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X1INH, an improved next-generation affinity-optimized hydrazonic ligand, attenuates abnormal copper(I)/copper(II)-α-Syn interactions and affects protein aggregation in a cellular model of synucleinopathy


Daphne S. Cukierman, Diana F. Lázaro, Pamela Sacco, Patrícia R. Ferreira, Renata Diniz, Claudio O. Fernández, Tiago F. Outeiro and Nicolás A. Rey
Dalton Trans., 2020,49, 16252-16267
From themed collection: New Talent: Americas

Abstract

By tuning the copper(I)/copper(II) affinity of a novel N-acylhydrazone, a more soluble, hydrolysis resistant and less toxic improved Metal–Protein Attenuating Compound for the bioinorganic management of metal-enhanced aggregopathies was obtained.


Highly fluorinated metal complexes as dual 19F and PARACEST imaging agents


Meng Yu, Bailey S. Bouley, Da Xie and Emily L. Que
Dalton Trans., 2019,48, 9337-9341

Abstract

Highly fluorinated, water-soluble transition metal complexes serve as both 19F and PARACEST magnetic resonance imaging agents.


Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR


Nirmal K. Shee, Michael G. B. Drew and Dipankar Datta
New J. Chem., 2017,41, 452-456

Abstract

Using 5,6-dihydro-5,6-epoxy-1,10-phenanthroline as the ligand L, the X-ray crystal structure of [FeL3](ClO4)2·2H2O is determined.


Recent developments of small molecule γ-secretase modulators for Alzheimer's disease


Shekar Mekala, Grady Nelson and Yue-Ming Li
RSC Med. Chem., 2020,11, 1003-1022

Abstract

This review article highlights the recent progress and outlook for small molecule gamma secretase modulators for potential Alzheimer's therapies.


Metal-based imaging agents: progress towards interrogating neurodegenerative disease


Adam C. Sedgwick, James T. Brewster, Peter Harvey, Diana A. Iovan, Graham Smith, Xiao-Peng He, He Tian, Jonathan L. Sessler and Tony D. James
Chem. Soc. Rev., 2020,49, 2886-2915

Abstract

Transition metals and lanthanide ions display unique properties that enable the development of non-invasive diagnostic tools for imaging. In this review, we highlight various metal-based imaging strategies used to interrogate neurodegeneration.


CHAPTER 11
Chemical Probes in Cellular Assays for Target Validation and Screening in Neurodegeneration


Ana M. Silva, Anna Cederbalk, Daniel Ebner and Elena Di Daniel
The Discovery and Utility of Chemical Probes in Target Discovery, 2021, 276-319

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