Issue 82, 2024

Hybrid materials comprising ferrocene and diaminoborane moieties: linear concatenation versus macrocyclization

Abstract

Combination of borane and diaminoferrocene monomers by Si/B exchange condensation reactions afforded either diazabora-[3]ferrocenophanes or, via stepwise processes, larger macrocycles and a series of linear oligomers. Additional incorporation of p-phenylene moieties in the backbone yielded alternating concatenation.

Graphical abstract: Hybrid materials comprising ferrocene and diaminoborane moieties: linear concatenation versus macrocyclization

Supplementary files

Article information

Article type
Communication
Submitted
29 jul. 2024
Accepted
28 ago. 2024
First published
29 ago. 2024

Chem. Commun., 2024,60, 11706-11709

Hybrid materials comprising ferrocene and diaminoborane moieties: linear concatenation versus macrocyclization

J. S. Schneider and H. Helten, Chem. Commun., 2024, 60, 11706 DOI: 10.1039/D4CC03813D

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