Themed collection Celebrating the 65th birthdays of Professors Jay Siegel and Kim Baldridge
Pentaphosphorylated magic spot nucleotides: chemoenzymatic synthesis and disassembly-based sensing
A new synthesis of pentaphosphorylated magic spot nucleotides and their sensing based on a disassembly approach are presented.
Org. Biomol. Chem., 2026,24, 3918-3925
https://doi.org/10.1039/D6OB00328A
Linker dependence of 1O2 generation by G4-binding tetra-imidazolium porphyrins
Org. Biomol. Chem., 2026, Accepted Manuscript
https://doi.org/10.1039/D6OB00581K
Design and synthesis of thiophene-based C2-symmetric chiral phosphoric acids on a decahydroquinoxaline scaffold for stereoselective transformations
In this study, the design and the synthesis of a thiophene-based phosphoric acid based on a chiral decahydroquinoxaline scaffold derived from enantiopure trans-1,2-diaminocyclohexane was reported.
Org. Biomol. Chem., 2026,24, 3490-3495
https://doi.org/10.1039/D6OB00309E
A chiral multibrominated triangular macrocycle for modulating circularly polarized phosphorescence
This work developed a chiral triangular macrocycle and achieved tunable circularly polarized room-temperature phosphorescence (CP-RTP) from blue-green to deep-red through rigidification and intermolecular charge-transfer interactions.
Org. Chem. Front., 2026, Advance Article
https://doi.org/10.1039/D6QO00378H
Intramolecular through-space heavy-atom effect in multiresonant thermally activated delayed fluorescence emitters with [2.2]paracyclophane
Org. Chem. Front., 2026, Accepted Manuscript
https://doi.org/10.1039/D6QO00318D
mer-Ir(pmp)3 as a strongly photoreducing and stable Ir(C^C)3 photocatalyst for metallaphotoredox catalysis
Here we report a new homoleptic Ir(NHC) photocatalyst, mer-Ir(pmp)3 which is the first Ir(C^C)3 photocatalyst to operate effectively using excitation sources peaking in the visible (λexc = 427, 440 and 456 nm).
Org. Chem. Front., 2026,13, 2707-2718
https://doi.org/10.1039/D6QO00086J
Double encapsulation of C60, [6]CPP and Li+@C60 inside a peropyrene-linked, CPP-based double nanohoop
Mass spectrometry evidence of elusive 1 : 2 complexes of peropyrene-linked double nanohoop with C60, [6]CPP and Li+@C60 indicates that packing, not intrinsic binding, limits host occupancy in these nanohoops in the solid state.
Org. Chem. Front., 2026, Advance Article
https://doi.org/10.1039/D6QO00235H
A polyaromatic dumbbell-based micelle capable of binding large dyes under organic solvent-rich conditions
A dumbbell-shaped amphiphile assembles into a spherical polyaromatic micelle in water. Binding of organic and metal–organic dyes by the micelle yields host–guest composites with very high stability against organic solvent addition (up to 75% v/v).
Org. Chem. Front., 2026, Advance Article
https://doi.org/10.1039/D6QO00227G
BisBF2 pyridoins: a new platform for the design of efficient two-photon absorbers
We report the synthesis and photophysical studies of quadrupolar dyes based on a new core bearing two BF2 moieties.
Org. Chem. Front., 2026,13, 389-394
https://doi.org/10.1039/D5QO01391G