Issue 35, 2014

Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

Abstract

Three-dimensional [CuX(TAA)]n (X = Br (1), I (2)) and bi-dimensional [AgX(TAA)]n (X = Cl (3), Br (4)) coordination polymers have been isolated by the direct synthesis from copper(I) and silver(I) halides and thioacetamide (TAA). These are multifunctional materials showing electrical conductivity (values at room temperature ranging from 7 × 10−6 to 2 × 10−9 S cm−1) and luminescence in the blue region. The unusual solubility of 1–4 in different solvents and the recrystallization process observed for 1 and 2 in acetonitrile and for 3 and 4 in pyridine have been measured. We show preliminary results of the processability of 2 on glass for the production of organized thin films. These results are very attractive for the processability of coordination polymers in materials science and nanoscience.

Graphical abstract: Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

Supplementary files

Article information

Article type
Paper
Submitted
07 mar. 2014
Accepted
25 abr. 2014
First published
25 abr. 2014

CrystEngComm, 2014,16, 8224-8231

Author version available

Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

J. Troyano, J. Perles, P. Amo-Ochoa, J. I. Martínez, F. Zamora and S. Delgado, CrystEngComm, 2014, 16, 8224 DOI: 10.1039/C4CE00480A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements