium: synthesis by pyridine insertion into the magnesium–silicon bond of triphenylsilyls and catalytic pyridine hydrofunctionalization
L. E. Lemmerz, T. P. Spaniol and J. Okuda
Dalton Trans., 2018, 47, 12553
DOI: 10.1039/C8DT01466C

Cyclooctatetraenyl calcium and strontium amido complexes
Farid M. Sroor, Laure Vendier and Michel Etienne
Dalton Trans., 2018, 47, 12587
DOI: 10.1039/C8DT02257G

Phosphorus mediated imidazolinium to oxazolium ring rearrangement
Deependra Bawari, Solomon Volodarsky, Yael Ginzburg, Kuldeep Jaiswal, Pooja Joshi and Roman Dobrovetsky
Dalton Trans., 2021, 50, 16478
DOI: 10.1039/D1DT03363H

Alkaline earth metals: homometallic bonding
Josef T. Boronski
Dalton Trans., 2024, 53, 33
DOI: 10.1039/D3DT03550F

Dialumenes – arylvs.silyl stabilisation for small molecule activation and catalysis
Catherine Weetman, Amelie Porzelt, Prasenjit Bag, Franziska Hanusch and Shigeyoshi Inoue
Chem. Sci., 2020, 11, 4817
DOI: 10.1039/D0SC01561J

Magnesium, calcium and zinc [N2N′] heteroscorpionate complexes
Mariana Luna Barros, Michael G. Cushion, Andrew D. Schwarz, Zoë R. Turner and Philip Mountford
Dalton Trans., 2019, 48, 4124
DOI: 10.1039/C8DT04985H

Bis-guanidinate magnesium amide-catalyzed hydroboration of nitriles and isocyanides via a substrate-assisted pathway
Sayantan Mukhopadhyay, Smrutirani Padhan, Anubhab Das and Sharanappa Nembenna
Org. Chem. Front., 2026, 13, 350
DOI: 10.1039/D5QO01184A

Heavier alkaline earth and heterobimetallic s-block “ate” complexes of a di(amido)siloxane ligand: solid-state structure and dynamic solution-phase behaviour
Matthew D. Haynes, Andrea O'Reilly, Alice J. M. Poole, Aisling F. Roper, Stefan Thum, Louis J. Morris, Martyn P. Coles, J. Robin Fulton, Sjoerd Harder, Zoë R. Turner and Dermot O'Hare
Dalton Trans., 2025, 54, 4542
DOI: 10.1039/D5DT00044K

Calcium catalyzed enantioselective intramolecular alkene hydroamination with chiral C2-symmetric bis-amide ligands
Philipp C. Stegner, Jonathan Eyselein, Gerd M. Ballmann, Jens Langer, Jochen Schmidt and Sjoerd Harder
Dalton Trans., 2021, 50, 3178
DOI: 10.1039/D1DT00173F

Synthesis, characterisation and reactivity of group 2 complexes with a thiopyridyl scorpionate ligand
Matthew P. Stevens, Emily Spray, Iñigo J. Vitorica-Yrezabal, Kuldip Singh, Vanessa M. Timmermann, Lia Sotorrios, Stuart A. Macgregor and Fabrizio Ortu
Dalton Trans., 2022, 51, 11922
DOI: 10.1039/D2DT02012B

Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates
Matthew J. Evans and Cameron Jones
Chem. Soc. Rev., 2024, 53, 5054
DOI: 10.1039/D4CS00097H

Magnesium–halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex
Alexander Friedrich, Jürgen Pahl, Jonathan Eyselein, Jens Langer, Nico van Eikema Hommes, Andreas Görling and Sjoerd Harder
Chem. Sci., 2021, 12, 2410
DOI: 10.1039/D0SC06321E

Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s
Joanna Hammoud, Fatima Abou-Khalil, Thierry Roisnel, Vincent Dorcet, Christophe Bour, Vincent Gandon, David Lebœuf, Jean-François Carpentier and Yann Sarazin
Dalton Trans., 2020, 49, 13017
DOI: 10.1039/D0DT02573A

Reversible hydrosilane addition to pyridines enabled by low-coordinate Ca(ii) and Yb(ii) hydrides
Alexander N. Selikhov, Mikhail A. Bogachev, Yulia V. Nelyubina, Grigory Yu. Zhigulin, Sergey Yu. Ketkov and Alexander A. Trifonov
Inorg. Chem. Front., 2024, 11, 4336
DOI: 10.1039/D4QI01028K

Barium tetraalkylaluminate complexes supported by the super-bulky hydrotris(pyrazolyl)borate ligand
Xianghui Shi, Zhizhou Liu and Jianhua Cheng
Dalton Trans., 2019, 48, 17919
DOI: 10.1039/C9DT04182F

Alkaline-earth metallacyclic complexes bearing a diborane-bridged tetraamide ligand: synthesis, structure and fluorescence property
Nan Li, Zifeng Zhao, Chao Yu, Botao Wu, Zuqiang Bian, Wen-Xiong Zhang and Zhenfeng Xi
Dalton Trans., 2019, 48, 9067
DOI: 10.1039/C9DT02118C

Catalyst-free and solvent-free hydroboration of alkynes
Ashok Kumar Jaladi, Hyeon Seong Choi and Duk Keun An
New J. Chem., 2020, 44, 13626
DOI: 10.1039/D0NJ02612C

Calcium stilbene complexes: structures and dual reactivity
Andrea Causero, Holger Elsen, Gerd Ballmann, Ana Escalona and Sjoerd Harder
Chem. Commun., 2017, 53, 10386
DOI: 10.1039/C7CC05792J

Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst
Debabrata Mukherjee, Satoru Shirase, Thomas P. Spaniol, Kazushi Mashima and Jun Okuda
Chem. Commun., 2016, 52, 13155
DOI: 10.1039/C6CC06805G

Organometallic and coordination chemistry of the s-block metals
Sjoerd Harder and Warren E. Piers
Dalton Trans., 2018, 47, 12491
DOI: 10.1039/C8DT90148A

Bi(iii)-catalyzed aminooxygenation of propargyl amidines to synthesize 2-fluoroalkyl imidazole-5-carbaldehydes and their decarbonylations
Shan Li, Yajun Li, Bin Feng, Jian Liang, Geyun You, Xiaofeng Liu and Liqing Xian
Chem. Commun., 2020, 56, 6400
DOI: 10.1039/D0CC02143A

Simple s-block metal hydrides for selective hydrogenation of quinoline compounds
Shengyuan Zhang, Hong Wen, Qianru Wang, Yongli Cai, Zhao Li, Liang Liu, Xuanwei Chang, Jianping Guo and Ping Chen
Chem. Sci., 2026, 17, 456
DOI: 10.1039/D5SC07195J

Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands
Darren Willcox, Jamie L. Carden, Adam J. Ruddy, Paul D. Newman and Rebecca L. Melen
Dalton Trans., 2020, 49, 2417
DOI: 10.1039/D0DT00232A

Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand
Caspar N. de Bruin-Dickason, Thomas Sutcliffe, Carlos Alvarez Lamsfus, Glen B. Deacon, Laurent Maron and Cameron Jones
Chem. Commun., 2018, 54, 786
DOI: 10.1039/C7CC09362D

Diborane heterolysis: breaking and making B–B bonds at magnesium
Anne-Frédérique Pécharman, Michael S. Hill and Mary F. Mahon
Dalton Trans., 2018, 47, 7300
DOI: 10.1039/C8DT01451E

Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands
Yu Zhang, Xinxin Wang, Yaorong Wang, Dan Yuan and Yingming Yao
Dalton Trans., 2018, 47, 9090
DOI: 10.1039/C8DT02122H

Bis(trimethylsilyl)amide complexes of s-block metals with bidentate ether and amine ligands
Philipp Schüler, Helmar Görls, Matthias Westerhausen and Sven Krieck
Dalton Trans., 2019, 48, 8966
DOI: 10.1039/C9DT01426H

Lithium and magnesium complexes by using pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and application as catalysts for the hydroboration of carbonyl compounds
Yafei Li, Huifen Pan, Yanhua Lu, Yanshu Luo, Yan Dang, Yalan Wang, Shengwang Xia, Yahong Li and Yuanzhi Xia
Dalton Trans., 2022, 51, 3616
DOI: 10.1039/D1DT03235F

Snapshots of magnesium-centred diborane heterolysis by an outer sphere SN2 process
Anne-Frédérique Pécharman, Michael S. Hill, Grace McMullon, Claire L. McMullin and Mary F. Mahon
Chem. Sci., 2019, 10, 6672
DOI: 10.1039/C9SC02087J

9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides
Alberto Ramos, Antonio Antiñolo, Fernando Carrillo-Hermosilla, Rafael Fernández-Galán and Daniel García-Vivó
Chem. Commun., 2019, 55, 3073
DOI: 10.1039/C9CC00593E

Recent advances in the application of calcium(ii) triflimide in organic synthesis
Haoran Li, Minyao Kuang, Yuwei Liu, Wei Yi and Shengdong Wang
Org. Chem. Front., 2025, 12, 1355
DOI: 10.1039/D4QO02164A

Highly Lewis acidic cationic alkaline earth metal complexes
Jürgen Pahl, Steffen Brand, Holger Elsen and Sjoerd Harder
Chem. Commun., 2018, 54, 8685
DOI: 10.1039/C8CC04083D

Enantiopure dimagnesium(i) and magnesium(ii) hydride complexes incorporating chiral amidinate or β-diketiminate ligands
Caspar N. de Bruin-Dickason, Christopher A. Rosengarten, Glen B. Deacon and Cameron Jones
Chem. Commun., 2021, 57, 1599
DOI: 10.1039/D0CC07947B

A versatile nitrogen ligand for alkaline-earth chemistry
Peter M. Chapple, Marie Cordier, Vincent Dorcet, Thierry Roisnel, Jean-François Carpentier and Yann Sarazin
Dalton Trans., 2020, 49, 11878
DOI: 10.1039/D0DT02236E

s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols
Michael Fairley, Laia Davin, Alberto Hernán-Gómez, Joaquín García-Álvarez, Charles T. O'Hara and Eva Hevia
Chem. Sci., 2019, 10, 5821
DOI: 10.1039/C9SC01598A

Metal–metal bonded alkaline-earth distannyls
Peter M. Chapple, Julien Cartron, Ghanem Hamdoun, Samia Kahlal, Marie Cordier, Hassan Oulyadi, Jean-François Carpentier, Jean-Yves Saillard and Yann Sarazin
Chem. Sci., 2021, 12, 7098
DOI: 10.1039/D1SC00436K

Reactivity of a quasi-four-coordinate butylmagnesium cation
Ankur, Deepti Sharma, Alex P. Andrews and Ajay Venugopal
Dalton Trans., 2023, 52, 1533
DOI: 10.1039/D3DT00018D

An anionic beryllium hydride dimer with an exceedingly short Be⋯Be distance
Terrance J. Hadlington
Dalton Trans., 2024, 53, 882
DOI: 10.1039/D3DT03976E

Controlled reduction of isocyanates to formamides using monomeric magnesium
Rohit Kumar, Vishal Sharma, Subhrashis Banerjee, Kumar Vanka and Sakya S. Sen
Chem. Commun., 2023, 59, 2255
DOI: 10.1039/D3CC00036B

Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated CO bond cleavage
Yan Yang, Mathew D. Anker, Jian Fang, Mary F. Mahon, Laurent Maron, Catherine Weetman and Michael S. Hill
Chem. Sci., 2017, 8, 3529
DOI: 10.1039/C7SC00117G

Alkaline earth metals: heterometallic bonding
Liam P. Griffin and Josef T. Boronski
Dalton Trans., 2025, 54, 13020
DOI: 10.1039/D5DT01662B

Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study
Yougourthen Boumekla, Fengjie Xia, Lucas Vidal, Cédric Totée, Christophe Raynaud and Armelle Ouali
Org. Biomol. Chem., 2023, 21, 1038
DOI: 10.1039/D2OB02243E

Generation of organo-alkaline earth metal complexes from non-polar unsaturated molecules and their synthetic applications
Kohei Watanabe, Jia Hao Pang, Ryo Takita and Shunsuke Chiba
Chem. Sci., 2022, 13, 27
DOI: 10.1039/D1SC05724C

Prediction of formation probability of rare earth uranates inside nuclear reactor fuel from the determined oxygen potential using a solid oxide galvanic cell
Manjulata Sahu, Sumanta Mukherjee, Geeta R. Patkare, Smruti Dash and M. K. Saxena
New J. Chem., 2021, 45, 9636
DOI: 10.1039/D1NJ00855B

Soft interactions with hard Lewis acids: generation of mono- and dicationic alkaline-earth metal arene-complexes by direct oxidation
Marcel Schorpp and Ingo Krossing
Chem. Sci., 2020, 11, 2068
DOI: 10.1039/C9SC06254H

Salt metathesis routes to homoleptic near-linear Mg(ii) and Ca(ii) bulky bis(silyl)amide complexes
Ji-Dong Leng, Conrad A. P. Goodwin, Iñigo. J. Vitorica-Yrezabal and David P. Mills
Dalton Trans., 2018, 47, 12526
DOI: 10.1039/C8DT00802G

Calcium complexes with imino-phosphinanilido chalcogenide ligands for heterofunctionalisation catalysis
Srinivas Anga, Jean-François Carpentier, Tarun K. Panda, Thierry Roisnel and Yann Sarazin
RSC Adv., 2016, 6, 57835
DOI: 10.1039/C6RA13117D

Catalyst-free and solvent-free hydroboration of ketones
Weifan Wang, Man Luo, Weiwei Yao, Mengtao Ma, Sumod A. Pullarkat, Li Xu and Pak-Hing Leung
New J. Chem., 2019, 43, 10744
DOI: 10.1039/C9NJ02722J

Recent progress in beryllium organometallic chemistry
Darakshan Parveen, Rahul Kumar Yadav and Dipak Kumar Roy
Chem. Commun., 2024, 60, 1663
DOI: 10.1039/D3CC04844F

Zinc catalyzed chemoselective hydrofunctionalization of cyanamides
Sagrika Rajput, Rajata Kumar Sahoo, Nithya M. T. and Sharanappa Nembenna
Chem. Commun., 2024, 60, 11148
DOI: 10.1039/D4CC03972F

Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones
Milan Kumar Bisai, Tamal Das, Kumar Vanka and Sakya S. Sen
Chem. Commun., 2018, 54, 6843
DOI: 10.1039/C8CC02314J

Ditopic bis(N,N′,N′-substituted 1,2-ethanediamine) ligands: synthesis and coordination chemistry
Andreas Rösch, Christoph M. Herzog, Simon H. F. Schreiner, Helmar Görls and Robert Kretschmer
Dalton Trans., 2020, 49, 13818
DOI: 10.1039/D0DT03124K

Magnesium hydrides bearing sterically demanding amidinate ligands: synthesis, reactivity and catalytic application
Clare Bakewell
Dalton Trans., 2020, 49, 11354
DOI: 10.1039/D0DT02523B

PCP and POCOP complexes of calcium
Alessandro Messori, Marcel Potocnik, Sara Belazregue, Richard Collins, Tobias Krämer and F. Mark Chadwick
Chem. Commun., 2025, 61, 7827
DOI: 10.1039/D5CC00872G

Reversible addition and hydrogenation of 1,1-diphenylethylene with a barium complex
Xianghui Shi and Jianhua Cheng
Dalton Trans., 2019, 48, 8565
DOI: 10.1039/C9DT01874C

Nature inspired singlet oxygen generation to access α-amino carbonyl compoundsvia1,2-acyl migration
Waldemar Schilling, Yu Zhang, Prakash Kumar Sahoo, Samir Kumar Sarkar, Sivaraman Gandhi, Herbert W. Roesky and Shoubhik Das
Green Chem., 2021, 23, 379
DOI: 10.1039/D0GC03555F

Hydroxypyridinone based chelators: a molecular tool for fluorescence sensing and sensitization
Shalini Singh, Neha Kumari, B. K. Kanungo and Minati Baral
Sens. Diagn., 2024, 3, 968
DOI: 10.1039/D3SD00346A

Boron carbonyl complexes analogous to hydrocarbons
Jiaye Jin and Mingfei Zhou
Dalton Trans., 2018, 47, 17192
DOI: 10.1039/C8DT03236J

Solvent-free hydrosilylation of carbonyl compounds catalyzed by organotin(iv) compounds
Debayan Basu, Sudipta Chakraborty, Gourav Chakraborty, Saptarshi Bhattacharya, Niladri Patra and Hari Pada Nayek
Dalton Trans., 2025, 54, 10614
DOI: 10.1039/D5DT01033K

Frustrated Lewis pair-ligated tetrelenes
Alvaro A. Omaña, Brandon L. Frenette, Eike Dornsiepen, Ryo Kobayashi, Michael J. Ferguson, Takeaki Iwamoto and Eric Rivard
Dalton Trans., 2023, 52, 774
DOI: 10.1039/D2DT03807B

Boron–nitrogen main chain analogues of polystyrene: poly(B-aryl)aminoboranes via catalytic dehydrocoupling
Diego A. Resendiz-Lara, Naomi E. Stubbs, Marius I. Arz, Natalie E. Pridmore, Hazel A. Sparkes and Ian Manners
Chem. Commun., 2017, 53, 11701
DOI: 10.1039/C7CC07331C

Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand
S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda
Dalton Trans., 2017, 46, 1761
DOI: 10.1039/C6DT04654A

Synthesis and molecular structures of divalent bridged bis(guanidinate) europium complexes and their application in intermolecular hydrophosphination of alkenes and alkynes
Qianqian Liu, Chuanyong Wang, Xingmin Zhang, Mingqiang Xue, Yingming Yao, Yong Zhang and Qi Shen
New J. Chem., 2016, 40, 10447
DOI: 10.1039/C6NJ02508K

ZnCl2-catalysed transfer hydrogenation of carbonyls and chemoselective reduction of the CC bond in α,β-unsaturated ketones
Sonu Sheokand, Sunita Sharma, Manali A. Mohite, Gopalan Rajaraman and Maravanji S. Balakrishna
Chem. Commun., 2024, 60, 7733
DOI: 10.1039/D4CC02700K

Uncovering the role of boronic acids and boroxines in the catalytic hydroboration of alkenes
Ryan Perry, Candace Richardson, Dustin Kenefake, Vani Gupta, Daniel Rose, Charles Leist, Suresh Mummadi and Clemens Krempner
Catal. Sci. Technol., 2026, 16, 1973
DOI: 10.1039/D5CY01394A

Nascent developments in main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes
Arumugam Vignesh, Jiahao Liu, Zhe Wang, Yan Liu and Zhuofeng Ke
Org. Chem. Front., 2024, 11, 576
DOI: 10.1039/D3QO01777J

A cationic aluminium complex: an efficient mononuclear main-group catalyst for the cyanosilylation of carbonyl compounds
Mahendra Kumar Sharma, Soumen Sinhababu, Goutam Mukherjee, Gopalan Rajaraman and Selvarajan Nagendran
Dalton Trans., 2017, 46, 7672
DOI: 10.1039/C7DT01760J

Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines
Adi E. Nako, Juzo Oyamada, Masayoshi Nishiura and Zhaomin Hou
Chem. Sci., 2016, 7, 6429
DOI: 10.1039/C6SC02129H

Barium phosphidoboranes and related calcium complexes
Gabriel Duneş, Peter M. Chapple, Samia Kahlal, Thierry Roisnel, Jean-François Carpentier, Jean-Yves Saillard and Yann Sarazin
Dalton Trans., 2024, 53, 6892
DOI: 10.1039/D4DT00487F

Tethered cationic alkaline earth – olefin complexes
Sorin-Claudiu Roşca, Vincent Dorcet, Thierry Roisnel, Jean-François Carpentier and Yann Sarazin
Dalton Trans., 2017, 46, 14785
DOI: 10.1039/C7DT03300A

Beryllium compounds for the carbon–halogen bond activation of phenyl halides: the role of non-innocent ligands
Daniel E. Trujillo-González, Gerardo González-García, J. Oscar C. Jiménez-Halla and Miquel Solà
Dalton Trans., 2023, 52, 13068
DOI: 10.1039/D3DT02251J

Organomagnesium amide catalyzed cross-dehydrocoupling of organosilanes with amines
Ashim Baishya, Thota Peddarao and Sharanappa Nembenna
Dalton Trans., 2017, 46, 5880
DOI: 10.1039/C7DT00806F

Recent advances in low oxidation state aluminium chemistry
Katie Hobson, Claire J. Carmalt and Clare Bakewell
Chem. Sci., 2020, 11, 6942
DOI: 10.1039/D0SC02686G

Group 2 metal (Mg, Ca, Sr) silylamides supported by a cyclen-derived macrocyclic polyamine
Debabrata Mukherjee, Satoru Shirase, Klaus Beckerle, Thomas P. Spaniol, Kazushi Mashima and Jun Okuda
Dalton Trans., 2017, 46, 8451
DOI: 10.1039/C7DT01727H

Fluorenyl-tethered N-heterocyclic carbene (NHC): an exclusive C-donor ligand for heteroleptic calcium and strontium chemistry
Sumana Mondal, Subham Sarkar, Chhotan Mandal, Dibyendu Mallick and Debabrata Mukherjee
Chem. Commun., 2024, 60, 4553
DOI: 10.1039/D4CC00397G

Catalytic and non-catalytic hydroboration of carbonyls: quantum-chemical studies
Mateusz Nowicki, Krzysztof Kuciński, Grzegorz Hreczycho and Marcin Hoffmann
Org. Biomol. Chem., 2021, 19, 3004
DOI: 10.1039/D1OB00037C

Reduction of 1,3,5,7-cyclooctatetraene by a molecular calcium hydride: an even electron polarised insertion/deprotonation mechanism
Michael S. Hill, Mary F. Mahon, Andrew S. S. Wilson, Chiara Dinoi, Laurent Maron and Emma Richards
Chem. Commun., 2019, 55, 5732
DOI: 10.1039/C9CC02418B

Magnesium bis(amidinate) and bis(guanidinate) complexes: impact of the ligand backbone and bridging groups on the coordination behaviour
Andreas Rösch, Simon H. F. Schreiner, Philipp Schüler, Helmar Görls and Robert Kretschmer
Dalton Trans., 2020, 49, 13072
DOI: 10.1039/D0DT01923B

Sterically bulky amido magnesium methyl complexes: syntheses, structures and catalysis
Mengtao Ma, Jia Li, Xingchao Shen, Zhijuan Yu, Weiwei Yao and Sumod A. Pullarkat
RSC Adv., 2017, 7, 45401
DOI: 10.1039/C7RA08836A

Magnesium halide-catalyzed hydroboration of isocyanates and ketones
Jinyi Shi, Man Luo, Xuguang Zhang, Taoyue Yuan, Xiaoyan Chen and Mengtao Ma
Org. Biomol. Chem., 2023, 21, 3628
DOI: 10.1039/D3OB00531C

Tunable reducibility of alkaline earth metal clusters for carbon dioxide and nitrogen molecule activation: a QM-QSPR study
Natalia Wiszowska, Natalia Rogoża and Celina Sikorska
Phys. Chem. Chem. Phys., 2025, 27, 23468
DOI: 10.1039/D5CP02913A

N^Nvs.N^E (E = S or Se) coordination behavior of imino-phosphanamidinate chalcogenide ligands towards aluminum alkyls: efficient hydroboration catalysis of nitriles, alkynes, and alkenes
Himadri Karmakar, Ravi Kumar, Jyoti Sharma, Jayanta Bag, Kuntal Pal, Tarun K. Panda and Vadapalli Chandrasekhar
Dalton Trans., 2023, 52, 4481
DOI: 10.1039/D3DT00038A

Iron catalysed selective reduction of esters to alcohols
Sem Raj Tamang, Anthony F. Cozzolino and Michael Findlater
Org. Biomol. Chem., 2019, 17, 1834
DOI: 10.1039/C8OB02661K

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes
Lucas A. Freeman, Jacob E. Walley, Diane A. Dickie and Robert J. Gilliard
Dalton Trans., 2019, 48, 17174
DOI: 10.1039/C9DT03915E

Synthesis and reactivity of alkaline-earth stannanide complexes by hydride-mediated distannane metathesis and organostannane dehydrogenation
Louis J. Morris, Nasir A. Rajabi, Mary F. Mahon, Ian Manners, Claire L. McMullin and Michael S. Hill
Dalton Trans., 2020, 49, 10523
DOI: 10.1039/D0DT02406F

Advances in the understanding of molecular beryllium element bonding
Magnus R. Buchner
Chem. Commun., 2025, 61, 11146
DOI: 10.1039/D5CC03056K

Borataalkenes, boraalkenes, and the η2-B,C coordination mode in coordination chemistry and catalysis
Maxwell Eaton, Yuanzhe Zhang and Shih-Yuan Liu
Chem. Soc. Rev., 2024, 53, 1915
DOI: 10.1039/D3CS00730H

Carbonyl-functionalized metallic ionic liquids via coordination for efficient hydrogen sulfide separation and conversion using α,β-unsaturated carboxylate esters
Keyi Huang, Chengqi Zhao, Zixuan Xu, Qing Zhao, Huiqin Xu, Xiaomin Zhang, Leizhi Zheng and Youting Wu
Green Chem., 2026, 28, 2578
DOI: 10.1039/D5GC05393E

Ultrafast scale-up synthesis of calcium rod/layer MOFs and luminescence detection of water in organic solvents
Yonghong Xiao, Zhi-Hong Lin, Mian Li and Xiao-Chun Huang
Mater. Adv., 2020, 1, 689
DOI: 10.1039/D0MA00038H

Direct arylation of gem-difluorostyrenes using in situ mechanochemically generated calcium-based heavy Grignard reagents
Xihong Wang, Yamato Fukuzawa, Pan Gao, Julong Jiang, Satoshi Maeda, Koji Kubota and Hajime Ito
RSC Mechanochem., 2025, 2, 256
DOI: 10.1039/D4MR00135D

Main group bimetallic partnerships for cooperative catalysis
Jose M. Gil-Negrete and Eva Hevia
Chem. Sci., 2021, 12, 1982
DOI: 10.1039/D0SC05116K

s-Block chemistry in weakly coordinating solvents
Magnus R. Buchner and Lewis R. Thomas-Hargreaves
Dalton Trans., 2021, 50, 16916
DOI: 10.1039/D1DT03443J

Transforming lanthanide and actinide chemistry with nanoparticles
Roger M. Pallares and Rebecca J. Abergel
Nanoscale, 2020, 12, 1339
DOI: 10.1039/C9NR09175K

Low-valent germanium and tin hydrides as catalysts for hydroboration, hydrodeoxygenation (HDO), and hydrodesulfurization (HDS) of heterocumulenes
Sayantan Mukhopadhyay, Rajata Kumar Sahoo, A. Ganesh Patro, Anwesh Prasad Khuntia and Sharanappa Nembenna
Dalton Trans., 2024, 53, 18207
DOI: 10.1039/D3DT04080A

Recent advancements in magnesium-mediated organic transformations
Inder Kumar, Manisha, Ritika Sharma and Upendra Sharma
Chem. Commun., 2026, 62, 4963
DOI: 10.1039/D5CC06257H

Aluminium complex-catalysed hydroboration of alkenes and alkynes
Adimulam Harinath, Indrani Banerjee, Jayeeta Bhattacharjee and Tarun K. Panda
New J. Chem., 2019, 43, 10531
DOI: 10.1039/C9NJ01859J

An aldehyde-stabilised alkoxyaluminium dication
Annabel Benny, Devika Vijayan, Rajeshkumar Thayalan, Laurent Maron and Ajay Venugopal
Chem. Commun., 2025, 61, 16074
DOI: 10.1039/D5CC04034E

Reversible borohydride formation from aluminium hydrides and {H(9-BBN)}2: structural, thermodynamic and reactivity studies
Alexa Caise, Eugene L. Kolychev, Jamie Hicks, M. Ángeles Fuentes, Jose M. Goicoechea and Simon Aldridge
Dalton Trans., 2019, 48, 10845
DOI: 10.1039/C9DT00535H

Hydroboration and hydrosilylation of alkenes catalyzed by an unsymmetrical magnesium methyl complex
Xuguang Zhang, Kai Lu, Xi Chen, Guanxin Su, Xiaofei Rong and Mengtao Ma
Org. Biomol. Chem., 2024, 22, 5353
DOI: 10.1039/D4OB00745J

Mononuclear calcium complex as effective catalyst for alkenes hydrogenation
Xianghui Shi, Cuiping Hou, Lanxiao Zhao, Peng Deng and Jianhua Cheng
Chem. Commun., 2020, 56, 5162
DOI: 10.1039/D0CC01745K

Bora-amidinate as a cooperative ligand in group 2 metal catalysis
Benjamin Freitag, Christian A. Fischer, Johanne Penafiel, Gerd Ballmann, Holger Elsen, Christian Färber, Dirk F. Piesik and Sjoerd Harder
Dalton Trans., 2017, 46, 11192
DOI: 10.1039/C7DT02136D

Two Carbenes versus One in Magnesium Chemistry: Synthesis of Terminal Dihalide, Dialkyl, and Grignard Reagents
Yuen Onn Wong, Lucas A. Freeman, A. Danai Agakidou, Diane A. Dickie, Charles Edwin Webster and Robert J. Gilliard
Organometallics, 2019, 38, 688
DOI: 10.1021/acs.organomet.8b00866

Bismuth Pyridine Dipyrrolide Complexes: a Transient Bi(II) Species Which Ring Opens Cyclic Ethers
Zoë R. Turner
Inorg. Chem., 2019, 58, 14212
DOI: 10.1021/acs.inorgchem.9b02314

Distannadithiophenes and Their Application towards Hydroboration of Carbonyl Compounds
Shreenibasa Sa, Joseph S. Ponniah, Priyabrata Biswal, Venkatesan Sathesh, Anna Chandrasekar Murali and Krishnan Venkatasubbaiah
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200283

Enantioselective Main Group Catalysis: Modern Catalysts for Organic Transformations
Lewis C. Wilkins and Rebecca L. Melen
Coordination Chemistry Reviews, 2016, 324, 123
DOI: 10.1016/j.ccr.2016.07.011

Monomeric Magnesium Catalyzed Alkene and Alkyne Hydroboration
Rohit Kumar, Sayan Dutta, Vishal Sharma, Praval P. Singh, Rajesh G. Gonnade, Debasis Koley and Sakya S. Sen
Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201896

Cyclic(alkyl)(amino) Carbene-Promoted Ring Expansion of a Carbodicarbene Beryllacycle
Jacob E. Walley, Akachukwu D. Obi, Grace Breiner, Guocang Wang, Diane A. Dickie, Andrew Molino, Jason L. Dutton, David J. D. Wilson and Robert J. Gilliard
Inorg. Chem., 2019, 58, 11118
DOI: 10.1021/acs.inorgchem.9b01643

Molekulare Magnesiumhydride
Debabrata Mukherjee and Jun Okuda
Angewandte Chemie, 2018, 130, 1472
DOI: 10.1002/ange.201708592

Coordination Chemistry of N‐(2‐Pyridylethyl)‐Substituted Bulky Amidinates and Triazenides of Magnesium
Diana Kalden, Sven Krieck, Helmar Görls and Matthias Westerhausen
Eur J Inorg Chem, 2018, 2018, 4361
DOI: 10.1002/ejic.201800890

A Well‐Defined Calcium Compound Catalyzes Trimerization of Arylisocyanates into 1,3,5‐Triarylisocyanurates
Rohit Kumar, Vishal Sharma, Shailja Jain, Himanshu Sharma, Kumar Vanka and Sakya S. Sen
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202101788

A novel case of atom-efficient C-C bond formation of small molecules catalyzed by the facile organoaluminum compound
Yunzhou Zhao, Xiaoli Ma, Ben Yan, Congjian Ni, Xing He, Yangfan Peng and Zhi Yang
Journal of Organometallic Chemistry, 2021, 946-947, 121879
DOI: 10.1016/j.jorganchem.2021.121879

Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)‐Centre: Labile Mono‐ and Bis(hydridogallyl)zinc Complexes
Louis J. Morris, Thayalan Rajeshkumar, Laurent Maron and Jun Okuda
Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201480

Dibenzotropylidene Substituted Ligands for Early Main Group Metal‐Alkene Bonding
Johannes Martin, Jens Langer, Michael Wiesinger, Holger Elsen and Sjoerd Harder
Eur J Inorg Chem, 2020, 2020, 2582
DOI: 10.1002/ejic.202000524

Cobalt-catalyzed hydro-difluoromethylthiolation/hydro-trifluoromethylthiolation of unactivated alkenes
Xinxin Shao, Xin Hong, Long Lu and Qilong Shen
Tetrahedron, 2019, 75, 4156
DOI: 10.1016/j.tet.2019.05.061

Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
Sem Raj Tamang and Michael Findlater
Molecules, 2019, 24, 3194
DOI: 10.3390/molecules24173194

Calcium‐Catalyzed Arene C−H Bond Activation by Low‐Valent AlI
Steffen Brand, Holger Elsen, Jens Langer, Samuel Grams and Sjoerd Harder
Angew Chem Int Ed, 2019, 58, 15496
DOI: 10.1002/anie.201908978

Magnesium Catalysis for the Hydroboration of Carbodiimides
Catherine Weetman, Michael S. Hill and Mary F. Mahon
Chemistry A European J, 2016, 22, 7158
DOI: 10.1002/chem.201600681

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane
Feng Wang, Oriol Planas and Josep Cornella
J. Am. Chem. Soc., 2019, 141, 4235
DOI: 10.1021/jacs.9b00594

Main Group Metal‐Mediated Transformations of Imines
Samantha A. Orr, Philip C. Andrews and Victoria L. Blair
Chemistry A European J, 2021, 27, 2569
DOI: 10.1002/chem.202003108

1,2-Bis(anilido)ethane Complexes of Calcium and Potassium: Synthesis, Structures, and Catalytic Activity
Steffen Ziemann, Sven Krieck, Helmar Görls and Matthias Westerhausen
Organometallics, 2018, 37, 924
DOI: 10.1021/acs.organomet.7b00890

Magnesium-Catalyzed Regioselective Hydrophosphinylation of Alkenes with Diarylphosphine Oxides
Lei Zhang, Shaokun Bai and Lijiao Zheng
Organometallics, 2023, 42
DOI: 10.1021/acs.organomet.3c00247

The Hidden Role of Boranes and Borohydrides in Hydroboration Catalysis
Andrew D. Bage, Kieran Nicholson, Thomas A. Hunt, Thomas Langer and Stephen P. Thomas
ACS Catal., 2020, 10, 13479
DOI: 10.1021/acscatal.0c04051

Alkaline Earth–Olefin Complexes with Secondary Interactions
Sorin‐Claudiu Roşca, Chiara Dinoi, Elsa Caytan, Vincent Dorcet, Michel Etienne, Jean‐François Carpentier and Yann Sarazin
Chemistry A European J, 2016, 22, 6505
DOI: 10.1002/chem.201601096

P–N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform
Yi-Chun Lin, Emmanuel Hatzakis, Sean M. McCarthy, Kyle D. Reichl, Ting-Yi Lai, Hemant P. Yennawar and Alexander T. Radosevich
J. Am. Chem. Soc., 2017, 139, 6008
DOI: 10.1021/jacs.7b02512

Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15
Jeffrey M. Lipshultz, Gen Li and Alexander T. Radosevich
J. Am. Chem. Soc., 2021, 143, 1699
DOI: 10.1021/jacs.0c12816

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set
Victoria A. Pollard, M. Ángeles Fuentes, Alan R. Kennedy, Ross McLellan and Robert E. Mulvey
Angewandte Chemie, 2018, 130, 10811
DOI: 10.1002/ange.201806168

Synthesis, Structure, and Reactivity of a Terminal Magnesium Hydride Compound with a Carbatrane Motif, [TismPriBenz]MgH: A Multifunctional Catalyst for Hydrosilylation and Hydroboration
Michael Rauch, Serge Ruccolo and Gerard Parkin
J. Am. Chem. Soc., 2017, 139, 13264
DOI: 10.1021/jacs.7b06719

Generalized Pitzer-Debye-Hückel (PDH) Framework for the Deep Eutectic Solvent Assisted Extraction of Europium (III), Americium (III), and Uranium (VI)
Dev K. Patra, Aradhana V. Thombre and Debashis Kundu
Solvent Extraction and Ion Exchange, 2024, 42, 78
DOI: 10.1080/07366299.2023.2293688

Neosilyllithium‐Catalyzed Hydroboration of Alkynes and Alkenes in the Presence of Pinacolborane (HBpin)
Gobbilla Sai Kumar, Shruti Moorthy, Himadri Karmakar, Saurabh Kumar Singh and Tarun K. Panda
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100895

P–H Functionalized Al/P-Based Frustrated Lewis Pairs in Dipolar Activation and Hydrophosphination: Reactions with CO2 and SO2
Niklas Aders, Lukas Keweloh, Damian Pleschka, Alexander Hepp, Marcus Layh, Friedhelm Rogel and Werner Uhl
Organometallics, 2019, 38, 2839
DOI: 10.1021/acs.organomet.9b00346

Binucleating Bis(pyrazolyl)alkane Ligands and Their Cationic Dizinc Complexes: Modular, Bimetallic Catalysts for Ring-Opening Polymerization
Zipeng Gu and Robert J. Comito
Organometallics, 2022, 41, 1911
DOI: 10.1021/acs.organomet.2c00167

Insertion of CO2, Isocyanates, and Acetonitrile into the P–Si Bond of a Silyl-Substituted N-Heterocyclic Carbene Phosphinidene
Andreas Hochholzer, Martin E. Doleschal, Priyanka Chakraborty and Shigeyoshi Inoue
Organometallics, 2026, 45, 573
DOI: 10.1021/acs.organomet.5c00466

Introducing NacNac-Like Bis(4,6-isopropylbenzoxazol-2-yl)methanide in s-Block Metal Coordination
Ingo Koehne, Nico Graw, Thorsten Teuteberg, Regine Herbst-Irmer and Dietmar Stalke
Inorg. Chem., 2017, 56, 14968
DOI: 10.1021/acs.inorgchem.7b02276

Benzene submits to main-group power
Robert Emmet Mulvey
Science, 2017, 358, 1132
DOI: 10.1126/science.aaq1314

Variable Ca‐Caryl Hapticity and its Consequences in Arylcalcium Dimers
Kyle G. Pearce, Chiara Dinoi, Ryan J. Schwamm, Laurent Maron, Mary F. Mahon and Michael S. Hill
Advanced Science, 2023, 10
DOI: 10.1002/advs.202304765

Barium‐Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight
Erwann Le Coz, Ziyun Zhang, Thierry Roisnel, Luigi Cavallo, Laura Falivene, Jean‐François Carpentier and Yann Sarazin
Chemistry A European J, 2020, 26, 3535
DOI: 10.1002/chem.201904933

Bonding in Barium Boryloxides, Siloxides, Phenoxides and Silazides: A Comparison with the Lighter Alkaline Earths
Erwann Le Coz, Joanna Hammoud, Thierry Roisnel, Marie Cordier, Vincent Dorcet, Samia Kahlal, Jean‐François Carpentier, Jean‐Yves Saillard and Yann Sarazin
Chemistry A European J, 2021, 27, 11966
DOI: 10.1002/chem.202101687

Application of a Stable and Soluble Dibenzylbarium Reagent in the Synthesis of a Barium Imido Cluster
Bastian Rösch, Johannes Martin, Jonathan Eyselein, Jens Langer, Michael Wiesinger and Sjoerd Harder
Organometallics, 2021, 40, 1395
DOI: 10.1021/acs.organomet.1c00199

Low-Symmetry β-Diketimine Aryloxide Rare-Earth Complexes: Flexible, Reactive, and Selective
Kerry C. Casey, Jude K. Appiah and Jerome R. Robinson
Inorg. Chem., 2020, 59, 14827
DOI: 10.1021/acs.inorgchem.0c02170

THF‐solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry
Lukas Brieger, Christian Unkelbach and Carsten Strohmann
Chemistry A European J, 2021, 27, 17780
DOI: 10.1002/chem.202103430

Self-separation ionic liquid catalyst for the highly effective conversion of H2S by α,β-unsaturated carboxylate esters under mild conditions
Wenjie Xiong, Xiaomin Zhang, Xingbang Hu and Youting Wu
Green Energy & Environment, 2024, 9, 1440
DOI: 10.1016/j.gee.2023.03.001

Mg(PF6)2-Based Electrolyte Systems: Understanding Electrolyte–Electrode Interactions for the Development of Mg-Ion Batteries
Evan N. Keyzer, Hugh F. J. Glass, Zigeng Liu, Paul M. Bayley, Siân E. Dutton, Clare P. Grey and Dominic S. Wright
J. Am. Chem. Soc., 2016, 138, 8682
DOI: 10.1021/jacs.6b04319

The Nature of the Heavy Alkaline Earth Metal–Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster
Debabrata Mukherjee, Thomas Höllerhage, Valeri Leich, Thomas P. Spaniol, Ulli Englert, Laurent Maron and Jun Okuda
J. Am. Chem. Soc., 2018, 140, 3403
DOI: 10.1021/jacs.7b13796

A PEGylated Tin Porphyrin Complex for Electrocatalytic Proton Reduction: Mechanistic Insights into Main‐Group‐Element Catalysis
Ashwin Chaturvedi, Gavin A. McCarver, Soumalya Sinha, Elijah G. Hix, Konstantinos D. Vogiatzis and Jianbing Jiang
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202206325

Examination of metal-π interactions in the coordination chemistry of heavy alkaline earth metal tetraarylborates
Catherine M. Lavin, Damian G. Allis, Miriam M. Gillett-Kunnath, Ashley Clements, Alan G. Goos, Joshua J. Woods, Paul Hager, Donyell S. Logan and Karin Ruhlandt-Senge
Journal of Coordination Chemistry, 2025, 78, 233
DOI: 10.1080/00958972.2025.2453065

Efficient Base‐Catalyzed Hydrosilylation of Tertiary Amides to Aldehydes
Joshua A. Clarke and Georgii I. Nikonov
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202201231

Tandem Synthesis of Linear Hydridopolycarbosilanes and Postfunctionalization by a Calcium Catalyst
Lanxiao Zhao, Peng Deng, Xun Gong and Jianhua Cheng
Macromolecules, 2023, 56, 9550
DOI: 10.1021/acs.macromol.3c02049

Stabilisation of a Strontium Hydride with a Monodentate Carbazolyl Ligand and its Reactivity
Lucas Winkler and Alexander Hinz
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202418558

Alkaline Earth Metal Aluminates as Catalysts for Imine Hydrogenation
Holger Elsen, Jens Langer, Michael Wiesinger and Sjoerd Harder
Organometallics, 2020, 39, 4238
DOI: 10.1021/acs.organomet.0c00226

Calcium-catalyzed C(sp)-H silylation of terminal alkynes with hydrosilanes
Xizhou Zheng, Shengjie Jiang, Chuan Dong, Qingyun Yao, Yingming Yao and Xin Xu
Polyhedron, 2022, 218, 115771
DOI: 10.1016/j.poly.2022.115771

Role of Alkaline-Earth Metal-Catalyst: A Theoretical Study of Pyridines Hydroboration
Yuanyuan Li, Meijun Wu, Haohua Chen, Dongdong Xu, Lingbo Qu, Jing Zhang, Ruopeng Bai and Yu Lan
Front. Chem., 2019, 7
DOI: 10.3389/fchem.2019.00149

Approaching a “Naked” Boryl Anion: Amide Metathesis as a Route to Calcium, Strontium, and Potassium Boryl Complexes
Andrey V. Protchenko, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Dragoslav Vidovic and Simon Aldridge
Angewandte Chemie, 2021, 133, 2092
DOI: 10.1002/ange.202011839

Arene Activation by Calcium Hydride/Zinc Amide Equilibration
Kyle G. Pearce, Agustín Morales, Michael S. Hill, Mary F. Mahon and Claire L. McMullin
J. Am. Chem. Soc., 2025, 147, 29554
DOI: 10.1021/jacs.5c10735

Magnesium-Promoted Selectively Reduction of Unprotected Indoles and Quinoxalines
Nana Wei, Wanzhen Guo, Xing Lu, Zhiqiang Ren, Haojie Ma, Yuqi Zhang, Jijiang Wang and Bo Han
Chinese Journal of Organic Chemistry, 2026, 46, 1027
DOI: 10.6023/cjoc202508021

Transition‐Metal‐Free Reduction of α‐Keto Thioesters with Hydrosilanes at Room Temperature: Divergent Synthesis through Reagent‐Controlled Chemoselectivities
Rajib Maity, Bhanuranjan Das and Indrajit Das
Adv Synth Catal, 2019, 361, 2347
DOI: 10.1002/adsc.201900222

New Tricks for an Old Dog: Aluminum Compounds as Catalysts in Reduction Chemistry
Georgii I. Nikonov
ACS Catal., 2017, 7, 7257
DOI: 10.1021/acscatal.7b02460

Synthesis and Characterisation of Two Lithium Tetramethylberyllate Salts and a Series of β-Diketiminato Beryllium Alkyl Complexes*
Albert Paparo, Caspar N. de Bruin-Dickason and Cameron Jones
Australian Journal of Chemistry, 2020, 73, 1144
DOI: 10.1071/CH20129

Bulky guanidinate calcium and zinc complexes as catalysts for the intramolecular hydroamination
Milan Kr Barman, Ashim Baishya and Sharanappa Nembenna
Journal of Organometallic Chemistry, 2019, 887, 40
DOI: 10.1016/j.jorganchem.2019.02.005

Theoretical Study of Hydrogenation Catalysis of Phosphorus Compound and Prediction of Catalyst with High Activity and Wide Application Scope
Guixiang Zeng, Satoshi Maeda, Tetsuya Taketsugu and Shigeyoshi Sakaki
ACS Catal., 2016, 6, 4859
DOI: 10.1021/acscatal.5b02968

Aluminium‐Catalyzed Selective Reduction of Heteroallenes Through Hydroboration: Amide/Thioamide/Selenoamide Bond Construction and C=X (X=O, S, Se) Bond Activation**
Nabin Sarkar, Rajata Kumar Sahoo and Sharanappa Nembenna
Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200941

Reversible C–N Bond Formation in the Zirconium-Catalyzed Intermolecular Hydroamination of 2-Vinylpyridine
Samuel E. Griffin, Javier Pacheco and Laurel L. Schafer
Organometallics, 2019, 38, 1011
DOI: 10.1021/acs.organomet.8b00904

Hepta‐Coordinated Alkaline‐Earth Complexes Featuring E^N^N^N^E (E = BH3, S, Se) Ligands as Efficient Catalysts for Heterocumulene Hydroboration and Cyclic Ester Ring‐Opening Polymerization
Jyoti Sharma, Pooja Dutta, Shweta Sagar, Priyanku Nath, Rohan Kumar Meher, Archana Jain and Tarun K. Panda
Chemistry A European J, 2026
DOI: 10.1002/chem.71006

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage
Smita Patnaik and Aaron D. Sadow
Angew Chem Int Ed, 2019, 58, 2505
DOI: 10.1002/anie.201813305

Nucleophilic Magnesium Silanide and Silaamidinate Derivatives
Bibian Okokhere-Edeghoghon, Maximilian Dehmel, Michael S. Hill, Robert Kretschmer, Mary F. Mahon, Claire L. McMullin, Louis J. Morris and Nasir A. Rajabi
Inorg. Chem., 2020, 59, 13679
DOI: 10.1021/acs.inorgchem.0c02034

Molecular Main Group Metal Hydrides
Matthew M. D. Roy, Alvaro A. Omaña, Andrew S. S. Wilson, Michael S. Hill, Simon Aldridge and Eric Rivard
Chem. Rev., 2021, 121, 12784
DOI: 10.1021/acs.chemrev.1c00278

Alkaline Earth Metal Bis(amides) Based on Unsymmetrical Acenaphthene-1,2-diimine
A. A. Bazanov, A. A. Skatova, E. V. Baranov and I. L. Fedushkin
Russ J Coord Chem, 2025, 51, 679
DOI: 10.1134/S1070328425600652

Electronically Unsaturated Three‐Coordinate Aluminum Hydride and Organoaluminum Cations
Billa Prashanth, Mamta Bhandari, Satyam Ravi, K. R. Shamasundar and Sanjay Singh
Chemistry A European J, 2018, 24, 4794
DOI: 10.1002/chem.201800299

Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air
Florian F. Mulks, Leonie J. Bole, Laia Davin, Alberto Hernán‐Gómez, Alan Kennedy, Joaquín García‐Álvarez and Eva Hevia
Angewandte Chemie, 2020, 132, 19183
DOI: 10.1002/ange.202008512

Aluminum Amidinates: Insights into Alkyne Hydroboration
Katie Hobson, Claire J. Carmalt and Clare Bakewell
Inorg. Chem., 2021, 60, 10958
DOI: 10.1021/acs.inorgchem.1c00619

An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects
Philip P. Power
Organometallics, 2020, 39, 4127
DOI: 10.1021/acs.organomet.0c00200

Silyl–Hydrosilane Exchange at a Magnesium Triphenylsilyl Complex Supported by a Cyclen-Derived NNNN-Type Macrocyclic Ligand
Lara E. Lemmerz, Valeri Leich, Daniel Martin, Thomas P. Spaniol and Jun Okuda
Inorg. Chem., 2017, 56, 14979
DOI: 10.1021/acs.inorgchem.7b02233

Calcium-mediated C(sp3)–H Activation and Alkylation of Alkylpyridines
Xizhou Zheng, Iker del Rosal, Xian Xu, Yingming Yao, Laurent Maron and Xin Xu
Inorg. Chem., 2021, 60, 5114
DOI: 10.1021/acs.inorgchem.1c00161

Synthesis, Structural Characterization, and Bonding of Molecular Heavier Beryllium Chalcogenides
Corinna Czernetzki, Tobias Tröster, Lukas Endres, Franziska Endres, Merle Arrowsmith, Annalena Gärtner, Felipe Fantuzzi and Holger Braunschweig
Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301418

Hydridostannylene Derivatives of Magnesium and Calcium
Dominic B. Kennedy, Kyle G. Pearce, Samuel E. Neale, Louis J. Morris, Mary F. Mahon, John P. Lowe, Claire L. McMullin, Cameron Jones and Michael S. Hill
Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404416

Exploring the Nuclearity and Structural Motifs of Phenoxyimine Alkaline Earth Complexes
Amy V. Rizzo, Rebecca L. Jones, Matthew D. Haynes, Clement G. Collins Rice, Jean-Charles Buffet, Zoë R. Turner and Dermot O’Hare
Organometallics, 2025, 44, 737
DOI: 10.1021/acs.organomet.4c00504

Aluminum Hydride Catalyzed Hydroboration of Alkynes
Alessandro Bismuto, Stephen P. Thomas and Michael J. Cowley
Angewandte Chemie, 2016, 128, 15582
DOI: 10.1002/ange.201609690

Recent development of aminophosphine chalcogenides and boranes as ligands in s -block metal chemistry
Chowan Ashok Kumar and Tarun K. Panda
Phosphorus, Sulfur, and Silicon and the Related Elements, 2017, 192, 1084
DOI: 10.1080/10426507.2017.1322967

Molecular Magnesium Hydrides
Debabrata Mukherjee and Jun Okuda
Angew Chem Int Ed, 2018, 57, 1458
DOI: 10.1002/anie.201708592

Formation and Properties of the Trichloroberyllate Ion
Magnus R. Buchner, Nils Spang, Matthias Müller and Stefan S. Rudel
Inorg. Chem., 2018, 57, 11314
DOI: 10.1021/acs.inorgchem.8b01934

Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation of Alkenes
Thomas X. Gentner, Alan R. Kennedy, Eva Hevia and Robert E. Mulvey
ChemCatChem, 2021, 13, 2371
DOI: 10.1002/cctc.202100218

Aluminum-Catalyzed Hydroboration of Alkenes
Alessandro Bismuto, Michael J. Cowley and Stephen P. Thomas
ACS Catal., 2018, 8, 2001
DOI: 10.1021/acscatal.7b04279

Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis
Yann Sarazin and Jean‐François Carpentier
The Chemical Record, 2016, 16, 2482
DOI: 10.1002/tcr.201600067

Calciumhydrid‐Kation [CaH]+ stabilisiert durch einen makrocyclischen NNNN‐Liganden: ein selektiver Katalysator für die Hydrierung von Olefinen
Danny Schuhknecht, Carolin Lhotzky, Thomas P. Spaniol, Laurent Maron and Jun Okuda
Angewandte Chemie, 2017, 129, 12539
DOI: 10.1002/ange.201706848

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes
Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping
Angew Chem Int Ed, 2019, 58, 7025
DOI: 10.1002/anie.201902188

Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings
Johannes Martin, Christian Knüpfer, Jonathan Eyselein, Christian Färber, Samuel Grams, Jens Langer, Katharina Thum, Michael Wiesinger and Sjoerd Harder
Angewandte Chemie, 2020, 132, 9187
DOI: 10.1002/ange.202001160

Early Main Group Metal Catalysts for Imine Hydrosilylation
Holger Elsen, Christian Fischer, Christian Knüpfer, Ana Escalona and Sjoerd Harder
Chemistry A European J, 2019, 25, 16141
DOI: 10.1002/chem.201904148

Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides
Arron C. Deacy, Alexander F. R. Kilpatrick, Anna Regoutz and Charlotte K. Williams
Nat. Chem., 2020, 12, 372
DOI: 10.1038/s41557-020-0450-3

Promoting π-Facial Interactions in Phenyl-Substituted 1,8-Bis(silylamido)naphthalene Alkaline Earth Complexes
Matthew D. Haynes, Clement G. Collins Rice, Louis J. Morris, Zoë R. Turner and Dermot O’Hare
Organometallics, 2025, 44, 582
DOI: 10.1021/acs.organomet.4c00479

Hydrido‐Komplexe des Calciums: eine neue Familie molekularer Erdalkalimetall‐Verbindungen
Debabrata Mukherjee, Danny Schuhknecht and Jun Okuda
Angewandte Chemie, 2018, 130, 9736
DOI: 10.1002/ange.201801869

Convenient one‐pot synthesis and coordination chemistry of a bulky asymmetrical 9,10‐dihydroacridine‐based ligand
Gareth R. Nelmes, Penelope J. Brothers and Jamie Hicks
Zeitschrift anorg allge chemie, 2022, 648
DOI: 10.1002/zaac.202200127

Atomically confined calcium in nitrogen-doped graphene as an efficient heterogeneous catalyst for hydrogen evolution
Jie Sun, Suchun Li, Qi Zhao, Cunping Huang, Qiang Wu, Wei Chen, Qunjie Xu and Weifeng Yao
iScience, 2021, 24, 102728
DOI: 10.1016/j.isci.2021.102728

Calcium-Catalyzed Dehydrogenative Silylation of Aromatic Ethers with Hydrosilane
Lanxiao Zhao, Xianghui Shi and Jianhua Cheng
ACS Catal., 2021, 11, 2041
DOI: 10.1021/acscatal.0c05440

Bulky bis-guanidinate ligand-supported magnesium hydride: Synthesis, reactivity, and catalytic applications
Sayantan Mukhopadhyay, Anubhab Das, Smrutirani Padhan and Sharanappa Nembenna
Inorganica Chimica Acta, 2026, 589, 122924
DOI: 10.1016/j.ica.2025.122924

Regioselective C–H Alkylation of Aromatic Ethers with Alkenes by a Half-Sandwich Calcium Catalyst
Lanxiao Zhao, Peng Deng, Xun Gong, Xiaohui Kang and Jianhua Cheng
ACS Catal., 2022, 12, 7877
DOI: 10.1021/acscatal.2c01572

Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides
Xianghui Shi, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu and Jianhua Cheng
Angew Chem Int Ed, 2019, 58, 4356
DOI: 10.1002/anie.201814733

Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N–H Activation by Metal–Ligand Cooperation as Key Steps
Yaoyu Liang, Jie Luo, Yael Diskin-Posner and David Milstein
J. Am. Chem. Soc., 2023, 145, 9164
DOI: 10.1021/jacs.3c01091

Synthesis and Reactivity of Stable Open-Shell Gallylene
Natalia L. Bazyakina, Alexandra A. Skatova, Mikhail V. Moskalev, Evgeny V. Baranov, Tatyana S. Koptseva, Sergey Yu. Ketkov, Xiao-Juan Yang and Igor L. Fedushkin
Inorg. Chem., 2025, 64, 4892
DOI: 10.1021/acs.inorgchem.4c04768

Solvated Alkali and Calcium 2,2,6,6‐Tetramethylpiperidides: Synthesis and Reactivity
Gabriel Duneş, Cléo Bastien, Savarithai Jenani Louis Anandaraj, Marie Cordier, Vincent Dorcet, Thierry Roisnel, William Erb, Florence Mongin and Yann Sarazin
Eur J Inorg Chem, 2025, 28
DOI: 10.1002/ejic.202500451

Alkene Transfer Hydrogenation with Alkaline‐Earth Metal Catalysts
Heiko Bauer, Katharina Thum, Mercedes Alonso, Christian Fischer and Sjoerd Harder
Angew Chem Int Ed, 2019, 58, 4248
DOI: 10.1002/anie.201813910

Synthesis, Characterization, and Reactivity of a Pincer-Type Aluminum(III) Complex
Penglong Wang, Mingxing Zhang and Congqing Zhu
Organometallics, 2020, 39, 2732
DOI: 10.1021/acs.organomet.0c00325

Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules
Carlos Ginés, Blanca Parra‐Cadenas, Rafael Fernández‐Galán, Daniel García‐Vivó, David Elorriaga, Alberto Ramos and Fernando Carrillo‐Hermosilla
Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202400843

Magnesium complexes in hydroelementation and reduction catalysis: Opportunities and challenges
Marc Magre, Marcin Szewczyk and Magnus Rueping
Current Opinion in Green and Sustainable Chemistry, 2021, 32, 100526
DOI: 10.1016/j.cogsc.2021.100526

Highly efficient MgF2 supported Co catalyst for cyclization reaction of o-nitroaniline and benzyl-alcohol
Yanjie Chen, Xinhui Sun, Yuli Sha, Xinjie Fang, Wenyi Chu and Xin Wang
Molecular Catalysis, 2023, 545, 113186
DOI: 10.1016/j.mcat.2023.113186

Not Only Hydrogen Bonds: Other Noncovalent Interactions
Ibon Alkorta, José Elguero and Antonio Frontera
Crystals, 2020, 10, 180
DOI: 10.3390/cryst10030180

Calcium and Magnesium Bis(β-diketiminate) Complexes: Impact of the Alkylene Bridge on Schlenk-Type Rearrangements
Philipp Rinke, Helmar Görls and Robert Kretschmer
Inorg. Chem., 2021, 60, 5310
DOI: 10.1021/acs.inorgchem.1c00301

Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds
Yuanyuan Li, Haohua Chen, Lingbo Qu, Ruopeng Bai and Yu Lan
Chinese Chemical Letters, 2019, 30, 2249
DOI: 10.1016/j.cclet.2019.06.001

Benzannulated N-heterocyclic plumbylene: An efficient catalyst in ring opening polymerization of -lactide
Tzung-Han Lin, Gene-Hsiang Lee, Shie-Ming Peng, Ching-Wen Chiu and Hsuan-Ying Chen
Polymer, 2019, 180, 121748
DOI: 10.1016/j.polymer.2019.121748

Comparison of Magnesium and Zinc in Cationic π-Arene and Halobenzene Complexes
Alexander Friedrich, Jonathan Eyselein, Jens Langer and Sjoerd Harder
Organometallics, 2021, 40, 448
DOI: 10.1021/acs.organomet.0c00786

Recent Advances in Aluminum Compounds for Catalysis
Congjian Ni, Xiaoli Ma, Zhi Yang and Herbert W. Roesky
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100929

Organocalcium Complex-Catalyzed Selective Redistribution of ArSiH3 or Ar(alkyl)SiH2 to Ar3SiH or Ar2(alkyl)SiH
Tao Li, Karl N. McCabe, Laurent Maron, Xuebing Leng and Yaofeng Chen
ACS Catal., 2021, 11, 6348
DOI: 10.1021/acscatal.1c00463

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications
Victoria A. Pollard, Allan Young, Ross McLellan, Alan R. Kennedy, Tell Tuttle and Robert E. Mulvey
Angewandte Chemie, 2019, 131, 12419
DOI: 10.1002/ange.201906807

Cyclopentadienyl Complexes of the Alkaline Earths in Light of the Periodic Trends
Sudip Baguli, Sumana Mondal, Chhotan Mandal, Santu Goswami and Debabrata Mukherjee
Chemistry — An Asian Journal, 2022, 17
DOI: 10.1002/asia.202100962

Reactivity of a Molecular Calcium Hydride Cation ([CaH]+) Supported by an NNNN Macrocycle
Danny Schuhknecht, Thomas P. Spaniol, Yan Yang, Laurent Maron and Jun Okuda
Inorg. Chem., 2020, 59, 9406
DOI: 10.1021/acs.inorgchem.0c01289

N-Heterocyclic Carbene–Carbodiimide (“NHC–CDI”) Adduct or Zwitterionic-Type Neutral Amidinate-Supported Magnesium(II) and Zinc(II) Complexes
Ashim Baishya, Lokesh Kumar, Milan Kr. Barman, Himansu S. Biswal and Sharanappa Nembenna
Inorg. Chem., 2017, 56, 9535
DOI: 10.1021/acs.inorgchem.7b00879

N-Heterocyclic Carbene-Supported Aryl- and Alk- oxides of Beryllium and Magnesium
Jacob E. Walley, Yuen-Onn Wong, Lucas A. Freeman, Diane A. Dickie and Robert J. Gilliard
Catalysts, 2019, 9, 934
DOI: 10.3390/catal9110934

Mechanism of Potassiumtert-Butoxide-Catalyzed Ketones Hydrogenation in the Solution Phase
Pavel A. Dub and Nikolay V. Tkachenko
J. Phys. Chem. A, 2021, 125, 5726
DOI: 10.1021/acs.jpca.1c02516

Alkali-Metal- and Alkaline-Earth-Metal-Mediated C–O Activation of an Anisole-Substituted Phosphido–Borane Ligand
Keith Izod, James M. Watson, Salima M. El-Hamruni, Ross W. Harrington and Paul G. Waddell
Organometallics, 2017, 36, 2218
DOI: 10.1021/acs.organomet.7b00262

Synthesis of asymmetrical β-diketiminate magnesium methyl complexes and their catalytic application in cyanosilylation of ketones
Kai Lu, Hui Qiu, Xi Chen, Taoyue Yuan, Fei Xue and Mengtao Ma
Journal of Molecular Structure, 2024, 1295, 136796
DOI: 10.1016/j.molstruc.2023.136796

Structural and Mechanistic Insights into s‐Block Bimetallic Catalysis: Sodium Magnesiate‐Catalyzed Guanylation of Amines
Marco De Tullio, Alberto Hernán‐Gómez, Zoe Livingstone, William Clegg, Alan R. Kennedy, Ross W. Harrington, Antonio Antiñolo, Antonio Martínez, Fernando Carrillo‐Hermosilla and Eva Hevia
Chemistry A European J, 2016, 22, 17646
DOI: 10.1002/chem.201602906

Unsupported Mg–Alkene Bonding
Katharina Thum, Alexander Friedrich, Jürgen Pahl, Holger Elsen, Jens Langer and Sjoerd Harder
Chemistry A European J, 2021, 27, 2513
DOI: 10.1002/chem.202004716

Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex
Zachary Mathe, Dimitrios A. Pantazis, Heui Beom Lee, Richard Gnewkow, Benjamin E. Van Kuiken, Theodor Agapie and Serena DeBeer
Inorg. Chem., 2019, 58, 16292
DOI: 10.1021/acs.inorgchem.9b02866

Syntheses of Dianionic α-Iminopyridine Rare-Earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes
Xiuli Zhang, Shuangliu Zhou, Xiaofei Fang, Lijun Zhang, Guide Tao, Yun Wei, Xiancui Zhu, Peng Cui and Shaowu Wang
Inorg. Chem., 2020, 59, 9683
DOI: 10.1021/acs.inorgchem.0c00907

Transition Metal Mimetic π-Activation by Cationic Bismuth(III) Catalysts for Allylic C–H Functionalization of Olefins Using C═O and C═N Electrophiles
Ruihan Wang, Sebastián Martínez, Johannes Schwarzmann, Christopher Z. Zhao, Jacqueline Ramler, Crispin Lichtenberg and Yi-Ming Wang
J. Am. Chem. Soc., 2024, 146, 22122
DOI: 10.1021/jacs.4c06235

C−H Deprotonation and C=C Hydrogenation of N‐Heterocyclic Olefin with Calcium Hydride Complexes: Cooperative Ca−H−Ca Bridge versus Terminal Ca−H bond
Zheng‐Wang Qu, Hui Zhu, Rainer Streubel and Stefan Grimme
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200508

Oxidative Addition and Reductive Elimination at Main-Group Element Centers
Terry Chu and Georgii I. Nikonov
Chem. Rev., 2018, 118, 3608
DOI: 10.1021/acs.chemrev.7b00572

Selective Cross‐Coupling of Unsaturated Substrates on AlI
Anton Dmitrienko, Melanie Pilkington and Georgii I. Nikonov
Chemistry A European J, 2021, 27, 5730
DOI: 10.1002/chem.202004907

Synthesis of gas-phase, group II metal hydride cations using preparative tandem mass spectrometry
Madeline R. Handel, Samuel J. Lenze, Lucas G. Fuller, Theodore A. Corcovilos and Michael J. van Stipdonk
Inorganica Chimica Acta, 2026, 592, 123043
DOI: 10.1016/j.ica.2025.123043

Isolation of an N‐Heterocyclic Carbene Complex of a Borasilene
Daniel Franz, Tibor Szilvási, Alexander Pöthig and Shigeyoshi Inoue
Chemistry A European J, 2019, 25, 11036
DOI: 10.1002/chem.201902877

Germanium Hydride Catalyzed Selective Hydroboration and Cyanosilylation of Ketones
Anwesh Prasad Khuntia, Nabin Sarkar, A. Ganesh Patro, Rajata Kumar Sahoo and Sharanappa Nembenna
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200209

Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
Daniel Janssen‐Müller and Martin Oestreich
Angewandte Chemie, 2020, 132, 8404
DOI: 10.1002/ange.201914729

Bis(benzoxazol‐2‐yl)methanes Hounding NacNac: Varieties and Applications in Main Group Metal Coordination
Johannes Kretsch, Ingo Koehne, Märt Lõkov, Ivo Leito and Dietmar Stalke
Eur J Inorg Chem, 2019, 2019, 3258
DOI: 10.1002/ejic.201900631

Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines
Cara R. Aversa-Fleener, Daniel K. Chang and Allegra L. Liberman-Martin
Organometallics, 2021, 40, 4050
DOI: 10.1021/acs.organomet.1c00628

Tetranuclear Strontium and Barium Siloxide/Amide Clusters in Metal‐Ligand Cooperative Catalysis
Benjamin Freitag, Phillip Stegner, Katharina Thum, Christian A. Fischer and Sjoerd Harder
Eur J Inorg Chem, 2018, 2018, 1938
DOI: 10.1002/ejic.201800231

Designing a Mesoporous Zeolite Catalyst for Products Optimizing in n-Decane Hydrocraking
Li Tan, Xiaoyu Guo, Xinhua Gao and Noritatsu Tsubaki
Catalysts, 2019, 9, 766
DOI: 10.3390/catal9090766

Catalytic hydrogenation of acetone to isopropyl alcohol with CAl3MgH2¯ containing planar tetracoordinate carbon
Abdul Hamid Malhan and Krishnan Thirumoorthy
Front. Chem., 2026, 13
DOI: 10.3389/fchem.2025.1750798

Bioinspired Alkyl Transfer Enabled by Ca(II)/HFIP Cooperative Catalysis: Modular Synthesis of Functionalized Isoindolinones
Fangting Huang, Jie Liu, Zhongyi Zeng, Zhi Zhou, Wei Yi and Shengdong Wang
Org. Lett., 2026
DOI: 10.1021/acs.orglett.6c01268

Highly Fluorinated Tris(indazolyl)borate Hydrocarbyl Complexes of Calcium and Magnesium: Synthesis and Structural Studies
Nuria Romero, Quentin Dufrois, Laure Vendier, Chiara Dinoi and Michel Etienne
Organometallics, 2017, 36, 564
DOI: 10.1021/acs.organomet.6b00783

Beyond Hydrofunctionalisation: A Well‐Defined Calcium Compound Catalysed Mild and Efficient Carbonyl Cyanosilylation
Sandeep Yadav, Ruchi Dixit, Kumar Vanka and Sakya S. Sen
Chemistry A European J, 2018, 24, 1269
DOI: 10.1002/chem.201705795

Catalytic CO2 Reduction with Boron‐ and Aluminum Hydrides
Daniel Franz, Christian Jandl, Claire Stark and Shigeyoshi Inoue
ChemCatChem, 2019, 11, 5275
DOI: 10.1002/cctc.201901255

Calcium-Mediated Catalytic Synthesis of 1-(Diorganylamino)-1,4-diphenyl-4-(diphenylphosphanyl)buta-1,3-dienes
Fadi M. Younis, Sven Krieck, Tareq M. A. Al-Shboul, Helmar Görls and Matthias Westerhausen
Inorg. Chem., 2016, 55, 4676
DOI: 10.1021/acs.inorgchem.6b00586

Calcium Hydride Cation [CaH]+ Stabilized by an NNNN‐type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation
Danny Schuhknecht, Carolin Lhotzky, Thomas P. Spaniol, Laurent Maron and Jun Okuda
Angew Chem Int Ed, 2017, 56, 12367
DOI: 10.1002/anie.201706848

A Highly Lewis Acidic Strontium ansa‐Arene Complex for Lewis Acid Catalysis and Isobutylene Polymerization
Philipp Dabringhaus, Marcel Schorpp, Harald Scherer and Ingo Krossing
Angewandte Chemie, 2020, 132, 22207
DOI: 10.1002/ange.202010019

Multimetallic Alkaline-Earth Hydride Cations
Lucia Garcia, Mary F. Mahon and Michael S. Hill
Organometallics, 2019, 38, 3778
DOI: 10.1021/acs.organomet.9b00493

Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes
Michael Rauch, Sayan Kar, Amit Kumar, Liat Avram, Linda J. W. Shimon and David Milstein
J. Am. Chem. Soc., 2020, 142, 14513
DOI: 10.1021/jacs.0c05500

Bis(imino)carbazolate: A Master Key for Barium Chemistry
Peter M. Chapple, Samia Kahlal, Julien Cartron, Thierry Roisnel, Vincent Dorcet, Marie Cordier, Jean‐Yves Saillard, Jean‐François Carpentier and Yann Sarazin
Angew Chem Int Ed, 2020, 59, 9120
DOI: 10.1002/anie.202001439

ХІМІЯ І БІОЛОГІЧНА РОЛЬ КОМПЛЕКСІВ БІОГЕННИХ МЕТАЛІВ ІЗ ЕНДОГЕННИМИ ТА ЕКЗОГЕННИМИ ЛІГАНДАМИ
Максим Дорошенко
GoS, 2025, 516
DOI: 10.36074/grail-of-science.20.06.2025.060

Alkene Transfer Hydrogenation with Alkaline‐Earth Metal Catalysts
Heiko Bauer, Katharina Thum, Mercedes Alonso, Christian Fischer and Sjoerd Harder
Angewandte Chemie, 2019, 131, 4292
DOI: 10.1002/ange.201813910

Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air
Florian F. Mulks, Leonie J. Bole, Laia Davin, Alberto Hernán‐Gómez, Alan Kennedy, Joaquín García‐Álvarez and Eva Hevia
Angew Chem Int Ed, 2020, 59, 19021
DOI: 10.1002/anie.202008512

Determination of the Mechanism and True Catalyst in CO2 Hydroboration Catalyzed by the Low-Valent Magnesium(I) Dimer: A Computational Study
Lin Yang, Zhendong Li and Xiaoyan Li
J. Phys. Chem. A, 2026, 130, 2061
DOI: 10.1021/acs.jpca.5c07854

A Molecular Barium Hydrido Complex Stabilized by a Super‐Bulky Hydrotris(pyrazolyl)borate Ligand
Xianghui Shi, Cuiping Hou, Chulu Zhou, Yanyao Song and Jianhua Cheng
Angewandte Chemie, 2017, 129, 16877
DOI: 10.1002/ange.201709344

Simple Alkaline‐Earth Metal Catalysts for Effective Alkene Hydrogenation
Heiko Bauer, Mercedes Alonso, Christian Fischer, Bastian Rösch, Holger Elsen and Sjoerd Harder
Angew Chem Int Ed, 2018, 57, 15177
DOI: 10.1002/anie.201810026

Barium Siloxides and Catalysed Formation of Si−O−Si' Motifs
Erwann Le Coz, Samia Kahlal, Jean‐Yves Saillard, Thierry Roisnel, Vincent Dorcet, Jean‐François Carpentier and Yann Sarazin
Chemistry A European J, 2019, 25, 13509
DOI: 10.1002/chem.201903676

Synthesis and Characterization of Magnesium-Hydride Complexes with Alkylene-Bridged Bis(β-diketiminate) Ligands
Philipp Rinke, Helmar Görls, Phil Liebing and Robert Kretschmer
Organometallics, 2023, 42, 2287
DOI: 10.1021/acs.organomet.3c00278

Reactivity of Strontium Hydride Supported by the Superbulky Hydrotris(pyrazolyl)borate Ligand
Xun Gong, Xianghui Shi, Peng Deng and Jianhua Cheng
Inorg. Chem., 2024, 63, 20654
DOI: 10.1021/acs.inorgchem.4c03296

Magnesium‐Mediated Cyanosilylation and Hydroboration of Arene and N‐Heteroarene Aldehydes: An Experimental and Theoretical Study
Darakshan Parveen, Sougata Saha, Rahul Kumar Yadav, Swapan K. Pati and Dipak Kumar Roy
Chemistry — An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401853

[9-{2-(Dimethylamino)ethyl}fluorenyl] as a Ligand on Magnesium Leads to a THF Ring-Opening by the Fluorenyl Moiety
Chhotan Mandal, Subham Sarkar, Narottam Mukhopadhyay, Dibyendu Mallick and Debabrata Mukherjee
Inorg. Chem., 2025, 64, 19266
DOI: 10.1021/acs.inorgchem.5c02658

Transition‐Metal‐Like Catalysis with a Main‐Group Element: Bismuth‐Catalyzed C−F Coupling of Aryl Boronic Esters
Daniel Janssen‐Müller and Martin Oestreich
Angew Chem Int Ed, 2020, 59, 8328
DOI: 10.1002/anie.201914729

Anti-Markovnikov Intermolecular Hydroamination of Alkenes and Alkynes: A Mechanistic View
Jorge Escorihuela, Agustí Lledós and Gregori Ujaque
Chem. Rev., 2023, 123, 9139
DOI: 10.1021/acs.chemrev.2c00482

Access to N-α-deuterated amino acids and DNA conjugates via Ca(II)-HFIP-mediated reductive deutero-amination of α-oxo-carbonyl compounds
Haoran Li, Yuwei Liu, Silin Zhang, Lei Ma, Zhongyi Zeng, Zhi Zhou, Vincent Gandon, Hongtao Xu, Wei Yi and Shengdong Wang
Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-57098-w

Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C−O Bond Cleavage
Smita Patnaik and Aaron D. Sadow
Angewandte Chemie, 2019, 131, 2527
DOI: 10.1002/ange.201813305

Heteroleptic Heavier Alkaline Earth Metal Amide Complexes Stabilized by a Superbulky β-Diketiminate Ligand
Thomas Xaver Gentner, Bastian Rösch, Katharina Thum, Jens Langer, Gerd Ballmann, Jürgen Pahl, Wolfgang A. Donaubauer, Frank Hampel and Sjoerd Harder
Organometallics, 2019, 38, 2485
DOI: 10.1021/acs.organomet.9b00211

Novel aluminium compounds derived from Schiff bases: Synthesis, characterization and catalytic performance in hydroboration
Da Jin, Xiaoli Ma, Yashuai Liu, Jiong Peng and Zhi Yang
Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.4637

Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis
Bhupendra Goswami, Thomas J. Feuerstein, Ravi Yadav, Ralf Köppe, Sergei Lebedkin, Manfred M. Kappes and Peter W. Roesky
Chemistry A European J, 2021, 27, 4401
DOI: 10.1002/chem.202004833

Calcium‐Ligand Cooperation Promoted Activation of N2O, Amine, and H2 as well as Catalytic Hydrogenation of Imines, Quinoline, and Alkenes
Yaoyu Liang, Irena Efremenko, Yael Diskin‐Posner, Liat Avram and David Milstein
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401702

Bemerkenswerte Reaktivität eines 1,2‐Dihydrodialans mit organischen Aziden – vom terminalen Diazido–Dialuman zur pendeluhrartigen Azidbrücke
Xiaobai Wang, Franziska Traeger, Raphael F. Ligorio, Nico Graw, Regine Herbst‐Irmer, Anna Krawczuk, Malte Fischer and Dietmar Stalke
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202503638

Conversion of Alkynes to Imidazolidin-2-ones: Insight into the Role of Magnesium Amido Complexes in the Reaction
Anubhab Das, Sayantan Mukhopadhyay and Sharanappa Nembenna
Organometallics, 2026, 45, 36
DOI: 10.1021/acs.organomet.5c00395

Ca(II) and Yb(II) complexes featuring M(C≡C)4 structural motif: enforced proximity or genuine η2‐bonding?
Dmitry M. Lyubov, Hamza Zakaria, Yulia V. Nelyubina, Rinat R. Aysin, Sergey S. Bukalov and Alexander A. Trifonov
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303533

Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring‐Size Effect of Macrocyclic Ligands on Activity
Thomas Höllerhage, Danny Schuhknecht, Alisha Mistry, Thomas P. Spaniol, Yan Yang, Laurent Maron and Jun Okuda
Chemistry A European J, 2021, 27, 3002
DOI: 10.1002/chem.202004931

Electrophilic Hydrosilylation of Electron‐Rich Alkenes Derived from Enamines
Carlos J. Laglera‐Gándara, Julián Jiménez‐Pérez, Francisco J. Fernández‐de‐Córdova, Pablo Ríos and Salvador Conejero
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202404859

Recent Advances in Metal‐Catalyzed Asymmetric Hydroboration of Ketones
Ruibin Wang and Sehoon Park
ChemCatChem, 2021, 13, 1898
DOI: 10.1002/cctc.202001947

Low‐Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes
Erwann Le Coz, Vincent Dorcet, Thierry Roisnel, Sven Tobisch, Jean‐François Carpentier and Yann Sarazin
Angewandte Chemie, 2018, 130, 11921
DOI: 10.1002/ange.201807297

Photosynthetic Production of Molecular Oxygen by Water Oxidation
Lars Olof Björn
Oxygen, 2022, 2, 337
DOI: 10.3390/oxygen2030024

Metal⋅⋅⋅F−C Bonding in Low‐Coordinate Alkaline Earth Fluoroarylamides
Hanieh Roueindeji, Antsa Ratsifitahina, Thierry Roisnel, Vincent Dorcet, Samia Kahlal, Jean‐Yves Saillard, Jean‐François Carpentier and Yann Sarazin
Chemistry A European J, 2019, 25, 8854
DOI: 10.1002/chem.201901262

Different Reaction Modes Operating in ansa‐Half‐Sandwich Magnesium Catalysts
Leonardo I. Lugo‐Fuentes, Victor A. Lucas‐Rosales, J. Antonio Sandoval‐Mendoza, Rong Shang, Juan Pablo Martínez and J. Oscar C. Jiménez‐Halla
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304130

Dilithium and Magnesium Alkanediides and 1‐Oxaalkanediides
Reinald Fischer, Helmar Görls, Sven Krieck and Matthias Westerhausen
Zeitschrift anorg allge chemie, 2017, 643, 1276
DOI: 10.1002/zaac.201700222

Hydrosilylation of Carbonyls Catalyzed by Hydridoborenium Borate Salts: Lewis Acid Activation and Anion Mediated Pathways
Sandeep Rawat, Mamta Bhandari, Vishal Kumar Porwal and Sanjay Singh
Inorg. Chem., 2020, 59, 7195
DOI: 10.1021/acs.inorgchem.0c00646

Contemporary Molecular Barium Chemistry
Peter M. Chapple and Yann Sarazin
Eur J Inorg Chem, 2020, 2020, 3321
DOI: 10.1002/ejic.202000501

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications
Ross McLellan, Alan R. Kennedy, Robert E. Mulvey, Samantha A. Orr and Stuart D. Robertson
Chemistry A European J, 2017, 23, 16853
DOI: 10.1002/chem.201703609

Main Group Multiple Bonds for Bond Activations and Catalysis
Catherine Weetman
Chemistry A European J, 2021, 27, 1941
DOI: 10.1002/chem.202002939

Facile, Reversible Hydrogen Activation by Low-Coordinate Magnesium Oxide Complexes
Samuel Thompson, Stuart Burnett, Rochelle Ferns, Tanja van Mourik, Aidan P. McKay, Alexandra M. Z. Slawin, David B. Cordes and Andreas Stasch
J. Am. Chem. Soc., 2025, 147, 5247
DOI: 10.1021/jacs.4c16041

Efficient absorption of H2S and in situ conversion of α,β-unsaturated carboxylate esters by bi-quaternary ammonium ionic liquids
Ruizhong Lu, Tao Jiang, Yang Zhai, Songqi Ma, Mohamad Chadia Celestinah and Yun Xu
Separation and Purification Technology, 2025, 360, 130919
DOI: 10.1016/j.seppur.2024.130919

The Road Travelled: After Main‐Group Elements as Transition Metals
Catherine Weetman and Shigeyoshi Inoue
ChemCatChem, 2018, 10, 4213
DOI: 10.1002/cctc.201800963

Calcium Amido Complexes Coordinated by Tridentate Amidinate Ligands: Synthesis, Structures and Catalytic Activity in Olefin Hydrophosphination and Polymerization of Cyclic Esters
Aleksei O. Tolpygin, Anton V. Cherkasov, Georgy K. Fukin, Tatyana A. Kovylina, Konstantin A. Lyssenko and Alexander A. Trifonov
Eur J Inorg Chem, 2019, 2019, 4289
DOI: 10.1002/ejic.201900610

Bis(4‐methylbenzoxazol‐2‐yl)methanide in s‐Block Metal Coordination
Ingo Koehne, Regine Herbst‐Irmer and Dietmar Stalke
Eur J Inorg Chem, 2017, 2017, 3322
DOI: 10.1002/ejic.201700501

Synthesis and reactivity of low-oxidation-state alkaline earth metal complexes
Lucas A. Freeman, Jacob E. Walley and Robert J. Gilliard
Nat. Synth, 2022, 1, 439
DOI: 10.1038/s44160-022-00077-6

Hydrophosphination of Aromatic Alkenes and α,β‐Unsaturated Compounds Using Cobalt Phenoxyimine Complex and Isolation of Double‐Insertion Products
Kouki Matsubara, Momoko Hori, Mizuki Horiguchi and Yuji Koga
Eur J Org Chem, 2026, 29
DOI: 10.1002/ejoc.202501079

Bisgermylene-Stabilized Stannylone: Catalytic Reduction of Nitrous Oxide and Nitro Compounds via Element-Ligand Cooperativity
Binglin Lei, Fanshu Cao, Ming Chen, Xuyang Wang and Zhenbo Mo
J. Am. Chem. Soc., 2024, 146, 17817
DOI: 10.1021/jacs.4c03227

A Simple Route to Calcium and Strontium Hydride Clusters
Brant Maitland, Michael Wiesinger, Jens Langer, Gerd Ballmann, Jürgen Pahl, Holger Elsen, Christian Färber and Sjoerd Harder
Angew Chem Int Ed, 2017, 56, 11880
DOI: 10.1002/anie.201706786

Calcium‐Catalyzed Arene C−H Bond Activation by Low‐Valent AlI
Steffen Brand, Holger Elsen, Jens Langer, Samuel Grams and Sjoerd Harder
Angewandte Chemie, 2019, 131, 15642
DOI: 10.1002/ange.201908978

Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis
Yoon Kyung Jang, Marc Magre and Magnus Rueping
Org. Lett., 2019, 21, 8349
DOI: 10.1021/acs.orglett.9b03131

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides
Christopher Z. Ye, Iker Del Rosal, Sheridon N. Kelly, Erik T. Ouellette, Laurent Maron, Clément Camp and John Arnold
Inorg. Chem., 2024, 63, 21167
DOI: 10.1021/acs.inorgchem.4c03449

A Molecular Barium Hydrido Complex Stabilized by a Super‐Bulky Hydrotris(pyrazolyl)borate Ligand
Xianghui Shi, Cuiping Hou, Chulu Zhou, Yanyao Song and Jianhua Cheng
Angew Chem Int Ed, 2017, 56, 16650
DOI: 10.1002/anie.201709344

Fast complete reduction of chlorite to chloride from drinking water in Al(III)/sulfite system: Kinetics, mechanisms, and applications
Xingli Ji, Li-an Hou, Shuili Yu, Ying Xu, Menghong Gao, Wei Zhang and Qian Xiao
Chemical Engineering Journal, 2025, 504, 158898
DOI: 10.1016/j.cej.2024.158898

Potassium Dimesitylphosphinite Catalyzed Intermolecular Hydrophosphorylation of Alkynes
Stephan M. Härling, Benjamin E. Fener, Sven Krieck, Helmar Görls and Matthias Westerhausen
Organometallics, 2018, 37, 4380
DOI: 10.1021/acs.organomet.8b00368

Mono(hydrosilylation) of N-Heterocycles Catalyzed by B(C6F5)3 and Silylium Ion
William D. Petrushko and Georgii I. Nikonov
Organometallics, 2020, 39, 4717
DOI: 10.1021/acs.organomet.0c00697

Heteroleptic Magnesium n-Butyl on a Chemically Non-innocent 2-Anilidomethylpyridine Ligand Leading to Diverse Magnesium Hydrides
Chhotan Mandal, Shalini Joshi, Sabyashachi Mishra and Debabrata Mukherjee
Inorg. Chem., 2024, 63, 15692
DOI: 10.1021/acs.inorgchem.4c01612

s‐Block Multiple Bonds: Isolation of a Beryllium Imido Complex
Guocang Wang, Jacob E. Walley, Diane A. Dickie, Andrew Molino, David J. D. Wilson and Robert J. Gilliard
Angewandte Chemie, 2021, 133, 9493
DOI: 10.1002/ange.202016027

Cooperative H–X Bond Activation by Electron‐Precise Aluminium and Gallium Compounds Incorporating β‐Diketiminate Ligands
Patrick S. Hitzfeld and Robert Kretschmer
Eur J Inorg Chem, 2020, 2020, 1624
DOI: 10.1002/ejic.201901320

Hydroamination of 2-vinylpyridine, styrene, and isoprene with pyrrolidine catalyzed by alkali and alkaline-earth metal complexes
A. M. Yakub, M. V. Moskalev, N. L. Bazyakina, A. V. Cherkasov, A. S. Shavyrin and I. L. Fedushkin
Russ Chem Bull, 2016, 65, 2887
DOI: 10.1007/s11172-016-1673-8

Aspects of Phosphaallene Chemistry: Heat-Induced Formation of 1,2-Dihydrophosphetes by Intramolecular Nucleophilic Aromatic Substitution and Photochemical Generation of Tricyclic Phosphiranes
Jonas C. Tendyck, Hans Klöcker, Lina Schürmann, Ernst-Ulrich Würthwein, Alexander Hepp, Marcus Layh and Werner Uhl
J. Org. Chem., 2020, 85, 14315
DOI: 10.1021/acs.joc.9b03056

Aluminum Hydride Catalyzed Hydroboration of Alkynes
Alessandro Bismuto, Stephen P. Thomas and Michael J. Cowley
Angew Chem Int Ed, 2016, 55, 15356
DOI: 10.1002/anie.201609690

Functionalised Alkaline Earth Iodides from Grignard Synthons “PhAeI(thf)n” (Ae = Mg‐Ba)
Caspar N. de Bruin‐Dickason, Glen B. Deacon, Cameron Jones, Peter C. Junk and Michal Wiecko
Eur J Inorg Chem, 2019, 2019, 1030
DOI: 10.1002/ejic.201801489

Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides
Qiumiao Shen, Xiaoli Ma, Wenling Li, Wenqing Liu, Yi Ding, Zhi Yang and Herbert W. Roesky
Chemistry A European J, 2019, 25, 11918
DOI: 10.1002/chem.201902000

Reductive Elimination and Oxidative Addition of Hydrogen at Organostannylium and Organogermylium Cations
Fatima Diab, Frederik S. W. Aicher, Christian P. Sindlinger, Klaus Eichele, Hartmut Schubert and Lars Wesemann
Chemistry A European J, 2019, 25, 4426
DOI: 10.1002/chem.201805770

Organocalcium Complex‐Catalyzed Dehydrogenative Coupling of Hydrosilanes with Terminal Alkynes
Ruixin Liu, Xiaojuan Liu, Tanyu Cheng and Yaofeng Chen
Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202101218

Imine hydrogenation with simple alkaline earth metal catalysts
Heiko Bauer, Mercedes Alonso, Christian Färber, Holger Elsen, Jürgen Pahl, Andrea Causero, Gerd Ballmann, Frank De Proft and Sjoerd Harder
Nat Catal, 2018, 1, 40
DOI: 10.1038/s41929-017-0006-0

Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation
Yaoyu Liang, Uttam Kumar Das, Jie Luo, Yael Diskin-Posner, Liat Avram and David Milstein
J. Am. Chem. Soc., 2022, 144, 19115
DOI: 10.1021/jacs.2c08491

Neutral and Cationic Zirconium Complexes Bearing Multidentate Aminophenolato Ligands for Hydrophosphination Reactions of Alkenes and Heterocumulenes
Yu Zhang, Liye Qu, Yaorong Wang, Dan Yuan, Yingming Yao and Qi Shen
Inorg. Chem., 2018, 57, 139
DOI: 10.1021/acs.inorgchem.7b02248

Heavier Alkaline‐Earth Catalyzed Dehydrocoupling of Silanes and Alcohols for the Synthesis of Metallo‐Polysilylethers
Louis J. Morris, Michael S. Hill, Mary F. Mahon, Ian Manners, Fred S. McMenamy and George R. Whittell
Chemistry A European J, 2020, 26, 2954
DOI: 10.1002/chem.201905313

Approaching a “Naked” Boryl Anion: Amide Metathesis as a Route to Calcium, Strontium, and Potassium Boryl Complexes
Andrey V. Protchenko, Petra Vasko, M. Ángeles Fuentes, Jamie Hicks, Dragoslav Vidovic and Simon Aldridge
Angew Chem Int Ed, 2021, 60, 2064
DOI: 10.1002/anie.202011839

Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes
Marc Magre, Bholanath Maity, Alban Falconnet, Luigi Cavallo and Magnus Rueping
Angewandte Chemie, 2019, 131, 7099
DOI: 10.1002/ange.201902188

Alkaline-Earth Metal Bis[bis(trimethylsilyl)amide] Complexes with Weakly Coordinating 2,2,5,5-Tetramethyltetrahydrofuran Ligands
Sven Krieck, Philipp Schüler, Helmar Görls and Matthias Westerhausen
Inorg. Chem., 2018, 57, 13937
DOI: 10.1021/acs.inorgchem.8b02469

Tris(carbene) Stabilization of Monomeric Magnesium Cations: A Neutral, Nontethered Ligand Approach
Akachukwu D. Obi, Jacob E. Walley, Nathan C. Frey, Yuen Onn Wong, Diane A. Dickie, Charles Edwin Webster and Robert J. Gilliard
Organometallics, 2020, 39, 4329
DOI: 10.1021/acs.organomet.0c00462

s‐Block Multiple Bonds: Isolation of a Beryllium Imido Complex
Guocang Wang, Jacob E. Walley, Diane A. Dickie, Andrew Molino, David J. D. Wilson and Robert J. Gilliard
Angew Chem Int Ed, 2021, 60, 9407
DOI: 10.1002/anie.202016027

Stabilisierung eines Strontiumhydridkomplexes mit einem Einzähnigen Carbazolylliganden und Dessen Reaktivität
Lucas Winkler and Alexander Hinz
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202418558

Ligand Effects in Calcium Catalyzed Ketone Hydroboration
Steffen Brand, Andrea Causero, Holger Elsen, Jürgen Pahl, Jens Langer and Sjoerd Harder
Eur J Inorg Chem, 2020, 2020, 1728
DOI: 10.1002/ejic.202000264

Controlling Al–M Interactions in Group 1 Metal Aluminyls (M = Li, Na, and K). Facile Conversion of Dimers to Monomeric and Separated Ion Pairs
Matthew J. Evans, Mathew D. Anker, Michael G. Gardiner, Claire L. McMullin and Martyn P. Coles
Inorg. Chem., 2021, 60, 18423
DOI: 10.1021/acs.inorgchem.1c03012

Lanthanide Mimicking by Magnesium for Oxazolidinone Synthesis
Rohit Kumar, Biplab Mahata, S. Gayathridevi, K. Vipin Raj, Kumar Vanka and Sakya S. Sen
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303478

Formation of Formic Acid Derivatives through Activation and Hydroboration of CO2 by Low-Valent Group 14 (Si, Ge, Sn, Pb) Catalysts
Nery Villegas-Escobar, Henry F. Schaefer and Alejandro Toro-Labbé
J. Phys. Chem. A, 2020, 124, 1121
DOI: 10.1021/acs.jpca.9b11648

Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings
Johannes Martin, Christian Knüpfer, Jonathan Eyselein, Christian Färber, Samuel Grams, Jens Langer, Katharina Thum, Michael Wiesinger and Sjoerd Harder
Angew Chem Int Ed, 2020, 59, 9102
DOI: 10.1002/anie.202001160

New Approach to Substrate Activation or How Heterobimetallic Complexes {[(p-tBu-C6H4)2CH]3M}K (M = Ca and Yb) Make Intermolecular Olefin Hydroamination and NH3 Cascade Hydroamination/Hydroaminomethylation Feasible
Alexander N. Selikhov, Anton V. Cherkasov, Yulia V. Nelyubina and Alexander A. Trifonov
ACS Catal., 2023, 13, 12582
DOI: 10.1021/acscatal.3c03471

Ytterbium(II) Complex‐Catalyzed Selective Single and Double Hydrophosphination of 1,3‐Enynes
Bing Jing, Cheng Zhu, Haibin Song, Jianfeng Li and Chunming Cui
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401234

NHC-Stabilized Early Main Group Species: Reactivity and Emerging Catalysis
Stuart Burnett, Scott Miller, Fáinché Murphy and Catherine E. Weetman
ACS Catal., 2026, 16, 5276
DOI: 10.1021/acscatal.5c08919

Theoretical Study on Bismuth(III) Catalysts for Synthesis of Phenylsulfonyl Fluoride: Reasons of Their Catalysis
Yu Tian and Shigeyoshi Sakaki
ACS Catal., 2024, 14, 2758
DOI: 10.1021/acscatal.3c04874

Hydrophosphanylation of Alkynes via Magnesium Complexes: Evidence for Ligand Dependency in Structure–Activity Relationships
Darakshan Parveen, Sneha Mittal, Radhika Shrivas, Biswarup Pathak and Dipak Kumar Roy
Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500002

s-Block Metal Dibenzoazepinate Complexes: Evidence for Mg–Alkene Encapsulation
Benjamin Freitag, Holger Elsen, Jürgen Pahl, Gerd Ballmann, Alberto Herrera, Romano Dorta and Sjoerd Harder
Organometallics, 2017, 36, 1860
DOI: 10.1021/acs.organomet.7b00200

Heavy alkaline earth π-complexes with doubly-reduced polycyclic aromatic hydrocarbons of variable sizes
Andrew Uresk, Natalie J. O'Neil, Zheng Zhou, Zheng Wei and Marina A. Petrukhina
Journal of Organometallic Chemistry, 2019, 897, 57
DOI: 10.1016/j.jorganchem.2019.06.011

MgCl2-Catalyzed Chemoselective Reduction of Aldehydes, Ketones and Imines
Miaomiao Zhang, Rong Chen, Hongmei Jiao, Haojie Ma, Bo Han, Yuqi Zhang and Jijiang Wang
Chinese Journal of Organic Chemistry, 2023, 43, 1462
DOI: 10.6023/cjoc202208042

Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species
Xufang Liu, Arseni Kostenko, Matthew M. D. Roy, Tobias Weng and Shigeyoshi Inoue
Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-63460-9

Hydrido Complexes of Calcium: A New Family of Molecular Alkaline‐Earth‐Metal Compounds
Debabrata Mukherjee, Danny Schuhknecht and Jun Okuda
Angew Chem Int Ed, 2018, 57, 9590
DOI: 10.1002/anie.201801869

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications
Victoria A. Pollard, Allan Young, Ross McLellan, Alan R. Kennedy, Tell Tuttle and Robert E. Mulvey
Angew Chem Int Ed, 2019, 58, 12291
DOI: 10.1002/anie.201906807

Ligand Influence on Carbonyl Hydroboration Catalysis by Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M=Li, Na, K)
Hassan Osseili, Debabrata Mukherjee, Thomas P. Spaniol and Jun Okuda
Chemistry A European J, 2017, 23, 14292
DOI: 10.1002/chem.201702818

Origin of the Ligand Ring‐Size Effect on the Catalytic Activity of Cationic Calcium Hydride Dimers in the Hydrogenation of Unactivated 1‐Alkenes
Hui Zhu, Zheng‐Wang Qu and Stefan Grimme
ChemistryOpen, 2022, 11
DOI: 10.1002/open.202200240

Fluorenyl-tethered N-heterocyclic carbene: An effective ancillary support for heteroleptic magnesium organometallics
Sumana Mondal, Subham Sarkar, Dibyendu Mallick and Debabrata Mukherjee
Polyhedron, 2024, 251, 116849
DOI: 10.1016/j.poly.2024.116849

Bis(imino)carbazolate: A Master Key for Barium Chemistry
Peter M. Chapple, Samia Kahlal, Julien Cartron, Thierry Roisnel, Vincent Dorcet, Marie Cordier, Jean‐Yves Saillard, Jean‐François Carpentier and Yann Sarazin
Angewandte Chemie, 2020, 132, 9205
DOI: 10.1002/ange.202001439

Chiral Tetra-coordinate Aluminum Cation in Catalysis
Ching-Pei Hsu, Yi-Hung Liu, Ramalingam Boobalan, Ya-Fan Lin, Rong-Jie Chein and Ching-Wen Chiu
Organometallics, 2021, 40, 1244
DOI: 10.1021/acs.organomet.1c00036

Magnesiation and calciation of C H acidic N-alkyl imidazoles
Bibian Okokhere-Edeghoghon, Michael S. Hill and Mary F. Mahon
Polyhedron, 2024, 264, 117255
DOI: 10.1016/j.poly.2024.117255

The Role of Complexes of Biogenic Metals in Living Organisms
Irena Kostova
Inorganics, 2023, 11, 56
DOI: 10.3390/inorganics11020056

Barium‐Catalyzed Dehydrocoupling of Terminal Alkynes and Hydrosilanes
Sakshi Mohan, Eric Clot, Marie Cordier, Jean‐François Carpentier and Yann Sarazin
ChemistryEurope, 2026, 4
DOI: 10.1002/ceur.202500401

Organocalcium Hydride-Catalyzed Intramolecular C(sp3)–H Annulation of Functionalized 2,6-Lutidines
Shuo Li, Xian Xu, Qianlin Sun and Xin Xu
J. Org. Chem., 2023, 88, 1742
DOI: 10.1021/acs.joc.2c02800

LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts
George Kleinhans, Aino J. Karhu, Hugo Boddaert, Sadia Tanweer, David Wunderlin and Daniela I. Bezuidenhout
Chem. Rev., 2023, 123, 8781
DOI: 10.1021/acs.chemrev.3c00202

LiAlH4: From Stoichiometric Reduction to Imine Hydrogenation Catalysis
Holger Elsen, Christian Färber, Gerd Ballmann and Sjoerd Harder
Angew Chem Int Ed, 2018, 57, 7156
DOI: 10.1002/anie.201803804

Regioselective Ring Opening Reactions of Pyridine N-Oxide Analogues by Magnesium Hydride Complexes
Hongyan Xie, Xinli Liu and Dongmei Cui
Organometallics, 2017, 36, 3597
DOI: 10.1021/acs.organomet.7b00517

Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)2
Chong Yu, Chenjun Guo, Linhong Jiang, Mingliang Gong and Yunjie Luo
Organometallics, 2021, 40, 1201
DOI: 10.1021/acs.organomet.1c00120

Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin
Andrew D. Bage, Thomas A. Hunt and Stephen P. Thomas
Org. Lett., 2020, 22, 4107
DOI: 10.1021/acs.orglett.0c01168

Calcium‐Ligand Cooperation Promoted Activation of N2O, Amine, and H2 as well as Catalytic Hydrogenation of Imines, Quinoline, and Alkenes
Yaoyu Liang, Irena Efremenko, Yael Diskin‐Posner, Liat Avram and David Milstein
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401702

Synthesis, characterization, thermal and photophysical properties of novel strontium (II) phthalocyanine
Mehmet Pişkin
J Incl Phenom Macrocycl Chem, 2022, 102, 35
DOI: 10.1007/s10847-021-01094-2

Bis(phenoxy-imine) Alkaline–Earth Complexes with Competing Binding Pockets
Rebecca L. Jones, Zoë R. Turner, Jean-Charles Buffet and Dermot O’Hare
Organometallics, 2024, 43, 414
DOI: 10.1021/acs.organomet.3c00504

Complexes of CaII with the tris[(2-dimethylaminomethyl)phenyl]methoxide ligand
A. N. Selikhov, Yu. V. Nelyubina and A. A. Trifonov
Russ Chem Bull, 2024, 73, 2844
DOI: 10.1007/s11172-024-4401-9

ChemInform Abstract: Alkaline Earths as Main Group Reagents in Molecular Catalysis
Michael S. Hill, David J. Liptrot and Catherine Weetman
ChemInform, 2016, 47
DOI: 10.1002/chin.201615248

NHI- and NHC-Supported Al(III) Hydrides for Amine–Borane Dehydrocoupling Catalysis
Catherine Weetman, Nozomi Ito, Masafumi Unno, Franziska Hanusch and Shigeyoshi Inoue
Inorganics, 2019, 7, 92
DOI: 10.3390/inorganics7080092

A PEGylated Tin Porphyrin Complex for Electrocatalytic Proton Reduction: Mechanistic Insights into Main‐Group‐Element Catalysis
Ashwin Chaturvedi, Gavin A. McCarver, Soumalya Sinha, Elijah G. Hix, Konstantinos D. Vogiatzis and Jianbing Jiang
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202206325

Regulating microenvironment of Cu-site in HKUST-1 for efficiently promoting alkali-free hydroboration of terminal alkyne under room temperature
Yanyan Deng, Long Tian, Xiaonan Song, Huaibiao Wang, Shuangjiang Li, Tianxiu He, Hanxi Li, Yunfei He, Kaili Yao, Hongying Su, Shaoyun Shan and Tianding Hu
Molecular Catalysis, 2025, 585, 115325
DOI: 10.1016/j.mcat.2025.115325

Role of alkaline-earth metal in catalysed imine hydrogenations
Bart De Tobel, Trevor A. Hamlin, Célia Fonseca Guerra, Sjoerd Harder, Frank De Proft and Mercedes Alonso
Polyhedron, 2024, 248, 116751
DOI: 10.1016/j.poly.2023.116751

Influence of 18-Crown-6 Ether Coordination on the Catalytic Activity of Potassium and Calcium Diarylphosphinites in Hydrophosphorylation Reactions
Stephan M. Härling, Sven Krieck, Helmar Görls and Matthias Westerhausen
Inorg. Chem., 2017, 56, 9255
DOI: 10.1021/acs.inorgchem.7b01314

Gallium Hydride‐Catalyzed Selective Hydroboration of Unsaturated Organic Substrates
Sagrika Rajput, Rajata Kumar Sahoo, Nabin Sarkar and Sharanappa Nembenna
ChemPlusChem, 2024, 89
DOI: 10.1002/cplu.202300737

Lewis Acidic Cationic Strontium and Barium Complexes
Katharina Thum, Johannes Martin, Holger Elsen, Jonathan Eyselein, Lena Stiegler, Jens Langer and Sjoerd Harder
Eur J Inorg Chem, 2021, 2021, 2643
DOI: 10.1002/ejic.202100345

Alkali-Metal Heavyweights: Up and Coming Contenders in Homogeneous Catalysis?
David Sánchez Roa, Robert E. Mulvey and Eva Hevia
ACS Catal., 2026, 16, 2935
DOI: 10.1021/acscatal.5c08156

Investigating di‐n‐Butylcalcium
Gabriel Duneş, Matthieu Hédouin, Cléo Bastien, Samia Kahlal, Marie Cordier, William Erb, Florence Mongin, Jean‐Yves Saillard, Hassan Oulyadi and Yann Sarazin
ChemistryEurope, 2025, 3
DOI: 10.1002/ceur.202500196

Organocalcium-Complex-Catalyzed Dehydrogenative Silylation and Mono/Dihydrosilylation Tandem Reactions of Terminal Alkynes
Tao Li, Ruixin Liu, Xiaojuan Liu and Yaofeng Chen
Org. Lett., 2023, 25, 761
DOI: 10.1021/acs.orglett.2c04230

Magnesium‐Catalyzed Tandem Dehydrogenation‐Dehydrocoupling: An Atom Economical Access to Alkynylboranes
Mélodie Birepinte, Virginie Liautard, Laurent Chabaud and Mathieu Pucheault
Chemistry A European J, 2020, 26, 3236
DOI: 10.1002/chem.201905772

Anion metathesis and chlorination of late transition metal pincer complexes: Comparing Co, Rh and Zn
Alyssa C. Cabelof, Alec M. Erny, Veronica Carta, Maren Pink and Kenneth G. Caulton
Inorganica Chimica Acta, 2021, 516, 120118
DOI: 10.1016/j.ica.2020.120118

Scope and Limitations of the s‐Block Metal‐Mediated Pudovik Reaction
Benjamin E. Fener, Philipp Schüler, Nico Ueberschaar, Peter Bellstedt, Helmar Görls, Sven Krieck and Matthias Westerhausen
Chemistry A European J, 2020, 26, 7235
DOI: 10.1002/chem.201905565

Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis
Thomas Höllerhage, Thomas P. Spaniol, Ambre Carpentier, Laurent Maron and Jun Okuda
Inorg. Chem., 2022, 61, 3309
DOI: 10.1021/acs.inorgchem.1c03894

Recent Progress of Calcium-Based Catalysts in Organic Transformations
Dipakkumar Bariya, Chandni Halpani and Satyendra Mishra
COC, 2022, 26, 1661
DOI: 10.2174/1385272827666221212163027

Hydrophosphination of Styrene and Polymerization of Vinylpyridine: A Computational Investigation of Calcium-Catalyzed Reactions and the Role of Fluxional Noncovalent Interactions
Bryan J. Ward and Patricia A. Hunt
ACS Catal., 2017, 7, 459
DOI: 10.1021/acscatal.6b02251

N-Heterocyclic Carbene-Mediated Ring Opening of Reduced Diazamagnesacycles
Akachukwu D. Obi, Lucas A. Freeman, Diane A. Dickie and Robert J. Gilliard
Organometallics, 2020, 39, 4575
DOI: 10.1021/acs.organomet.0c00620

A Novel Bulky Heteroaromatic‐Substituted Methanide Mimicking NacNac: Bis(4,6‐tert‐butylbenzoxazol‐2‐yl)methanide in s‐Block Metal Coordination
Ingo Koehne, Sebastian Bachmann, Thomas Niklas, Regine Herbst‐Irmer and Dietmar Stalke
Chemistry A European J, 2017, 23, 13141
DOI: 10.1002/chem.201702378

N-Heterocyclic Carbene-Coordinated M(II) (M = Yb, Sm, Ca) Bisamides: Expanding the Limits of Intermolecular Alkene Hydrophosphination
Ivan V. Lapshin, Anton V. Cherkasov, Konstantin A. Lyssenko, Georgy K. Fukin and Alexander A. Trifonov
Inorg. Chem., 2022, 61, 9147
DOI: 10.1021/acs.inorgchem.2c00698

Stabilization of Heteroleptic Heavier Alkaline Earth Metal Complexes with an Encapsulating Dipyrromethene Ligand
Gerd Ballmann, Bastian Rösch and Sjoerd Harder
Eur J Inorg Chem, 2019, 2019, 3683
DOI: 10.1002/ejic.201900743

LiAlH4: From Stoichiometric Reduction to Imine Hydrogenation Catalysis
Holger Elsen, Christian Färber, Gerd Ballmann and Sjoerd Harder
Angewandte Chemie, 2018, 130, 7274
DOI: 10.1002/ange.201803804

Development and mechanistic studies of calcium–BINOL phosphate-catalyzed hydrocyanation of hydrazones
Carola Tortora, Christian Andreas Fischer, Sascha Kohlbauer, Alexandru Zamfir, Gerd M Ballmann, Jürgen Pahl, Sjoerd Harder and Svetlana B Tsogoeva
Beilstein J. Org. Chem., 2025, 21, 755
DOI: 10.3762/bjoc.21.59

Ring‐Shaped Phosphinoamido‐Magnesium‐Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis
Lea Fohlmeister and Andreas Stasch
Chemistry A European J, 2016, 22, 10235
DOI: 10.1002/chem.201601623

Homoleptic Chiral Benzamidinate Complexes of the Heavier Alkaline Earth Metals and the Divalent Lanthanides
Meng He, Michael T. Gamer and Peter W. Roesky
Organometallics, 2016, 35, 2638
DOI: 10.1021/acs.organomet.6b00373

Super‐Bulky Penta‐arylcyclopentadienyl Ligands: Isolation of the Full Range of Half‐Sandwich Heavy Alkaline‐Earth Metal Hydrides
Xianghui Shi, Guorui Qin, Yang Wang, Lanxiao Zhao, Zhizhou Liu and Jianhua Cheng
Angewandte Chemie, 2019, 131, 4400
DOI: 10.1002/ange.201814733

A Cationic Barium Hydride Complex Supported by an NNNN‐Type Macrocycle
Thomas Höllerhage, Thomas P. Spaniol, Ulli Englert and Jun Okuda
Zeitschrift anorg allge chemie, 2023, 649
DOI: 10.1002/zaac.202200315

Secondary interactions – Cement in trinuclear calcium complexes
Sorin-Claudiu Roşca, Vincent Dorcet, Jean-François Carpentier and Yann Sarazin
Inorganica Chimica Acta, 2018, 475, 59
DOI: 10.1016/j.ica.2017.08.038

Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block
Magnus R. Buchner, Sudip Pan, Christina Poggel, Nils Spang, Matthias Müller, Gernot Frenking and Jörg Sundermeyer
Organometallics, 2020, 39, 3224
DOI: 10.1021/acs.organomet.0c00434

Stannylenes Bearing an Amino‐Linked NHC Ligand as Efficient Catalysts for Hydroboration of Carbonyls and Imines
Yoshiki Kobayashi, Kazuki Nakaya, Shintaro Takahashi, Ryota Watanabe and Norio Nakata
Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501396

Reduction of Cyclic and Linear Organic Carbonates Using a Readily Available Magnesium Catalyst
Marcin Szewczyk, Marc Magre, Viktoriia Zubar and Magnus Rueping
ACS Catal., 2019, 9, 11634
DOI: 10.1021/acscatal.9b04086

Electrophilic Hydrosilylation of Electron‐Rich Alkenes Derived from Enamines
Carlos J. Laglera‐Gándara, Julián Jiménez‐Pérez, Francisco J. Fernández‐de‐Córdova, Pablo Ríos and Salvador Conejero
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202404859

A Simple Route to Calcium and Strontium Hydride Clusters
Brant Maitland, Michael Wiesinger, Jens Langer, Gerd Ballmann, Jürgen Pahl, Holger Elsen, Christian Färber and Sjoerd Harder
Angewandte Chemie, 2017, 129, 12042
DOI: 10.1002/ange.201706786

Pincer‐Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide
Lingyu Liu, Siu‐Kwan Lo, Cory Smith and Jose M. Goicoechea
Chemistry A European J, 2021, 27, 17379
DOI: 10.1002/chem.202103009

Breaking Bonds at Tin(II): Reductive or Oxidative Addition?
Maximilian Dietz, Josef T. Boronski, Amelia M. Swarbrook and Simon Aldridge
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202503050

Main Group Catalysis
Shigeyoshi Inoue, Rebecca L. Melen and Sjoerd Harder
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202200414

Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation
Marc Magre, Eva Paffenholz, Bholanath Maity, Luigi Cavallo and Magnus Rueping
J. Am. Chem. Soc., 2020, 142, 14286
DOI: 10.1021/jacs.0c05917

Base‐Catalyzed Hydrosilylation of Nitriles to Amines and Esters to Alcohols
Joshua A. Clarke, Art van der Est and Georgii I. Nikonov
Eur J Org Chem, 2021, 2021, 4434
DOI: 10.1002/ejoc.202100834

Simple Alkaline‐Earth Metal Catalysts for Effective Alkene Hydrogenation
Heiko Bauer, Mercedes Alonso, Christian Fischer, Bastian Rösch, Holger Elsen and Sjoerd Harder
Angewandte Chemie, 2018, 130, 15397
DOI: 10.1002/ange.201810026

Chiral β-diketiminate-supported magnesium alkyl complexes: Synthesis and their application in the polymerization of rac-lactide
Ziyi Xu, Shaohui Zhang and Wenshan Ren
Inorganica Chimica Acta, 2019, 495, 118970
DOI: 10.1016/j.ica.2019.118970

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis
Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping
Angew Chem Int Ed, 2019, 58, 17567
DOI: 10.1002/anie.201908012

Synthesis and Characterization of Neutral and Cationic Magnesium Complexes Supported by NHC Ligands
Jean-Charles Bruyere, Christophe Gourlaouen, Lydia Karmazin, Corinne Bailly, Corinne Boudon, Laurent Ruhlmann, Pierre de Frémont and Samuel Dagorne
Organometallics, 2019, 38, 2748
DOI: 10.1021/acs.organomet.9b00304

Iron Catalyzed Dehydrocoupling of Amine‐ and Phosphine‐Boranes
Nathan T. Coles and Ruth L. Webster
Israel Journal of Chemistry, 2017, 57, 1070
DOI: 10.1002/ijch.201700018

Intriguing Reactivity of a 1,2‐Dihydrodialumane Towards Organic Azides – From a Terminal Diazido–Dialumane to Pendulum‐Clock‐Like Azide Bridging
Xiaobai Wang, Franziska Traeger, Raphael F. Ligorio, Nico Graw, Regine Herbst‐Irmer, Anna Krawczuk, Malte Fischer and Dietmar Stalke
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202503638

Mechanism and Chemoselectivity of Small Molecule (CO2, tBuNCO, and iPrNCNiPr) Activation by Homobimetallic Compounds: Cp*2Ae2 (Ae = Be, Mg, and Ca) vs Cp*2Zn2
Huixing Wen, Zhendong Li and Xiaoyan Li
J. Phys. Chem. A, 2025, 129, 9667
DOI: 10.1021/acs.jpca.5c04628

Low‐Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes
Erwann Le Coz, Vincent Dorcet, Thierry Roisnel, Sven Tobisch, Jean‐François Carpentier and Yann Sarazin
Angew Chem Int Ed, 2018, 57, 11747
DOI: 10.1002/anie.201807297

Potassium-Mediated Hydrophosphorylation of Heterocumulenes with Diarylphosphane Oxide and Sulfide
Stephan M. Härling, Helmar Görls, Sven Krieck and Matthias Westerhausen
Inorg. Chem., 2016, 55, 10741
DOI: 10.1021/acs.inorgchem.6b01973

Grignard reagents-catalyzed hydroboration of aldehydes and ketones
Weifan Wang, Kai Lu, Yi Qin, Weiwei Yao, Dandan Yuan, Sumod A. Pullarkat, Li Xu and Mengtao Ma
Tetrahedron, 2020, 76, 131145
DOI: 10.1016/j.tet.2020.131145

[(Me6TREN)MgOCHPh2][B(C6F5)4]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration
Ankur, Ramkumar Kannan, Raju Chambenahalli, Sumanta Banerjee, Yan Yang, Laurent Maron and Ajay Venugopal
Eur J Inorg Chem, 2021, 2021, 4632
DOI: 10.1002/ejic.202100651

Kudos and Renaissance of s-Block Metal Chemistry
Sven Krieck and Matthias Westerhausen
Inorganics, 2017, 5, 17
DOI: 10.3390/inorganics5010017

s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds
Marc Magre, Marcin Szewczyk and Magnus Rueping
Chem. Rev., 2022, 122, 8261
DOI: 10.1021/acs.chemrev.1c00641

Benchmark study of popular density functionals for calculating binding energies of three‐center two‐electron bonds
Cheng‐Xing Cui, Dongdong Xu, Bo‐Wen Ding, Ling‐Bo Qu, Yu‐Ping Zhang and Yu Lan
J Comput Chem, 2019, 40, 657
DOI: 10.1002/jcc.25752

Accelerating σ-Bond Metathesis at Sn(II) Centers
Richard Y. Kong, Joseph B. Parry, Guy R. Anello, Matthew E. Ong and Kyle M. Lancaster
J. Am. Chem. Soc., 2023, 145, 24136
DOI: 10.1021/jacs.3c07997

A Stable Calcium Alumanyl
Ryan J. Schwamm, Martyn P. Coles, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Nasir A. Rajabi and Andrew S. S. Wilson
Angewandte Chemie, 2020, 132, 3956
DOI: 10.1002/ange.201914986

A Highly Lewis Acidic Strontium ansa‐Arene Complex for Lewis Acid Catalysis and Isobutylene Polymerization
Philipp Dabringhaus, Marcel Schorpp, Harald Scherer and Ingo Krossing
Angew Chem Int Ed, 2020, 59, 22023
DOI: 10.1002/anie.202010019

Expedient Access to Normal‐ and Abnormal‐ N‐Heterocyclic Carbene (NHC) Magnesium Compounds from Imidazolium Salts
Rajendra S. Ghadwal, Dennis Rottschäfer and Christian J. Schürmann
Zeitschrift anorg allge chemie, 2016, 642, 1236
DOI: 10.1002/zaac.201600308

Organocalcium-mediated nucleophilic alkylation of benzene
Andrew S. S. Wilson, Michael S. Hill, Mary F. Mahon, Chiara Dinoi and Laurent Maron
Science, 2017, 358, 1168
DOI: 10.1126/science.aao5923

Tropylium-Promoted Hydroboration Reactions: Mechanistic Insights Via Experimental and Computational Studies
Nhan N. H. Ton, Binh Khanh Mai and Thanh Vinh Nguyen
J. Org. Chem., 2021, 86, 9117
DOI: 10.1021/acs.joc.1c01208

Cationic barium benzyl and hydride complexes that contain an eighteen-membered N,N,N,N,N,N-type macrocycle
Thomas Höllerhage, Thomas P. Spaniol, Ulli Englert and Jun Okuda
Inorganica Chimica Acta, 2022, 543, 121198
DOI: 10.1016/j.ica.2022.121198

Zinc-Catalyzed Hydrosilylation and Hydroboration of N-Heterocycles
John L. Lortie, Travis Dudding, Bulat M. Gabidullin and Georgii I. Nikonov
ACS Catal., 2017, 7, 8454
DOI: 10.1021/acscatal.7b02811

Synthesis of Mono- and Acyclic Bis-aminoboranes via Controlled Hydroboration of Imines
Siyuan Zhai, Craig Forsyth, Zhizhou Liu and Dragoslav Vidović
Organometallics, 2022, 41, 2562
DOI: 10.1021/acs.organomet.2c00283

Insights Into the Magnesium‐Catalyzed C−C Coupling of Terminal Alkynes with Carbodiimides
Sayantan Mukhopadhyay, Sagrika Rajput, Rajata Kumar Sahoo and Sharanappa Nembenna
Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400702

Aluminum-Catalyzed Selective Hydroboration of Alkenes and Alkynylsilanes
Feng Li, Xu Bai, Yuan Cai, Han Li, Shuo-Qing Zhang, Feng-Hua Liu, Xin Hong, Youjun Xu and Shi-Liang Shi
Org. Process Res. Dev., 2019, 23, 1703
DOI: 10.1021/acs.oprd.9b00205

Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds
Ivan V. Lapshin, Anton V. Cherkasov and Alexander A. Trifonov
Organometallics, 2023, 42, 2531
DOI: 10.1021/acs.organomet.2c00596

Surprisingly Different Reaction Behavior of Alkali and Alkaline Earth Metal Bis(trimethylsilyl)amides toward Bulky N‐(2‐Pyridylethyl)‐N′‐(2,6‐diisopropylphenyl)pivalamidine
Diana Kalden, Ansgar Oberheide, Claas Loh, Helmar Görls, Sven Krieck and Matthias Westerhausen
Chemistry A European J, 2016, 22, 10944
DOI: 10.1002/chem.201602074

Zwitterion‐Initiated Hydroboration of Alkynes and Styrene
Alessandro Bismuto, Michael J. Cowley and Stephen P. Thomas
Adv Synth Catal, 2021, 363, 2382
DOI: 10.1002/adsc.202001323

Metal‐Catalyzed Hydrophosphination
Bryan T. Novas and Rory Waterman
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200988

Highly Soluble Cyclic Organoalanes Based on Anionic Dicarbenes
Arne Merschel, Yury V. Vishnevskiy, Beate Neumann, Hans‐Georg Stammler and Rajendra S. Ghadwal
Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301037

Catalytic hydrogenation of alkyne with planar tetracoordinate carbon in CAl3MgH2¯ system
Abdul Hamid Malhan and Krishnan Thirumoorthy
Front. Chem., 2025, 13
DOI: 10.3389/fchem.2025.1672968

Calcium Mediated C−H Silylation of Aromatic Heterocycles with Hydrosilanes
Xun Gong, Peng Deng and Jianhua Cheng
ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200060

Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis
Alban Falconnet, Marc Magre, Bholanath Maity, Luigi Cavallo and Magnus Rueping
Angewandte Chemie, 2019, 131, 17731
DOI: 10.1002/ange.201908012

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set
Victoria A. Pollard, M. Ángeles Fuentes, Alan R. Kennedy, Ross McLellan and Robert E. Mulvey
Angew Chem Int Ed, 2018, 57, 10651
DOI: 10.1002/anie.201806168

Multielectron Reduction of Nitrosoarene via Aluminylene-Silylene Cooperation
Xi Chen, Dezhi Yang, Fanshu Cao and Zhenbo Mo
J. Am. Chem. Soc., 2024, 146, 29278
DOI: 10.1021/jacs.4c10323

Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α-Diimines
Lucas A. Freeman, Jacob E. Walley, Akachukwu D. Obi, Guocang Wang, Diane A. Dickie, Andrew Molino, David J. D. Wilson and Robert J. Gilliard
Inorg. Chem., 2019, 58, 10554
DOI: 10.1021/acs.inorgchem.9b01058

Reactivity of the magnesium bisamide complex towards C=C=O-, N=C=O-, and N—N=O-containing substrates
V. A. Dodonov, A. A. Skatova and I. L. Fedushkin
Russ Chem Bull, 2024, 73, 555
DOI: 10.1007/s11172-024-4165-2

Mechanism and Catalyst Design in Ru-Catalyzed Alkene Hydrophosphination
Roman G. Belli, Jin Yang, Erick Nuñez Bahena, Robert McDonald and Lisa Rosenberg
ACS Catal., 2022, 12, 5247
DOI: 10.1021/acscatal.1c05636

Heavy Alkaline–Earth Metal Formazanate Complexes and Their Catalytic Applications
Da Jin, Xiaofei Sun and Peter W. Roesky
Organometallics, 2023, 42, 1725
DOI: 10.1021/acs.organomet.2c00591

Unprecedented Reaction Pathway of Sterically Crowded Calcium Complexes: Sequential C−N Bond Cleavage Reactions Induced by C−H Bond Activations
Yang Yang, Haobing Wang and Haiyan Ma
Chemistry — An Asian Journal, 2017, 12, 239
DOI: 10.1002/asia.201601497

Neutral, Cationic and Hydride‐substituted Siloxygermylenes
Matthew M. D. Roy, Shiori Fujimori, Michael J. Ferguson, Robert McDonald, Norihiro Tokitoh and Eric Rivard
Chemistry A European J, 2018, 24, 14392
DOI: 10.1002/chem.201802958

Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
John J. Sandoval, Pilar Palma, Eleuterio Álvarez, Juan Cámpora and Antonio Rodríguez-Delgado
Organometallics, 2016, 35, 3197
DOI: 10.1021/acs.organomet.6b00528

Divergent Reactivity of a Cyclic Bis‐Hydridostannylene: A Masked Sn(I) Diradicaloid
Falk Ebeler, Beate Neumann, Hans‐Georg Stammler and Rajendra S. Ghadwal
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202400382

Hydroboration of substituted alkynes using a solid polymeric carboxylic acid catalyst
Caroline B. Hoyt, Michele L. Sarazen and Christopher W. Jones
Journal of Catalysis, 2019, 369, 493
DOI: 10.1016/j.jcat.2018.11.021

Carbene–Calcium Silylamides and Amidoboranes
Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster and Robert J. Gilliard
Organometallics, 2022, 41, 3064
DOI: 10.1021/acs.organomet.2c00464

A Soft Grip: Magnesium Complexes with a Phosphine‐Modified Phosphonium Diylidic Lewis Base
Jens Langer, Irina Kosygin, Ralph Puchta, Jürgen Pahl and Sjoerd Harder
Chemistry A European J, 2016, 22, 17425
DOI: 10.1002/chem.201603775

Insights into Rare-Earth Metal Complex-Mediated Hydroamination
Shuqi Dong, Jinjin Chen, Kening Qiao, Jian Fang, Yan Yang, Laurent Maron and Bo Liu
ACS Catal., 2021, 11, 3790
DOI: 10.1021/acscatal.1c00566

Mechanistic Insight into Alkali‐Metal‐Mediation of Styrene Transfer Hydrogenation: A DFT Study
Keelan M. Byrne, Stuart D. Robertson, Robert E. Mulvey and Tobias Krämer
ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400655

Diverse Functionality of Molecular Germanium: Emerging Opportunities as Catalysts
Nilanjana Mukherjee and Moumita Majumdar
J. Am. Chem. Soc., 2024, 146, 24209
DOI: 10.1021/jacs.4c05498

A Stable Calcium Alumanyl
Ryan J. Schwamm, Martyn P. Coles, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Nasir A. Rajabi and Andrew S. S. Wilson
Angew Chem Int Ed, 2020, 59, 3928
DOI: 10.1002/anie.201914986

Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium–Hydrogen Bond
Silvia Schnitzler, Thomas P. Spaniol and Jun Okuda
Inorg. Chem., 2016, 55, 12997
DOI: 10.1021/acs.inorgchem.6b02509

Borenium Ion Equivalents Stabilized by BICAAC and Their Implementation as Catalysts in Hydrosilylation of Carbonyls
Manu Adhikari, Sandeep Kumar Thakur and Sanjay Singh
Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403322

Recent Contributions to the Coordination Chemistry of Beryllium
Magnus R. Buchner
Chemistry A European J, 2019, 25, 12018
DOI: 10.1002/chem.201901766

Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions
Matthew J. Margeson, Felix Seeberger, John A. Kelly, Julia Leitl, Peter Coburger, Robert Szlosek, Christian Müller and Robert Wolf
ChemCatChem, 2021, 13, 3761
DOI: 10.1002/cctc.202100651

Organoaluminum Cation Catalyzed Selective Hydrosilylation of Carbonyls, Alkenes, and Alkynes
Nabin Sarkar, Rajata Kumar Sahoo, Sayantan Mukhopadhyay and Sharanappa Nembenna
Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202101030

Interaction of Multiple Bonds with NacNacGa: Oxidative Cleavage vs Coupling and Cyclization
Aishabibi Kassymbek, James F. Britten, Denis Spasyuk, Bulat Gabidullin and Georgii I. Nikonov
Inorg. Chem., 2019, 58, 8665
DOI: 10.1021/acs.inorgchem.9b01005

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes
Marc Magre, Marcin Szewczyk and Magnus Rueping
Org. Lett., 2020, 22, 1594
DOI: 10.1021/acs.orglett.0c00184

Heteroleptic carbazolato-barium hydroborates and a related separated ion pair
Peter.M. Chapple, Thierry Roisnel, Marie Cordier, Jean-François Carpentier and Yann Sarazin
Polyhedron, 2022, 217, 115731
DOI: 10.1016/j.poly.2022.115731

Breaking Bonds at Tin(II): Reductive or Oxidative Addition?
Maximilian Dietz, Josef T. Boronski, Amelia M. Swarbrook and Simon Aldridge
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202503050

Zinc Catalyzed Hydroelementation (HE; E = B, C, N, and O) of Carbodiimides: Intermediates Isolation and Mechanistic Insights
Rajata Kumar Sahoo, Arukela Ganesh Patro, Nabin Sarkar and Sharanappa Nembenna
Organometallics, 2023, 42, 1746
DOI: 10.1021/acs.organomet.2c00610