Issue 56, 2019

Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives

Abstract

Base-assisted diazonium activation has been employed to promote gold(I)/(III) redox catalysis toward allylic oxime cyclization/aryl coupling. Functional isoxazolines were prepared with good to excellent yields, while the alternative photoactivation method provided trace amounts of the isoxazoline products. This study further broadens the scope of gold redox chemistry.

Graphical abstract: Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives

Supplementary files

Article information

Article type
Communication
Submitted
12 abr. 2019
Accepted
14 jun. 2019
First published
18 jun. 2019

Chem. Commun., 2019,55, 8150-8153

Author version available

Gold redox catalysis for cyclization/arylation of allylic oximes: synthesis of isoxazoline derivatives

A. A. Jimoh, S. Hosseyni, X. Ye, L. Wojtas, Y. Hu and X. Shi, Chem. Commun., 2019, 55, 8150 DOI: 10.1039/C9CC02830G

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