Issue 72, 2004

Phenylamines as building blocks to layered inorganic–organic structures

Abstract

Five inorganic–organic layered composites have been prepared and characterised. Copper(II) chloride and lead(II) chloride compounds with 1,4-phenylenediamine and benzidine have a 1∶1 inorganic∶organic layer structure. The copper(II) chloride structure with p-biphenylamine is a 1∶2 inorganic∶organic layer structure; this compound undergoes an order–disorder transition at ca. 200 K. Crystallisation of benzidine in the presence of lead (II) chloride or cobalt(II) chloride at elevated temperature produced the chloride salt of benzidine.

Graphical abstract: Phenylamines as building blocks to layered inorganic–organic structures

Article information

Article type
Paper
Submitted
04 may. 2004
Accepted
03 jun. 2004
First published
17 sep. 2004

CrystEngComm, 2004,6, 438-442

Phenylamines as building blocks to layered inorganic–organic structures

S. A. Bourne and Z. Mangombo, CrystEngComm, 2004, 6, 438 DOI: 10.1039/B406671E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements