Issue 33, 2021

A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Abstract

The reactions of the phosphanylborane Ph2PBH2·NMe3 (L) with Ag[FAl{OC6F10(C6F5)}3] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2·NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2·NMe3)2][FAl] (2) and [Ag(Ph2P-BH2·NMe3)3][FAl] (3), while the second reaction afforded the one-dimensional coordination polymer [Ag(Ph2P-BH2·NMe3)]n[BF4]n (4). Compounds 1–4 are the first reported Ag(I) complexes stabilised by phosphanylboranes.

Graphical abstract: A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Supplementary files

Article information

Article type
Communication
Submitted
03 abr. 2020
Accepted
04 may. 2020
First published
04 may. 2020

New J. Chem., 2021,45, 14916-14919

A new family of silver(I) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

M. Elsayed Moussa, C. Marquardt, O. Hegen, M. Seidl and M. Scheer, New J. Chem., 2021, 45, 14916 DOI: 10.1039/D0NJ01679A

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