Issue 10, 2015

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Abstract

A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10−4 S cm−1), moderate activation energies (0.25–0.28 eV), and high lithium ion transport numbers (up to tLi+ = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes.

Graphical abstract: Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Supplementary files

Article information

Article type
Edge Article
Submitted
08 jun. 2015
Accepted
23 jun. 2015
First published
23 jun. 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2015,6, 5499-5505

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

J. F. Van Humbeck, M. L. Aubrey, A. Alsbaiee, R. Ameloot, G. W. Coates, W. R. Dichtel and J. R. Long, Chem. Sci., 2015, 6, 5499 DOI: 10.1039/C5SC02052B

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