Issue 23, 2021

Photo-induced direct alkynylation of methane and other light alkanes by iron catalysis

Abstract

Here we show a practical iron-catalysed photoredox approach for C(sp3)–H alkynylation of methane, ethane, and other light alkanes without pre-functionalisation processes, producing valuable internal alkynes. The protocol has many advantages, including a concise and efficient system, good selectivity, mild conditions, wide application of the synthesised products, and low cost.

Graphical abstract: Photo-induced direct alkynylation of methane and other light alkanes by iron catalysis

Supplementary files

Article information

Article type
Communication
Submitted
15 sep. 2021
Accepted
02 nov. 2021
First published
02 nov. 2021

Green Chem., 2021,23, 9406-9411

Photo-induced direct alkynylation of methane and other light alkanes by iron catalysis

Y. Jin, L. Wang, Q. Zhang, Y. Zhang, Q. Liao and C. Duan, Green Chem., 2021, 23, 9406 DOI: 10.1039/D1GC03388C

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