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Photosensitizing ruthenium(II)–dye multilayers: photoinduced charge separation and back electron transfer suppression


Nobutaka Yoshimura, Atsushi Kobayashi, Wataru Genno, Takashi Okubo, Masaki Yoshida and Masako Kato
Sustainable Energy Fuels, 2020,4, 3450-3457
From themed collection: Artificial Photosynthesis - From Sunlight to Fuels and Valuable Products for a Sustainable Future

Abstract

Photocatalytic H2 evolution activity in iodide aqueous solution was improved by increasing the Ru(II)–dye layer number on the Pt–TiO2 surface.


Bio-inspired protonic memristor devices based on metal complexes with proton-coupled electron transfer


Yusuke Hiruma, Kai Yoshikawa and Masa-aki Haga
Faraday Discuss., 2019,213, 99-113
From themed collection: New memory paradigms: memristive phenomena and neuromorphic applications

Abstract

A new type of memristor inspired by bio-membranes is presented, based on the proton movement resulting from proton-coupled electron transfer (PCET) processes in dinuclear Ru complexes, whereby a two-terminal device based on said Ru complexes and a proton-conducting polymer was constructed as a proof-of-concept.


Durable photoelectrochemical CO2 reduction with water oxidation using a visible-light driven molecular photocathode


Ryutaro Kamata, Hiromu Kumagai, Yasuomi Yamazaki, Masanobu Higashi, Ryu Abe and Osamu Ishitani
J. Mater. Chem. A, 2021, Advance Article
From themed collection: Journal of Materials Chemistry A HOT Papers

Abstract

A durable molecular photocathode driving CO2 reduction with over 1200 of turnover number was developed by electropolymerization of Ru(II) complexes. The cell with a suitable photoanode enabled CO2 reduction with H2O oxidation with no bias for 24 h.


Dye-sensitized electron transfer from TiO2 to oxidized triphenylamines that follows first-order kinetics


Brian N. DiMarco, Ludovic Troian-Gautier, Renato N. Sampaio and Gerald J. Meyer
Chem. Sci., 2018,9, 940-949

Abstract

Two sensitizers, [Ru(bpy)2(dcb)]2+ (RuC) and [Ru(bpy)2(dpb)]2+ (RuP), were anchored to mesoporous TiO2 thin films and utilized to sensitize the reaction of TiO2 electrons with oxidized triphenylamines to visible light in CH3CN electrolytes.


Anthraquinone-bridged diruthenium(II) complexes inhibit migration and invasion of human hepatocarcinoma MHCC97-H cells


Jin-Quan Wang, Jun-Feng Kou, Zi-Zhuo Zhao, Kang-Qiang Qiu and Hui Chao
Inorg. Chem. Front., 2017,4, 1003-1012

Abstract

Four diruthenium(II) complexes exhibited anti-metastatic properties on MHCC97-H cells, which involved in the inhibition of migration and invasion, negative remodulation of the cytoskeleton, blocking cell cycles and regulation of relative signal pathways.


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